A Comparative Study on the Corrosion Performance of Ni47Ti49Co4 and Ni51Ti49 Shape Memory Alloys in Simulated Saliva Solution for Dental Applications

doi:10.1007/s40195-016-0463-5

Abstract

Abstract:

In this study, the corrosion behavior of Ni₄₇Ti₄₉Co₄ shape memory alloy (SMA) was investigated in simulated saliva solution with the binary alloy Ni₅₁Ti₄₉ as a reference. The surface morphology and the chemical composition of the oxide films were characterized by scanning electron microscopy and X-ray photoelectron spectroscopy before and after immersion in the test solutions, respectively. The results showed that the ternary alloy was less affected by the test solution, owning to the formation of passive layer composed mainly of the oxides of titanium and cobalt in several oxidation states. Cyclic voltammetry, electrochemical impedance spectroscopy and potentiodynamic polarization measurements affirmed that the passive oxide film significantly improved the corrosion resistance of Ni₄₇Ti₄₉Co₄ SMAs as demonstrated by the smaller corrosion current density, larger resistance and smaller capacitance. Consequently, alloying with cobalt, which has paramount importance in enhancing the passive layer, expands the use of Ni₄₇Ti₄₉Co₄ SMAs in dental work as new nitinol alloys with high corrosion resistances.

Key words: Ni₄₇Ti₄₉Co₄, Shape memory alloy (SMA), Corrosion, Artificial saliva, X-ray photoelectron spectroscopy (XPS)

Rasha A. Ahmed. A Comparative Study on the Corrosion Performance of Ni₄₇Ti₄₉Co₄ and Ni₅₁Ti₄₉ Shape Memory Alloys in Simulated Saliva Solution for Dental Applications[J]. Acta Metallurgica Sinica (English Letters), 2016, 29(11): 1001-1010.

Figures/Tables 10

Fig. 1 SEM micrographs of surface morphology: Ni51Ti49a and Ni47Ti49Co4b SMAs before immersion in artificial saliva solution; Ni51Ti49c, e and Ni47Ti49Co4d, f SMAs after immersion in artificial saliva solution for 14 days with different magnifications

Fig. 2 XPS survey spectra: Ni51Ti49a and Ni47Ti49Co4b SMAs before immersion in artificial saliva solution; Ni51Ti49c and Ni47Ti49Co4d SMAs after immersion in artificial saliva solution

Fig. 3 Cyclic voltammograms: Ni51Ti49a and Ni47Ti49Co4b SMAs in artificial saliva at 37 ± 1 °C and scan rate of 10 mV s-1

Fig. 4 Experimental data in artificial saliva solution with immersion time till 15 h at 37 ± 1 °C: Nyquist plots a, b; Bode plot c, d for Ni51Ti49 and Ni47Ti49Co4 SMAs, respectively

Fig. 5 Experimental data in artificial saliva solution with immersion time till 168 h at 37 ± 1 °C: Nyquist plots a, c and Bode plot b, d of Ni51Ti49 a and Ni47Ti49Co4 b SMAs, respectively

Fig. 6 Proposed equivalent circuit: Ni51Ti49a and Ni47Ti49Co4b SMAs used to obtain impedance parameters

Fig. 7 Potentiodynamic polarization curves: Ni51Ti49a and Ni47Ti49Co4b SMAs in artificial saliva solution at 37 ± 1 °C showing positive corrosion behavior for Ni47Ti49Co4

Fig. 8 Current density versus time curves: Ni51Ti49a and Ni47Ti49Co4b SMAs in artificial saliva solution at 37 ± 1 °C

References

[1]	Y. Fu, H. Du, W. Huang, S. Zhang, M. Hu, Sens. Actu. A-Phys. 112, 395(2004)
[2]	Y.Y. Su, V. Raman, Wire J. Int. 31, 106(1998)
[3]	S.A. Shabalovskaya, Biomed. Mater. Eng. 12, 69(2002)
[4]	X. Zhang, Y. Zhang, Chin. J. Mater. Res. 21, 561(2007)
[5]	F. Geng, P. Shi, D.Z. Yang, J. Funct. Mater. 36, 11(2005)
[6]	X. Zhao, L. Ma, Y. Yao, Y. Ding, X. Shen, Energy Environ. Sci. 3, 1316(2010)
[7]	K.W. Yeung, R.W. Poon, P.K. Chu, C.Y. Chung, X.Y. Liu, W.W. Lu, D. Chan, S.C. Chan, K.D. Luk, K.M. Cheung, J. Biomed. Mater. Res. A 82, 403 (2007)
[8]	M.H. Elahinia, M. Hashemi, M. Tabesh, S.B. Bhaduri, Prog. Mater Sci. 57, 911(2012)
[9]	K. Otsuka, X. Ren, Prog. Mater Sci. 50, 511(2005)
[10]	F. El Feninat, G. Laroche, M. Fiset, D. Mantovani, Adv. Eng. Mater. 4, 91(2002)
[11]	D. Mantovani, JOM 52, 36 (2000)
[12]	A.M. Maurer, K. Merritt, S.A. Brown, J. Biomed. Mater. Res. 28, 241(1994)
[13]	P. Locci, E. Becchetti, M. Pugliese, L. Rossi, C. Lilli, M. Calvitti, N. Staffolani, J. Periodont 67, 1260 (1996)
[14]	M.G. Bergcr, B. Broxup, C.H. Rivard, L.H. Yahia, J. Biomed. Mater. Res. 32, 243(1996)
[15]	A. Pequegnat, A. Michael, J. Wang, K. Lian, Y. Zhou, M.I. Khan, Mater. Sci. Eng.,C 50, 367 (2015)
[16]	X. Liua, P.K. Chub, C. Dinga, R 47, 49 (2004)
[17]	Z.H. Huang, Intermetallics 16, 727 (2008)
[18]	G.N. Jenkins, The physiology and biochemistry of the mouth. (Blackwell Scientific Publications, Oxford Press, Oxford, 1978)
[19]	H. Hsiung, H.T. Lee, Dent. Mater. 21, 749(2005)
[20]	Y. Li, C. Yang, H. Zhao, S. Qu, X. Li, Y. Li, Mater. 7, 1709(2014)
[21]	R. Bhola, S.M. Bhola, B. Mishra, D.L. Olson, Tren. Biomater. Artif. Organs 25, 34 (2011)
[22]	J.C.M. J. Bio. Tribo. Corros. 2, 1(2015)
[23]	K. Ide, M. Hattori, M. Yoshinari, E. Kawada, Y. Oda, Dent. Mater. J. 22, 359(2003)
[24]	K. Nomura, H. Ohta, A. Takagi, T. Kamiya, M. Hirano, H. Hosono, Nature 432, 488 (2004)
[25]	R.A. Ahmed, Ind. Eng. Chem. Res. 54, 8397(2015)
[26]	J. Geis-Gerstorfer, H. Weber, Dtsch Zahna¨rztl Z 40, 87 (1985)
[27]	A. Fasching, D. Norwich, T. Geiser, G.W. Paul, J. Mater. Eng. Perform. 20, 641(2011)
[28]	Q.Y. Wang, Y.F. Zheng, Dent. Mater. 24, 1207(2008)
[29]	A.C. Guyton, J.E. Hall, Philadelphia, 2006)
[30]	S.M. Green, D.M. Grant, J.V. Wood, A 224, 21 (1997)
[31]	H. Chen, L.F. Hu, M. Chen, Y. Yan, L.M. Wu, Adv. Funct. Mater. 24, 934(2014)
[32]	R. Oltra, M. Keddam, Electrochim. Acta 35, 1619 (1990)
[33]	N. Elbagoury, Mater. Sci. Technol. 30, 1795(2014)
[34]	X. Huang, D.W. Norwich, M. Ehrlinspiel, J. Mater. Eng. Perform. 23, 2630(2014)
[35]	J.R. Macdonald, Impedance spectroscopy: Emphasizing solid materials and systems. (Wiley, New York, 1987), p. 60
[36]	Z. Lukacs, J. Electroanal. Chem. 464, 68(1999)
[37]	S.H. Chang, W.C. Chiu, Appl. Surf. Sci. 324, 106(2015)
[38]	C. Fei, J. Chuanhai, Z. Zhongquan, M. Enzo, F. Peng, Z. Yuantao, J. Vincent, J. Alloys Compd. 635, 73(2015)
[39]	S.N. Saud, E. Hamzah, T. Abubakr, H.R. Bakhseshi, Trans. Nonferrous Met. Soc. China 25, 1158 (2015)

A Comparative Study on the Corrosion Performance of Ni₄₇Ti₄₉Co₄ and Ni₅₁Ti₄₉ Shape Memory Alloys in Simulated Saliva Solution for Dental Applications

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 10

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Ping Deng, En-Hou Han, Qunjia Peng, Chen Sun. Corrosion Behavior and Mechanism of Irradiated 304 Nuclear Grade Stainless Steel in High-Temperature Water [J]. Acta Metallurgica Sinica (English Letters), 2021, 34(2): 174-186.
[2]	Baojie Wang, Daokui Xu, Tianyu Zhao, Liyuan Sheng. Effect of CaCl₂ and NaHCO₃ in Physiological Saline Solution on the Corrosion Behavior of an As-Extruded Mg-Zn-Y-Nd alloy [J]. Acta Metallurgica Sinica (English Letters), 2021, 34(2): 239-247.
[3]	Jiaqi Hu, Qite Li, Hong Gao. Influence of Twinning Texture on the Corrosion Fatigue Behavior of Extruded Magnesium Alloys [J]. Acta Metallurgica Sinica (English Letters), 2021, 34(1): 65-76.
[4]	Zheng-Zheng Yin, Zhao-Qi Zhang, Xiu-Juan Tian, Zhen-Lin Wang, Rong-Chang Zeng. Corrosion Resistance and Durability of Superhydrophobic Coating on AZ31 Mg Alloy via One-Step Electrodeposition [J]. Acta Metallurgica Sinica (English Letters), 2021, 34(1): 25-38.
[5]	Dong-Dong Gu, Jian Peng, Jia-Wen Wang, Zheng-Tao Liu, Fu-Sheng Pan. Effect of Mn Modification on the Corrosion Susceptibility of Mg-Mn Alloys by Magnesium Scrap [J]. Acta Metallurgica Sinica (English Letters), 2021, 34(1): 1-11.
[6]	Yuanyuan Liu, Zhongmin Lang, Jinlong Cui, Shengli An. Performance of Nb_0.8Zr_0.2 Layer-Modified AISI430 Stainless Steel as Bipolar Plates for Direct Formic Acid Fuel Cells [J]. Acta Metallurgica Sinica (English Letters), 2021, 34(1): 77-84.
[7]	He Huang, Huan Liu, Li-Sha Wang, Yu-Hua Li, Solomon-Oshioke Agbedor, Jing Bai, Feng Xue, Jing-Hua Jiang. A High-Strength and Biodegradable Zn-Mg Alloy with Refined Ternary Eutectic Structure Processed by ECAP [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(9): 1191-1200.
[8]	Li-Sha Wang, Jing-Hua Jiang, Bassiouny Saleh, Qiu-Yuan Xie, Qiong Xu, Huan Liu, Ai-Bin Ma. Controlling Corrosion Resistance of a Biodegradable Mg-Y-Zn Alloy with LPSO Phases via Multi-pass ECAP Process [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(9): 1180-1190.
[9]	Dan-Yang Liu, Jin-Feng Li, Yong-Cheng Lin, Peng-Cheng Ma, Yong-Lai Chen, Xu-Hu Zhang, Rui-Feng Zhang. Cu/Li Ratio on the Microstructure Evolution and Corrosion Behaviors of Al-xCu-yLi-Mg Alloys [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(9): 1201-1216.
[10]	Yu-Wei Liu, Jian Zhang, Xiao Lu, Miao-Ran Liu, Zhen-Yao Wang. Effect of Metal Cations on Corrosion Behavior and Surface Structure of Carbon Steel in Chloride Ion Atmosphere [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(9): 1302-1310.
[11]	Ren Li, Jing Ren, Guo-Jia Zhang, Jun-Yang He, Yi-Ping Lu, Tong-Min Wang, Ting-Ju Li. Novel (CoFe₂NiV_0.5Mo_0.2)_100-_xNb_x Eutectic High-Entropy Alloys with Excellent Combination of Mechanical and Corrosion Properties [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(8): 1046-1056.
[12]	Xigang Yang, Yun Zhou, Ruihua Zhu, Shengqi Xi, Cheng He, Hongjing Wu, Yuan Gao. A Novel, Amorphous, Non-equiatomic FeCrAlCuNiSi High-Entropy Alloy with Exceptional Corrosion Resistance and Mechanical Properties [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(8): 1057-1063.
[13]	P. F. Zhou, D. H. Xiao, T. C. Yuan. Microstructure, Mechanical and Corrosion Properties of AlCoCrFeNi High-Entropy Alloy Prepared by Spark Plasma Sintering [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(7): 937-946.
[14]	Yunhai Su, Xuewei Liang, Yunqi Liu, Zhiyong Dai. Effect of Ti Addition on the Microstructure and Property of FeAlCuCrNiMo_0.6 High-Entropy Alloy [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(7): 957-967.
[15]	Feng Shi, Ruo-Han Gao, Xian-Jun Guan, Chun-Ming Liu, Xiao-Wu Li. Application of Grain Boundary Engineering to Improve Intergranular Corrosion Resistance in a Fe–Cr–Mn–Mo–N High-Nitrogen and Nickel-Free Austenitic Stainless Steel [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(6): 789-798.