Acta Metallurgica Sinica (English Letters) ›› 2021, Vol. 34 ›› Issue (11): 1537-1545.DOI: 10.1007/s40195-021-01255-9
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Chuang-Shi Feng1,2, Tian-Wei Lu1,3, Tian-Li Wang1,2, Man-Zhen Lin1, Junhua Hou4, Wenjun Lu4, Wei-Bing Liao1()
Received:
2021-01-20
Revised:
2021-03-29
Accepted:
2021-04-02
Online:
2021-05-26
Published:
2021-05-26
Contact:
Wei-Bing Liao
About author:
Wei-Bing Liao, liaowb@szu.edu.cnChuang-Shi Feng, Tian-Wei Lu, Tian-Li Wang, Man-Zhen Lin, Junhua Hou, Wenjun Lu, Wei-Bing Liao. A Novel High-Entropy Amorphous Thin Film with High Electrical Resistivity and Outstanding Corrosion Resistance[J]. Acta Metallurgica Sinica (English Letters), 2021, 34(11): 1537-1545.
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Fig. 1 a Typical top surface morphologies, the corresponding inset shows several nano-sized granules on the top surface and b cross-section view by SEM; c 2D surface nanostructure by AFM; d 3D surface topography corresponding to (c)
Samples | D (nm) | Ra (nm) | ρ (μΩ cm) | Structure |
---|---|---|---|---|
This study | 191.88 | 0.426 ± 0.143 | 320.6 | Amorphous |
W | 5-11 | - | 182-225 | β-phase |
NbMoTaW | 350 | - | 168 | BCC |
CoCrFeNi | 1982 | 1.91 | 135.1 | FCC |
Table 1 Related performance parameters of the thin film
Samples | D (nm) | Ra (nm) | ρ (μΩ cm) | Structure |
---|---|---|---|---|
This study | 191.88 | 0.426 ± 0.143 | 320.6 | Amorphous |
W | 5-11 | - | 182-225 | β-phase |
NbMoTaW | 350 | - | 168 | BCC |
CoCrFeNi | 1982 | 1.91 | 135.1 | FCC |
Fig. 2 a Elemental contents of all the contained elements in the thin films, granules and the target (at.%); b XRD pattern of the thin film; c TEM image of the film at low magnification, inset showing the corresponding SAED pattern; d HRTEM image of the film, showing an amorphous structure
Fig. 3 a OCP diagrams of the thin film and 316L stainless steel; b dynamic polarization curves of the WNbMoTaV HETF and 316L stainless steel; c SEM surface morphology of the thin film after corrosion
Samples | Eoc (V) | Ec (V) | Ic (μA/cm2) | Ep (V) | Ip (μA/cm2) |
---|---|---|---|---|---|
HETF | 0.252 | - 0.225 | 0.088 | - | - |
316L | - 0.076 | - 0.263 | 0.101 | 0.361 | 1.903 |
Table 2 Experimental data of electrochemical tests for the HETF and 316L stainless steel in 3.5 wt% NaCl solution with a scanning rate of 1 mV/s
Samples | Eoc (V) | Ec (V) | Ic (μA/cm2) | Ep (V) | Ip (μA/cm2) |
---|---|---|---|---|---|
HETF | 0.252 | - 0.225 | 0.088 | - | - |
316L | - 0.076 | - 0.263 | 0.101 | 0.361 | 1.903 |
Fig. 4 High resolution XPS spectra of the corrosion products of as-deposited thin film as comparison: a full scan of spectrum; b W-4f; c Nb-3d; d Mo-3d; e Ta-4f; f V-2p; g O-1 s
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