Acta Metallurgica Sinica (English Letters) ›› 2025, Vol. 38 ›› Issue (10): 1735-1741.DOI: 10.1007/s40195-025-01897-z

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Improving Tensile Strength and Ductility of Medium-Entropy Alloy via Three Principles of Composition Design

Z. Q. Wang1,2, J. X. Yan3(), H. Z. Liu1, X. G. Wang1, Z. J. Zhang1,2, Z. F. Zhang1,2()   

  1. 1 Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang, 110016, China
    2 School of Materials Science and Engineering, University of Science and Technology of China, Shenyang, 110016, China
    3 School of Materials Science and Engineering, Chongqing Jiaotong University, Chongqing, 400074, China
  • Received:2025-02-20 Revised:2025-04-02 Accepted:2025-04-19 Online:2025-07-08 Published:2025-07-08
  • Contact: J. X. Yan, Z. F. Zhang

Abstract:

Composition design is one of the significant methods to break the trade-off relation between strength and ductility of medium-/high-entropy alloys (M/HEAs). Herein, we introduced three fundamental principles for the composition design: high elastic modulus, low stacking-fault energy (SFE), and appropriate phase stability. Subsequently, based on the three principles of component design and the first-principles calculation results, we designed and investigated a non-equiatomic Ni28 MEA with a single-phase and uniform microstructure. The Ni28 MEA has great mechanical properties with yield strength of 329.5 MPa, tensile strength of 829.4 MPa, and uniform elongation of 56.9% at ambient temperature, respectively. The high ductility of Ni28 MEA may be attributed to the dynamically refined microstructure composed of hexagonal close-packed (HCP) lamellas and stacking faults (SFs), which provide extremely high work-hardening ability. This work demonstrates the feasibility of the three principles for composition design and can be extended to more M/HEAs in the future.

Key words: Medium-entropy alloys, Strength, Ductility, Stacking-fault energy, Work-hardening rate