Tribological Behaviors of Ni3Al Intermetallics with MoO3Multilayer Ribbon Crystal Prepared by Spark Plasma Sintering

doi:10.1007/s40195-017-0531-5

Abstract

Abstract:

This study reports that small amounts of MoO₃ multilayer ribbon crystal (MoO₃ MLRC) in Ni₃Al intermetallics showed the decreased friction coefficients and improved wear resistance at different contact loads. Specifically, the friction coefficients (0.32-0.34) and wear rates [(2-4) × 10^-5 mm³ N^-1 m^-1] are significantly reduced for Ni₃Al at 2-8 N. A possible explanation for the friction and wear reduction is that MoO₃ MLRC as a multilayer material shears easily in the tribo-layer during the sliding contact, and provides low friction. In addition, this MoO₃ MLRC with excellent bending strength is found to dissipate shear stress and suppress severe plastic deformation under a cyclic stress, thus drastically improving wear resistance of Ni₃Al.

Key words: Intermetallics, Tribological properties, Powder metallurgy, Microstructure, Wear resistant

Wenzheng Zhai, Xiaoliang Shi, Kang Yang, Yuchun Huang, Liping Zhou, Wenlong Lu. Tribological Behaviors of Ni₃Al Intermetallics with MoO₃Multilayer Ribbon Crystal Prepared by Spark Plasma Sintering[J]. Acta Metallurgica Sinica (English Letters), 2017, 30(6): 576-584.

Figures/Tables 6

Fig. 1 A typical FE-SEM image of MoO3 MLRC a; high-magnification FE-SEM image of MoO3MLRC b; HRTEM image of MoO3 MLRC c; the XRD pattern of Ni3Al d; FE-SEM image of cross section of Ni3Al e

Fig. 2 a Friction coefficients, wear rates of b Ni3Al with MoO3 MLRC, c Si3N4 counterpart at different loads

Fig. 3 Dynamic friction coefficients of Ni3Al at 2 a, 5 b, 8 c, 11 d N; the insets show the corresponding worn surfaces

Fig. 4 Depth distributions of the worn surfaces at the contact loads of 5 a, 11 b N; a back-scattered electron image of the worn surface at contact load of 11 N c

Fig. 5 Subsurface microstructures beneath the worn surface of Ni3Al parallel to sliding direction

Fig. 6 Schematic illustrations of wear mechanisms of Ni3Al in the worn subsurface microstructure

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Tribological Behaviors of Ni₃Al Intermetallics with MoO₃Multilayer Ribbon Crystal Prepared by Spark Plasma Sintering

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