Acta Metallurgica Sinica (English Letters) ›› 2022, Vol. 35 ›› Issue (10): 1617-1630.DOI: 10.1007/s40195-022-01394-7

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High-temperature Mechanical Properties and Dynamic Recrystallization Mechanism of in situ Silicide-reinforced MoNbTaTiVSi Refractory High-entropy Alloy Composite

Shaofan Ge1,2, Shifeng Lin1, Huameng Fu1,3,4(), Long Zhang1, Tieqiang Geng1, Zhengwang Zhu1,3,4, Zhengkun Li1,3, Hong Li1,3(), Aimin Wang1,3,4, Hongwei Zhang1,3,4, Haifeng Zhang1,3,4   

  1. 1Shi-Changxu Innovation Center for Advanced Materials, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
    2School of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026, China
    3CAS Key Laboratory of Nuclear Materials and Safety Assessment, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
    4Dongguan Eontec Co., Ltd, Dongguan 523662, China
  • Received:2021-11-05 Revised:2021-12-10 Accepted:2021-12-27 Online:2022-04-09 Published:2022-04-09
  • Contact: Huameng Fu,Hong Li
  • About author:Hong Li, lihong@imr.ac.cn
    Huameng Fu, hmfu@imr.ac.cn;

Abstract:

The hypoeutectic composite material composed of BCC phase and in situ precipitated Ti5Si3 was prepared by adding Si into MoNbTaTiV high-entropy alloy. The obvious oriented in situ Ti5Si3 phase formed eutectic phase with BCC phase in the inter-dendritic area, which leads to excellent properties of the composite. The alloy exhibits ultra-high yield stress of 718 MPa at 1200 °C and obvious compression plasticity. After reaching the maximum strength, dynamic recovery (DRV) and dynamic recrystallization (DRX) caused soften phenomena. The DRX mechanism of the dual-phase eutectic structure is analyzed by electron backscatter diffraction. The DRX of the BCC phase conforms to the discontinuous DRX and continuous DRX mechanisms, while the Ti5Si3 phase has a geometric DRX mechanism in addition to the above two mechanisms. The high performance of this composite has enough potential high-temperature applications such as nuclear and aero engine.

Key words: Refractory high-entropy alloy composite, Mechanical properties, In situ silicide compound, Dynamic recrystallization