Acta Metallurgica Sinica (English Letters) ›› 2021, Vol. 34 ›› Issue (11): 1557-1564.DOI: 10.1007/s40195-021-01256-8
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Man Zhu1(), Chi Zhang1, Kun Li1, Yongqin Liu1, Mao Zhang1, Lijuan Yao1, Zengyun Jian1
Received:
2021-01-23
Revised:
2021-03-06
Accepted:
2021-03-23
Online:
2021-05-25
Published:
2021-05-25
Contact:
Man Zhu
About author:
Man Zhu, zhuman0428@126.comMan Zhu, Chi Zhang, Kun Li, Yongqin Liu, Mao Zhang, Lijuan Yao, Zengyun Jian. A Novel CoFe2NiMn0.3AlCux High-Entropy Alloy with Excellent Magnetic Properties and Good Mechanical Properties[J]. Acta Metallurgica Sinica (English Letters), 2021, 34(11): 1557-1564.
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Fig. 2 BSE images showing the microstructure of the CoFe2NiMn0.3AlCux (x = 0.25, 0.50, 0.75, and 1.00) HEAs: a, b x = 0.25, c, d x = 0.50, e, f) x = 0.75, and g, h x = 1.00
Alloys | Region | Co | Fe | Ni | Mn | Al | Cu |
---|---|---|---|---|---|---|---|
Cu0.25 | Nominal | 18.02 | 36.04 | 18.02 | 5.41 | 18.02 | 4.49 |
BCC phase | 18.52 | 34.23 | 18.18 | 5.96 | 18.45 | 4.66 | |
FCC phase | 17.06 | 31.14 | 17.62 | 6.25 | 20.66 | 7.27 | |
Cu0.50 | Nominal | 17.24 | 34.48 | 17.24 | 5.17 | 17.25 | 8.62 |
BCC phase | 16.83 | 30.86 | 17.28 | 5.84 | 20.54 | 8.65 | |
FCC phase | 17.36 | 32.14 | 17.49 | 5.88 | 18.66 | 8.47 | |
Cu0.75 | Nominal | 16.53 | 33.06 | 16.53 | 4.96 | 16.53 | 12.39 |
BCC phase | 17.33 | 32.75 | 16.10 | 5.36 | 17.98 | 10.48 | |
FCC phase | 14.67 | 27.80 | 17.36 | 6.37 | 16.49 | 17.31 | |
Cu1.00 | Nominal | 15.87 | 31.76 | 15.87 | 4.76 | 15.87 | 15.87 |
BCC phase | 15.91 | 30.58 | 14.84 | 5.04 | 19.87 | 13.76 | |
FCC phase | 13.09 | 24.40 | 15.56 | 6.00 | 15.99 | 24.96 |
Table 1 Nominal composition and EDS analyses of the different regions in the CoFe2NiMn0.3AlCux (x = 0.25, 0.50, 0.75, and 1.00) HEAs (at.%)
Alloys | Region | Co | Fe | Ni | Mn | Al | Cu |
---|---|---|---|---|---|---|---|
Cu0.25 | Nominal | 18.02 | 36.04 | 18.02 | 5.41 | 18.02 | 4.49 |
BCC phase | 18.52 | 34.23 | 18.18 | 5.96 | 18.45 | 4.66 | |
FCC phase | 17.06 | 31.14 | 17.62 | 6.25 | 20.66 | 7.27 | |
Cu0.50 | Nominal | 17.24 | 34.48 | 17.24 | 5.17 | 17.25 | 8.62 |
BCC phase | 16.83 | 30.86 | 17.28 | 5.84 | 20.54 | 8.65 | |
FCC phase | 17.36 | 32.14 | 17.49 | 5.88 | 18.66 | 8.47 | |
Cu0.75 | Nominal | 16.53 | 33.06 | 16.53 | 4.96 | 16.53 | 12.39 |
BCC phase | 17.33 | 32.75 | 16.10 | 5.36 | 17.98 | 10.48 | |
FCC phase | 14.67 | 27.80 | 17.36 | 6.37 | 16.49 | 17.31 | |
Cu1.00 | Nominal | 15.87 | 31.76 | 15.87 | 4.76 | 15.87 | 15.87 |
BCC phase | 15.91 | 30.58 | 14.84 | 5.04 | 19.87 | 13.76 | |
FCC phase | 13.09 | 24.40 | 15.56 | 6.00 | 15.99 | 24.96 |
Elements (Atomic radii) | Fe | Co | Ni | Mn | Al | Cu |
---|---|---|---|---|---|---|
Fe (0.1241 nm) | - | - 1 | - 2 | 0 | - 11 | + 13 |
Co (0.1251 mm) | - 1 | - | 0 | - 5 | - 19 | + 6 |
Ni (0.1246 nm) | - 2 | 0 | - | - 8 | - 22 | + 4 |
Mn (0.1350 nm) | 0 | - 5 | - 8 | - | - 19 | + 4 |
Al (0.1432 nm) | - 11 | - 19 | - 22 | - 19 | - | - 1 |
Cu (0.1278 nm) | + 13 | + 6 | + 4 | + 4 | - 1 | - |
Table 2 Enthalpy of mixing among the main constituents in the CoFe2NiMn0.3AlCux alloys (kJ mol-1)
Elements (Atomic radii) | Fe | Co | Ni | Mn | Al | Cu |
---|---|---|---|---|---|---|
Fe (0.1241 nm) | - | - 1 | - 2 | 0 | - 11 | + 13 |
Co (0.1251 mm) | - 1 | - | 0 | - 5 | - 19 | + 6 |
Ni (0.1246 nm) | - 2 | 0 | - | - 8 | - 22 | + 4 |
Mn (0.1350 nm) | 0 | - 5 | - 8 | - | - 19 | + 4 |
Al (0.1432 nm) | - 11 | - 19 | - 22 | - 19 | - | - 1 |
Cu (0.1278 nm) | + 13 | + 6 | + 4 | + 4 | - 1 | - |
Alloys | ΔHmix (kJ·mol-1) | ΔSmix (J·K-1·mol-1) | Ω | δ (%) | VEC |
---|---|---|---|---|---|
Cu0.25 | - 9.03 | 13.23 | 2.34 | 5.08 | 7.72 |
Cu0.50 | - 7.19 | 13.64 | 3.00 | 4.97 | 7.86 |
Cu0.75 | - 5.62 | 13.85 | 3.88 | 4.88 | 7.99 |
Cu1.00 | - 4.27 | 13.95 | 5.11 | 4.78 | 8.11 |
Table 3 Calculated values of ΔHmix, ΔSmix, Ω, δ, and VEC in the CoFe2NiMn0.3AlCux HEAs
Alloys | ΔHmix (kJ·mol-1) | ΔSmix (J·K-1·mol-1) | Ω | δ (%) | VEC |
---|---|---|---|---|---|
Cu0.25 | - 9.03 | 13.23 | 2.34 | 5.08 | 7.72 |
Cu0.50 | - 7.19 | 13.64 | 3.00 | 4.97 | 7.86 |
Cu0.75 | - 5.62 | 13.85 | 3.88 | 4.88 | 7.99 |
Cu1.00 | - 4.27 | 13.95 | 5.11 | 4.78 | 8.11 |
Alloys | σ0.2 (MPa) | σf (MPa) | εy (%) | HV |
---|---|---|---|---|
Cu0.25 | - | 675 | 4.58 | 647 |
Cu0.50 | - | 1058 | 6.04 | 637 |
Cu0.75 | - | 1811 | 9.15 | 595 |
Cu1.00 | 1048 | 1832 | 22.38 | 408 |
Table 4 Compression yield strength (σ0.2), fracture strength (σf), and fracture strain (εy) of the CoFe2NiMn0.3AlCux (x = 0.25, 0.50, 0.75, and 1.00) HEAs
Alloys | σ0.2 (MPa) | σf (MPa) | εy (%) | HV |
---|---|---|---|---|
Cu0.25 | - | 675 | 4.58 | 647 |
Cu0.50 | - | 1058 | 6.04 | 637 |
Cu0.75 | - | 1811 | 9.15 | 595 |
Cu1.00 | 1048 | 1832 | 22.38 | 408 |
Fig. 4 a-d Room-temperature magnetic hysteresis loop of the CoFe2NiMn0.3AlCux (x = 0.25, 0.50, 0.75, and 1.00) HEAs and e variation of Ms and Hc as a function of the Cu content
Alloys | Structure | Ms (emu/g) | Hc (Oe) | Ref. |
---|---|---|---|---|
CoFe2NiMn0.3AlCu0.25 | BCC + FCC | 130 | 182 | Present study |
CoFe2NiMn0.3AlCu0.50 | BCC + FCC | 122 | 158 | Present study |
CoFe2NiMn0.3AlCu0.75 | BCC + FCC | 112 | 103 | Present study |
CoFe2NiMn0.3AlCu1.00 | BCC + FCC | 74 | 40 | Present study |
FeCoNi | FCC | 151 | 1.52 | [ |
FeCoNiCr0.2Si0.2 | FCC | 98.11 | 2.36 | [ |
CoCuFeMnNi | FCC | 84 | 6 | [ |
CoCr2.0CuFeMnNi | BCC + FCC | 25 | 75 | [ |
AlCoCuFeNi0.5 | BCC + FCC + B2 | 89.21 | 7.3 | [ |
AlCoCrFeNi | BCC | 64.71 | 52 | [ |
AlCoCrFeNb0.25Ni | BCC + Laves | 34.69 | 94 | [ |
AlNiCoCuFe | BCC + FCC | 84 | 162 | [ |
Table 5 Comparison of magnetic properties for present CoFe2NiMn0.3AlCux HEAs and other HEAs reported in literature
Alloys | Structure | Ms (emu/g) | Hc (Oe) | Ref. |
---|---|---|---|---|
CoFe2NiMn0.3AlCu0.25 | BCC + FCC | 130 | 182 | Present study |
CoFe2NiMn0.3AlCu0.50 | BCC + FCC | 122 | 158 | Present study |
CoFe2NiMn0.3AlCu0.75 | BCC + FCC | 112 | 103 | Present study |
CoFe2NiMn0.3AlCu1.00 | BCC + FCC | 74 | 40 | Present study |
FeCoNi | FCC | 151 | 1.52 | [ |
FeCoNiCr0.2Si0.2 | FCC | 98.11 | 2.36 | [ |
CoCuFeMnNi | FCC | 84 | 6 | [ |
CoCr2.0CuFeMnNi | BCC + FCC | 25 | 75 | [ |
AlCoCuFeNi0.5 | BCC + FCC + B2 | 89.21 | 7.3 | [ |
AlCoCrFeNi | BCC | 64.71 | 52 | [ |
AlCoCrFeNb0.25Ni | BCC + Laves | 34.69 | 94 | [ |
AlNiCoCuFe | BCC + FCC | 84 | 162 | [ |
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