Acta Metallurgica Sinica (English Letters) ›› 2021, Vol. 34 ›› Issue (8): 1029-1041.DOI: 10.1007/s40195-021-01203-7
Shuai Zhang1, Bao-Chang Liu1, Mei-Xuan Li2, Hui-Yuan Wang2, Yin-Long Ma1,2()
Received:
2020-09-15
Revised:
2020-11-11
Accepted:
2020-11-17
Online:
2021-02-09
Published:
2021-08-10
Contact:
Yin-Long Ma
About author:
Yin-Long Ma, ylma@jlu.edu.cnShuai Zhang, Bao-Chang Liu, Mei-Xuan Li, Hui-Yuan Wang, Yin-Long Ma. Effect of Microstructures and Textures on Different Surfaces on Corrosion Behavior of an as-Extruded ATZ411 Magnesium Alloy Sheet[J]. Acta Metallurgica Sinica (English Letters), 2021, 34(8): 1029-1041.
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Specimens | Al | Sn | Zn | Mn | Fe | Cu | Ni | Mg |
---|---|---|---|---|---|---|---|---|
1 | 3.6612 | 0.8543 | 0.6832 | 0.4829 | 0.0014 | 0.002 | 0.0008 | Bal |
2 | 3.7252 | 0.8335 | 0.6387 | 0.4256 | 0.0023 | 0.0019 | 0.0007 | Bal |
3 | 3.695 | 0.8576 | 0.677 | 0.4845 | 0.0014 | 0.002 | 0.0007 | Bal |
Average | 3.6938 | 0.8485 | 0.6663 | 0.4644 | 0.0017 | 0.002 | 0.0007 | Bal |
Table 1 Chemical composition of the ATZ411 alloy sheets (wt%)
Specimens | Al | Sn | Zn | Mn | Fe | Cu | Ni | Mg |
---|---|---|---|---|---|---|---|---|
1 | 3.6612 | 0.8543 | 0.6832 | 0.4829 | 0.0014 | 0.002 | 0.0008 | Bal |
2 | 3.7252 | 0.8335 | 0.6387 | 0.4256 | 0.0023 | 0.0019 | 0.0007 | Bal |
3 | 3.695 | 0.8576 | 0.677 | 0.4845 | 0.0014 | 0.002 | 0.0007 | Bal |
Average | 3.6938 | 0.8485 | 0.6663 | 0.4644 | 0.0017 | 0.002 | 0.0007 | Bal |
Spectrum points | Chemical composition (at.%) | |||||
---|---|---|---|---|---|---|
Mg | Al | Mn | Zn | Sn | Others | |
1 | 25.90 ± 0.17 | 37.01 ± 0.21 | 18.56 ± 0.17 | / | / | 18.54 ± 0.26 |
2 | 0.69 ± 0.07 | 46.41 ± 0.28 | 46.01 ± 0.32 | 0.39 ± 0.10 | 0.11 ± 0.03 | 6.40 ± 0.18 |
3 | 75.56 ± 0.26 | 11.74 ± 0.16 | 2.17 ± 0.07 | / | 2.12 ± 0.04 | 8.41 ± 0.15 |
Table 2 EDS analysis of phases in Fig. 1(a-c
Spectrum points | Chemical composition (at.%) | |||||
---|---|---|---|---|---|---|
Mg | Al | Mn | Zn | Sn | Others | |
1 | 25.90 ± 0.17 | 37.01 ± 0.21 | 18.56 ± 0.17 | / | / | 18.54 ± 0.26 |
2 | 0.69 ± 0.07 | 46.41 ± 0.28 | 46.01 ± 0.32 | 0.39 ± 0.10 | 0.11 ± 0.03 | 6.40 ± 0.18 |
3 | 75.56 ± 0.26 | 11.74 ± 0.16 | 2.17 ± 0.07 | / | 2.12 ± 0.04 | 8.41 ± 0.15 |
Fig. 6 a Hydrogen evolution rates as a function of immersion time a, and b average mass loss rate of the EDS, NDS, and TDS specimens in 3.5 wt% NaCl at 25?±?1 °C
Specimens | Corrosion rate (mm/y) |
---|---|
EDS | 1.738 ± 0.018 |
NDS | 3.03 ± 0.029 |
TDS | 2.761 ± 0.026 |
Table 3 Converted annual corrosion rate (evaluated from the weight loss rate) for EDS, NDS, and TDS specimens in 3.5 wt% NaCl at 25?±?1 °C
Specimens | Corrosion rate (mm/y) |
---|---|
EDS | 1.738 ± 0.018 |
NDS | 3.03 ± 0.029 |
TDS | 2.761 ± 0.026 |
Fig. 9 a A schematic polarization curve of extruded ATZ411 alloys, b polarization curve of extruded ATZ411 alloys after immersion in 3.5 wt% NaCl at 25?±?1 °C
Specimens | Ecorr (VSCE) | Icorr (μA·cm-2) | βC (mV·dec-1) |
---|---|---|---|
EDS | - 1.551 ± 0.001 | 61.37 ± 2.89 | - 155.4 ± 0.63 |
TDS | - 1.529 ± 0.003 | 95.28 ± 1.78 | - 172.9 ± 0.12 |
NDS | - 1.547 ± 0.001 | 133.35 ± 2.94 | - 203.6 ± 0.30 |
Table 4 Values of E corr, I corr and βC extracted from the polarization curves of EDS, TDS, and NDS in 3.5 wt% NaCl at 25?±?1 °C
Specimens | Ecorr (VSCE) | Icorr (μA·cm-2) | βC (mV·dec-1) |
---|---|---|---|
EDS | - 1.551 ± 0.001 | 61.37 ± 2.89 | - 155.4 ± 0.63 |
TDS | - 1.529 ± 0.003 | 95.28 ± 1.78 | - 172.9 ± 0.12 |
NDS | - 1.547 ± 0.001 | 133.35 ± 2.94 | - 203.6 ± 0.30 |
Specimens | RS (Ω cm2) | Qdl (S secn cm-2) | n | Rt (Ω cm2) | RL Mg+ (Ω cm2) | LMg+ (H cm-2) |
---|---|---|---|---|---|---|
EDS | 10.15 | 1.906E-5 | 0.811 | 957.6 | 1566.0 | 705.0 |
TDS | 10.35 | 1.416E-5 | 0.899 | 597.1 | 789.9 | 217.1 |
NDS | 14.34 | 1.520E-5 | 0.879 | 418.2 | 737.1 | 192.1 |
Table 5 Fitting results for EIS in 3.5 wt% NaCl at 25?±?1 °C
Specimens | RS (Ω cm2) | Qdl (S secn cm-2) | n | Rt (Ω cm2) | RL Mg+ (Ω cm2) | LMg+ (H cm-2) |
---|---|---|---|---|---|---|
EDS | 10.15 | 1.906E-5 | 0.811 | 957.6 | 1566.0 | 705.0 |
TDS | 10.35 | 1.416E-5 | 0.899 | 597.1 | 789.9 | 217.1 |
NDS | 14.34 | 1.520E-5 | 0.879 | 418.2 | 737.1 | 192.1 |
Fig. 12 Typical corrosion morphologies of the NDS surface of the grain boundary was exposed in advance after immersion testing for 1 h in 3.5 wt% NaCl at 25?±?1 °C
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