Acta Metallurgica Sinica (English Letters) ›› 2022, Vol. 35 ›› Issue (8): 1301-1316.DOI: 10.1007/s40195-021-01368-1
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Xiong Zhou1, Qichi Le1(), Chenglu Hu1, Ruizhen Guo1, Tong Wang1, Chunming Liu2, Dandan Li1, Xiaoqiang Li1
Received:
2021-09-13
Revised:
2021-10-14
Accepted:
2021-10-30
Online:
2022-01-05
Published:
2022-01-05
Contact:
Qichi Le
About author:
Qichi Le qichil@mail.neu.edu.cnXiong Zhou, Qichi Le, Chenglu Hu, Ruizhen Guo, Tong Wang, Chunming Liu, Dandan Li, Xiaoqiang Li. Mechanical Properties and Corrosion Behavior of Multi-Microalloying Mg Alloys Prepared by Adding AlCoCrFeNi Alloy[J]. Acta Metallurgica Sinica (English Letters), 2022, 35(8): 1301-1316.
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Code of alloys | Al | Co | Cr | Fe | Ni | Mg |
---|---|---|---|---|---|---|
Pure Mg | 0.013 | 0.0002 | 0.0003 | 0.0023 | 0.0004 | Bal. |
Mg-1 HEA | 0.045 | 0.083 | 0.042 | 0.063 | 0.2 | Bal. |
Mg-3 HEA | 0.05 | 0.095 | 0.018 | 0.15 | 0.51 | Bal. |
Table 1 Chemical composition of the as-cast Mg-x HEA (x?=?0, 1, 3) alloys (wt%)
Code of alloys | Al | Co | Cr | Fe | Ni | Mg |
---|---|---|---|---|---|---|
Pure Mg | 0.013 | 0.0002 | 0.0003 | 0.0023 | 0.0004 | Bal. |
Mg-1 HEA | 0.045 | 0.083 | 0.042 | 0.063 | 0.2 | Bal. |
Mg-3 HEA | 0.05 | 0.095 | 0.018 | 0.15 | 0.51 | Bal. |
Fig. 3 OM images and corresponding grain size distribution maps (Ave. represents the average grain size) of the extruded Mg-x HEA alloys: a, d x?=?0, b, e x?=?1, c, f x?=?3
Fig. 5 SEM micrographs and EDS analysis of the extruded alloys: a pure Mg, b Mg-1 HEA, c Mg-3 HEA, d, e corresponding to the EDS spectra of Point A and Point B in b, c, respectively, f Magnification morphology of c and elemental mappings are shown
Alloy | Tensile | Compressive | ||||
---|---|---|---|---|---|---|
TYS (MPa) | UTS (MPa) | Fracture strain (δ) | CYS (MPa) | UCS (MPa) | Fracture strain (δ) | |
Pure Mg | 93 ± 2 | 159 ± 4 | 14.1 ± 1 | 72 ± 2 | 298 ± 5 | 17.5 ± 0.3 |
Mg-1HEA | 165 ± 5 | 217 ± 7 | 14.7 ± 1.3 | 89 ± 9 | 363 ± 10 | 15.5 ± 1.2 |
Mg-3HEA | 183 ± 4 | 237 ± 3 | 13.9 ± 1.1 | 103 ± 2 | 392 ± 3 | 14.6 ± 0.9 |
Table 2 Tensile and compressive properties of extruded Mg-x HEA (x?=?0, 1, 3) alloys
Alloy | Tensile | Compressive | ||||
---|---|---|---|---|---|---|
TYS (MPa) | UTS (MPa) | Fracture strain (δ) | CYS (MPa) | UCS (MPa) | Fracture strain (δ) | |
Pure Mg | 93 ± 2 | 159 ± 4 | 14.1 ± 1 | 72 ± 2 | 298 ± 5 | 17.5 ± 0.3 |
Mg-1HEA | 165 ± 5 | 217 ± 7 | 14.7 ± 1.3 | 89 ± 9 | 363 ± 10 | 15.5 ± 1.2 |
Mg-3HEA | 183 ± 4 | 237 ± 3 | 13.9 ± 1.1 | 103 ± 2 | 392 ± 3 | 14.6 ± 0.9 |
Materials | | | | |
---|---|---|---|---|
Pure Mg | - 1.704 | 0.02 | 12.6 | 0.46 |
Mg-1 HEA | - 1.403 | 5.75 | 766.1 | 131.39 |
Mg-3 HEA | - 1.352 | 6.21 | 1270.1 | 141.90 |
Table 3 Corrosion potential ($E_{{{\rm{corr}}}}$) and self-corrosion current density ($i_{{{\rm{corr}}}}$) obtained from polarization curves of Mg-x HEA (x?=?0, 1, 3) alloys in 3.5 wt% NaCl solution
Materials | | | | |
---|---|---|---|---|
Pure Mg | - 1.704 | 0.02 | 12.6 | 0.46 |
Mg-1 HEA | - 1.403 | 5.75 | 766.1 | 131.39 |
Mg-3 HEA | - 1.352 | 6.21 | 1270.1 | 141.90 |
Fig. 12 EIS plots of the experimental alloys in 3.5 wt% NaCl solution: a Nyquist plots; b, c Bode plots of impedance modulus vs. frequency and phase angle vs. frequency, respectively
Alloys | RS (Ω cm2) | Rt (Ω cm2) | CPEdl (sn Ω-1 cm-2) | n1 | Rf (Ω cm2) | CPEf (sn Ω-1 cm-2) | n2 | RL (Ω cm2) | L (H cm2) | χ2 |
---|---|---|---|---|---|---|---|---|---|---|
Pure Mg | 4.04 | 5.86 | 2.04 × 10-5 | 0.928 | 112.31 | 5.57 × 10-5 | 0.953 | - | - | 6.477 × 10-4 |
Mg-1 HEA | 4.20 | 3.45 | 24.82 × 10-5 | 0.856 | 1.27 | 51.36 × 10-5 | 0.832 | 22.93 | 37.3 | 4.275 × 10-4 |
Mg-3 HEA | 4.63 | 0.83 | 34.42 × 10-5 | 0.823 | 1.18 | 77.94 × 10-5 | 0.801 | 19.33 | 69.2 | 9.466 × 10-5 |
Table 4 Equivalent circuit parameters obtained by fitting the EIS data
Alloys | RS (Ω cm2) | Rt (Ω cm2) | CPEdl (sn Ω-1 cm-2) | n1 | Rf (Ω cm2) | CPEf (sn Ω-1 cm-2) | n2 | RL (Ω cm2) | L (H cm2) | χ2 |
---|---|---|---|---|---|---|---|---|---|---|
Pure Mg | 4.04 | 5.86 | 2.04 × 10-5 | 0.928 | 112.31 | 5.57 × 10-5 | 0.953 | - | - | 6.477 × 10-4 |
Mg-1 HEA | 4.20 | 3.45 | 24.82 × 10-5 | 0.856 | 1.27 | 51.36 × 10-5 | 0.832 | 22.93 | 37.3 | 4.275 × 10-4 |
Mg-3 HEA | 4.63 | 0.83 | 34.42 × 10-5 | 0.823 | 1.18 | 77.94 × 10-5 | 0.801 | 19.33 | 69.2 | 9.466 × 10-5 |
Fig. 14 SEM morphologies of the extruded alloys after immersion in 3.5 wt% NaCl solution for 1, 5 and 10 min: a, d, g pure Mg, b, e, h Mg-1 HEA, c, f, i Mg-3 HEA, j Mg-1 HEA alloy without corrosion products, k Mg-3 HEA alloy without corrosion products, l EDS analysis of the corrosion products (Point A)
[1] | X. Liang, J.H. Zhu, X.Z. Shi, J.C. Zhang, C. Liu, F. He, R. Li, Nat. Gas Ind. B 4, 134 (2017) |
[2] |
B.C. Yao, Q.X. Ding, Y. Hou, S.H. Liu, S.M. Zhang, J. Nat. Gas Sci. Eng. 50, 11 (2018)
DOI URL |
[3] |
B.S. Liu, Y.X. Yang, Y.Z. Zhang, H.Y. Du, L.F. Hou, Y.H. Wei, J. Phys. Chem. Solids 144, 109499 (2020)
DOI URL |
[4] |
J.F. Wang, S.Q. Gao, X.Y. Liu, X. Peng, K. Wang, S.J. Liu, W.Y. Jiang, S.F. Guo, F.S. Pan, J. Magnes. Alloy. 8, 127 (2020)
DOI URL |
[5] |
H.Y. Niu, K.K. Deng, K.B. Nie, C.J. Wang, W. Liang, Y.C. Wu, Mater. Chem. Phys. 249, 123131 (2020)
DOI URL |
[6] |
G.L. Song, A. Atrens, Adv. Eng. Mater. 1, 11 (2010)
DOI URL |
[7] | C. Zhang, L. Wu, G.S. Huang, L. Chen, D.B. Xia, B. Jiang, A. Atrens, F. Pan, J. Mater. Sci. Technol. 35, 2086 (2019) |
[8] |
Z.W. Geng, D.H. Xiao, L. Chen, J. Alloys Compd. 686, 145 (2016)
DOI URL |
[9] |
J. Wang, T. Li, H.X. Li, Y.Z. Ma, K.N. Zhao, C.L. Yang, J.S. Zhang, J. Magnes. Alloy. 9, 1632 (2021)
DOI URL |
[10] | T. Li, X.T. Wang, S.Q. Tang, Y.S. Yang, J.H. Wu, Rare Met. 40, 2206 (2021) |
[11] |
M.L. Wang, H.Z. Cui, Y.Q. Zhao, C.M. Wang, N. Wei, Y. Zhao, X. Zhang, Q. Song, Mater. Des. 180, 107893 (2019)
DOI URL |
[12] |
M.L. Wang, Y.P. Lu, G.J. Zhang, H.Z. Cui, D.F. Xu, N. Wei, T.J. Li, Vacuum. 184, 109905 (2021)
DOI URL |
[13] |
M.L. Wang, Y.P. Lu, T.M. Wang, C. Zhang, Z.Q. Cao, T.J. Li, P.K. Liaw, Scr. Mater. 204, 114132 (2021)
DOI URL |
[14] |
N.I. Zainal Abidin, A.D. Atrens, D. Martin, A. Atrens, Corros. Sci. 53, 3542 (2011)
DOI URL |
[15] |
F.Y. Cao, Z.M. Shi, G.L. Song, M. Liu, A. Atrens, Corros. Sci. 76, 60 (2013)
DOI URL |
[16] |
F.Y. Cao, Z.M. Shi, J. Hofstetter, P.J. Uggowitzer, G.L. Song, M. Liu, A. Atrens, Corros. Sci. 75, 78 (2013)
DOI URL |
[17] | Z.P. Liu, P.J. Li, L.T. Xiong, T.Y. Liu, L.J. He, Mater. Sci. Eng. A 680, 259 (2017) |
[18] |
L.Z. Liu, F.S. Pan, X.H. Chen, Y.D. Huang, B. Song, H. Yang, N. Hort, Vacuum. 155, 445 (2018)
DOI URL |
[19] | X.R. Chen, Y.H. Jia, Q.C. Le, H.N. Wang, X. Zhou, F.X. Yu, A. Atrens, J. Magnes. Alloy. (2020). https://doi.org/10.1016/j.jma.2020.07.008 |
[20] |
L. Bao, Z.Q. Zhang, Q.C. Le, S.R.L. Zhang, J.Z. Cui, J. Alloys Compd. 712, 15 (2017)
DOI URL |
[21] |
S.Q. Yin, W.C. Duan, W.H. Liu, L. Wu, J.X. Bao, J.M. Yu, L. Li, Z. Zhao, J.Z. Cui, Z.Q. Zhang, Corros. Sci. 177, 108962 (2020)
DOI URL |
[22] |
G.L. Song, R. Mishra, Z. Xu, Electrochem. Commun. 12, 1009 (2010)
DOI URL |
[23] |
X. Liu, J.L. Xue, P.J. Zhang, Z.J. Wang, J. Power Sourc. 414, 174 (2019)
DOI URL |
[24] |
X. Liu, J.L. Xue, S.H. Liu, Mater. Des. 160, 138 (2018)
DOI URL |
[25] |
P.L. Jiang, C. Blawert, R. Hou, N. Scharnagl, J. Bohlen, M.L. Zheludkevich, J. Alloys Compd. 783, 179 (2019)
DOI URL |
[26] |
P.L. Jiang, C. Blawert, N. Scharnagl, M.L. Zheludkevich, Corros. Sci. 153, 62 (2019)
DOI URL |
[27] | M. Franco, T. Hari Krishna, A.M. Pillai, A. Rajendra, A.K. Sharma, Acta Metall. Sin. -Engl. Lett. 26, 647 (2013) |
[28] |
F.Y. Cao, G.L. Song, A. Atrens, Corros. Sci. 111, 835 (2016)
DOI URL |
[29] |
S. Peng, S.K. Xie, F. Xiao, J.T. Lu, Corros. Sci. 163, 108237 (2020)
DOI URL |
[30] |
G.L. Song, A. Atrens, Adv. Eng. Mater. 5, 837 (2003)
DOI URL |
[31] |
C. Zhang, L. Wu, G.S. Huang, Y. Huang, B. Jiang, A. Atrens, F.S. Pan, J. Alloys Compd. 823, 153844 (2020)
DOI URL |
[32] | G. Zhang, L. Wu, A.T. Tang, H.L. Pan, Y.L. Ma, Q. Zhan, Q.Y. Tan, F.S. Pan, A. Atrens. J. Electrochem. Soc. 165, C317 (2018) |
[33] | B.M. Praveen, T.V. Venkatesha, Int. J. Electrochem. Sci. 4, 267 (2009) |
[34] |
Q.Y. Huang, Y. Liu, M. Tong, H.C. Pan, C.L. Yang, T.J. Luo, Y.S. Yang, Vacuum. 177, 109356 (2020)
DOI URL |
[35] | Z.T. Li, X.D. Zhang, M.Y. Zheng, X.G. Qiao, K. Wu, C. Xu, S. Kamado, Mater. Sci. Eng. A 682, 423 (2017) |
[36] |
F. Wang, R.X. Zheng, J. Chen, S.Y. Lyu, Y. Li, W.L. Xiao, C.L. Ma, Vacuum. 161, 429 (2019)
DOI URL |
[37] | Z. Zhang, D.L. Chen, Mater. Sci. Eng. A 483-484, 148 (2008) |
[38] |
P. Luo, D.T. McDonald, W. Xu, S. Palanisamy, M.S. Dargusch, K. Xia, Scr. Mater. 66, 785 (2012)
DOI URL |
[39] | E.O. Hall, Proc. Phys. Soc., London, Sect. B. 64, 495 (2002) |
[40] | N.J. Petch, J. Iron Steel Inst. Lond. 173, 25 (1953) |
[41] |
C.S. Kim, I. Sohn, M. Nezafati, J.B. Ferguson, B.F. Schultz, Z. Bajestani-Gohari, P.K. Rohatgi, K. Cho, J. Mater. Sci. 48, 4191 (2013)
DOI URL |
[42] | H.Y. Wang, E.S. Xue, W. Xiao, Z. Liu, J.B. Li, Q.C. Jiang, Mater. Sci. Eng. A 528, 8790 (2011) |
[43] | H. Okamoto Desk Hand Book. 315, (2000). |
[44] |
D.B. Xia, X. Chen, G.S. Huang, B. Jiang, A.T. Tang, H. Yang, S. Gavras, Y.D. Huang, N. Hort, F.S. Pan, Scr. Mater. 171, 31 (2019)
DOI URL |
[45] |
X.Q. Li, Q.C. Le, X. Zhou, C.L. Cheng, Y. Cao, X.R. Chen, P. Wang, L. Ren, D.D. Li, Composites, Part B 216, 108866 (2021)
DOI URL |
[46] |
J.S. Zhang, J.D. Xu, W.L. Cheng, C.J. Chen, J.J. Kang, J. Mater. Sci. Technol. 28, 1157 (2012)
DOI URL |
[47] |
A. Srinivasan, C. Blawert, Y. Huang, C.L. Mendis, K.U. Kainer, N. Hort, J. Magnes. Alloy. 2, 245 (2014)
DOI URL |
[48] |
X.B. Zhang, Z.X. Ba, Z.Z. Wang, Y.J. Wu, Y.J. Xue, Mater. Lett. 163, 250 (2016)
DOI URL |
[49] | T. Zhang, Y.W. Shao, G.Z. Meng, Z.Y. Cui, F.H. Wang, Corros. Sci. 53, 1960 (2011) |
[50] |
L. Liu, Y. Li, F.H. Wang, Electrochim. Acta. 54, 768 (2008)
DOI URL |
[51] |
B. Jiang, Q. Xiang, A. Atrens, J.F. Song, F.S. Pan, Corros. Sci. 126, 374 (2017)
DOI URL |
[52] |
U. König, B. Davepon, Electrochim. Acta 47, 149 (2001)
DOI URL |
[53] | S. Bahl, S. Suwas, K. Chatterjee,RSC Adv 4, 55677 (2014) |
[54] |
G.L. Song, A. Atrens, X.L. Wu, B. Zhang, Corros. Sci. 40, 1769 (1998)
DOI URL |
[55] | H.G. Liu, F.Y. Cao, G.L. Song, D.J. Zheng, Z.M. Shi, M.S. Dargusch, A. Atrens, J. Mater. Sci. Technol. 35, 2003 (2019) |
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