Acta Metallurgica Sinica (English Letters) ›› 2015, Vol. 28 ›› Issue (6): 748-757.DOI: 10.1007/s40195-015-0256-2
• Orginal Article • Previous Articles Next Articles
Shao-Qiu Gou1, Bang-Xin Zhou1(), Mei-Yi Yao1, Jian-Chao Peng2, Chuan-Ming Chen1, Qiang Li2, Jin-Long Zhang1
Received:
2014-10-19
Revised:
2015-01-27
Online:
2015-03-21
Published:
2015-07-23
Shao-Qiu Gou, Bang-Xin Zhou, Mei-Yi Yao, Jian-Chao Peng, Chuan-Ming Chen, Qiang Li, Jin-Long Zhang. Oxide Layers on (0001) Plane of Zircaloy-4 After Corrosion at 360 °C in Lithiated Aqueous Solution[J]. Acta Metallurgica Sinica (English Letters), 2015, 28(6): 748-757.
Add to citation manager EndNote|Ris|BibTeX
Fig. 2 a Bright-field image of metal matrix; b SAED pattern of the metal matrix; c bright-field image of the oxygen-rich region; d SAED pattern of the oxygen-rich region
Position | Zr content (at%) | O content (at%) | Zr/O ratio |
---|---|---|---|
1 | 96.04 | 3.96 | 24.3 |
2 | 96.30 | 3.70 | 26.0 |
3 | 97.15 | 2.85 | 34.1 |
4 | 85.15 | 14.85 | 5.7 |
5 | 83.16 | 16.84 | 4.9 |
6 | 59.79 | 40.21 | 1.5 |
7 | 61.56 | 38.44 | 1.6 |
8 | 56.75 | 43.25 | 1.3 |
Table 1 EDS results of the positions in Fig. 2a marked by the numbers
Position | Zr content (at%) | O content (at%) | Zr/O ratio |
---|---|---|---|
1 | 96.04 | 3.96 | 24.3 |
2 | 96.30 | 3.70 | 26.0 |
3 | 97.15 | 2.85 | 34.1 |
4 | 85.15 | 14.85 | 5.7 |
5 | 83.16 | 16.84 | 4.9 |
6 | 59.79 | 40.21 | 1.5 |
7 | 61.56 | 38.44 | 1.6 |
8 | 56.75 | 43.25 | 1.3 |
Fig. 3 Inner surface morphologies of the oxide layers formed on the grain surface with near (0001) plane: a the inner surface was concave-convex; b there were some relatively small concave-convex on the ridge strips observed at higher magnification
Fig. 4 HRTEM image of the type 1 O/M interface and FFT patterns for the areas marked by the letters (A α-Zr matrix, B bcc-ZrOx, C m-ZrO2, D c-ZrO2, E undefined structure)
Fig. 5 HRTEM image of the type 2 O/M interface and FFT patterns for the areas marked by the letters (A oxygen-rich region, B t-ZrO2, C m-ZrO2, D m-ZrO2)
Fig. 9 SAED patterns of the oxide layers formed on near (0001) plane a, near () plane b, the corresponding dark-field TEM images obtained from the oxide layers on near (0001) plane c, near () plane d
[1] | H.J. Kim, T.H. Kim, Y.H. Jeong, J. Nucl. Mater. 306, 44(2002) |
[2] | G. Bakradze, P.H. Jeurgens, J. Mittemeijer,Surf. Interface Anal. 42, 588(2010) |
[3] | D. Charquet, R. Tricot, J.F. Wadier, paper present in: Zirconium in the Nuclear Industry, 8th International Symposium, West Conshohocken, ASTM STP 1023, (1989), pp. 374-388 |
[4] | G.C. Sun, B.X. Zhou, M.Y. Yao, S.J. Xie, Q. Li,Acta Metall. Sin. 48, 1103(2012). (in Chinese) |
[5] | J. Favergeon, T. Montesin, G. Bertrand,Oxid. Met. 64, 253(2005) |
[6] | C.S. Zhang, B.J. Flinn, I.V. Mitchell, P.R. Norton,Surf. Sci. 245, 373(1991) |
[7] | B.X. Zhou, J.C. Peng, M.Y. Yao, Q. Li, S. Xia, C.X. Du, G. Xu, paper present in: Zirconium in the Nuclear Industry: 16th International Symposium, ASTM STP 1529, ASTM International, (2011), pp. 620-646 |
[8] | A. Yilmazbayhan, E. Breval, A.T. Motta, R.J. Comstock, J. Nucl. Mater. 349, 265(2006) |
[9] | P. Bossis, G. Lelievre, P. Barberis, X. Iltis, F. Lefebvre, L. Thomas, M. Maguire, paper present in: Zirconium in the Nuclear Industry: Twelfth International Symposium, ASTM International, (2000), pp. 918-945 |
[10] | B. Wadman, Z. Lai, H.O. Nystrom, L.A. Nystrom, P. Rudling, H. Pettersson, paper present in: Zirconium in the Nuclear Industry: Tenth International Symposium, ASTM International, Baltimore, (1993), pp. 579-598 |
[11] | S. Abolhassania, G. Barta, A. Jakobb, J. Nucl. Mater. 399, 1(2009) |
[12] | H. Anada, K. Takeda, paper present in: Zirconium in the Nuclear Industry: Eleventh International Symposium, American Society for Testing and Materials, Garmisch-Partenkirchen, Germany, (1995), pp. 35-54 |
[13] | Y. Dong, A.T. Motta, E.A. Marquis, J. Nucl. Mater. 442, 270(2013) |
[14] | B.X. Zhou, Q. Li, M.Y. Yao, W.Q. Liu, Y.L. Chu,Corros. Prot. 30, 589(2009) |
[15] | W.J. Gong, H.L. Zhang, Y. Qiao, H. Tian, X.D. Ni, Z.K. Li, X.T. Wang,Corros. Sci. 74, 323(2013) |
[16] | J.C. Peng, MS Thesis, Shanghai University, 2009 |
[17] | S.Q. Gou, B.X. Zhou, C.M. Chen, M.Y. Yao, J.C. Peng, X. Liang, J.L. Zhang, Q. Li,Corros. Sci. 92, 237(2015) |
[18] | M.Y. Yao, B.X. Zhou, Q. Li, W.Q. Liu, X. Geng, Y.P. Lu, J. Nucl. Mater. 374, 197(2008) |
[19] | M. Paris, R. Foerch, G. Cailletaud, J. Phys. IV France 9, 311 (1999) |
[20] | D.S. Balint, J.W. Hutchinson,Acta Mater. 51, 3965(2003) |
[21] | V. Likhanskii, M. Kolesnik,Corros. Sci. 87, 416(2014) |
[22] | B.X. Zhou, Q. Li, W.Q. Liu, M.Y. Yao, Y.L. Chu,Rare Met. Mater. Eng. 35, 1009(2006). (in Chinese) |
[23] | D.J. Park, J.Y. Park, Y.H. Jeong, J. Nucl. Mater. 412, 233(2011) |
[24] | H.J. Beie, A. Mitwalsky, F. Garzarolli, H. Ruhmann, H.J. Sell, paper present in: Zirconium in the Nuclear Industry: 10th International Symposium, ASTM STP 1245, ASTM International, (1994), pp. 615-643 |
[25] | H. Arashi, M. Ishigame, Phys. Stat. Solidi A 71, 313 (1982) |
[26] | H.X. Zhang, D. Fruchart, E.K. Hill, L. Ortega, Z.K. Li, J.J. Zhang, J. Sun, L. Zhou, J. Nucl. Mater. 396, 65(2010) |
[27] | E. Polatidis, P. Frankel, J. Wei, M. Klaus, R.J. Comstock, A. Ambard, S. Lyon, R.A. Cottis, M. Preuss, J. Nucl. Mater. 432, 102(2013) |
[28] | W. Qin, C. Nam, H.L. Li, J.A. Szpunar,Acta Mater. 437, 280(2007) |
[29] | R.C. Garvie, J. Phys. Chem. 69, 218(1965) |
[30] | S. Fabris, A.T. Paxton, M.W. Finnis,Acta Mater. 50, 5171(2002) |
[31] | P. Ghigna, G. Spinolo, U. Anselmi-Tamburini, F. Maglia, M. Dapiaggi, G. Spina, L. Cianchi, J. Am. Chem. Soc. 121, 301(1999) |
[32] | C.X. Du, J.C. Peng, H. Li, B.X. Zhou,Acta Metall. Sin. 47, 887(2011). (in Chinese) |
[1] | Chun-Hua Ma, Fu-Sheng Pan, Ding-Fei Zhang, Ai-Tao Tang, Zhi-Wen Lu. Effects of Sb Addition on Microstructural Evolution and Mechanical Properties of Mg-9Al-5Sn Alloy [J]. Acta Metallurgica Sinica (English Letters), 2021, 34(2): 278-288. |
[2] | L. B. Tong, J. H. Chu, D. N. Zou, Q. Sun, S. Kamado, H. G. Brokmeier, M. Y. Zheng. Simultaneously Enhanced Mechanical Properties and Damping Capacities of ZK60 Mg Alloys Processed by Multi-Directional Forging [J]. Acta Metallurgica Sinica (English Letters), 2021, 34(2): 265-277. |
[3] | Meichen Liang, Hao Zhang, Lifeng Zhang, Peng Xue, Dingrui Ni, Weizhen Wang, Zongyi Ma, Hengqiang Ye, Zhiqing Yang. Evolution of Quasicrystals and Long-Period Stacking Ordered Structures During Severe Plastic Deformation and Mixing of Dissimilar Mg Alloys Upon Friction Stir Welding [J]. Acta Metallurgica Sinica (English Letters), 2021, 34(1): 12-24. |
[4] | Jinglin Liu, Qi Song, Lihui Song, Shude Ji, Mingshen Li, Zhen Jia, Kang Yang. A Novel Friction Stir Spot Riveting of Al/Cu Dissimilar Materials [J]. Acta Metallurgica Sinica (English Letters), 2021, 34(1): 135-144. |
[5] | Xudong Du, Feng Wang, Zhi Wang, Xingxing Li, Zheng Liu, Pingli Mao. Hot Tearing Susceptibility of AXJ530 Alloy Under Low-Frequency Alternating Magnetic Field [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(9): 1259-1270. |
[6] | Dan-Yang Liu, Jin-Feng Li, Yong-Cheng Lin, Peng-Cheng Ma, Yong-Lai Chen, Xu-Hu Zhang, Rui-Feng Zhang. Cu/Li Ratio on the Microstructure Evolution and Corrosion Behaviors of Al-xCu-yLi-Mg Alloys [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(9): 1201-1216. |
[7] | Chao-Yue Zhao, Xian-Hua Chen, Peng Peng, Teng Tu, Andrej Atrens, Fu-Sheng Pan. Microstructures and Mechanical Properties of Mg-xAl-1Sn-0.3Mn (x = 1, 3, 5) Alloy Sheets [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(9): 1217-1225. |
[8] | Qiuxin Nie, Hui Liang, Dongxu Qiao, Zhaoxin Qi, Zhiqiang Cao. Microstructures and Mechanical Properties of Multi-component AlxCrFe2Ni2Mo0.2 High-Entropy Alloys [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(8): 1135-1144. |
[9] | Yuan Yu, Peiying Shi, Kai Feng, Jiongjie Liu, Jun Cheng, Zhuhui Qiao, Jun Yang, Jinshan Li, Weimin Liu. Effects of Ti and Cu on the Microstructure Evolution of AlCoCrFeNi High-Entropy Alloy During Heat Treatment [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(8): 1077-1090. |
[10] | Hui Jiang, Tian-Dang Huang, Chao Su, Hong-Bin Zhang, Kai-Ming Han, Sheng-Xue Qin. Microstructure and Mechanical Behavior of CrFeNi2V0.5Wx (x = 0, 0.25) High-Entropy Alloys [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(8): 1117-1123. |
[11] | Ibrahim Ondicho, Bernard Alunda, Dicken Owino, Luke Otieno, Melody Chepkoech. Revealing a Transformation-Induced Plasticity (TRIP) Phenomenon in a Medium-Entropy Alloy [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(8): 1159-1165. |
[12] | Ren Li, Jing Ren, Guo-Jia Zhang, Jun-Yang He, Yi-Ping Lu, Tong-Min Wang, Ting-Ju Li. Novel (CoFe2NiV0.5Mo0.2)100-xNbx Eutectic High-Entropy Alloys with Excellent Combination of Mechanical and Corrosion Properties [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(8): 1046-1056. |
[13] | Chengbo Yang, Jing Zhang, Meng Li, Xuejian Liu. Soft-Magnetic High-Entropy AlCoFeMnNi Alloys with Dual-Phase Microstructures Induced by Annealing [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(8): 1124-1134. |
[14] | Ning Li, Cun-Lei Jia, Zhi-Wei Wang, Li-Hui Wu, Ding-Rui Ni, Zheng-Kun Li, Hua-Meng Fu, Peng Xue, Bo-Lv Xiao, Zong-Yi Ma, Yi Shao, Yun-Long Chang. Achieving a High-Strength CoCrFeNiCu High-Entropy Alloy with an Ultrafine-Grained Structure via Friction Stir Processing [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(7): 947-956. |
[15] | Zhigang Zhang, Xiaotong Lu, Jianrong Xu, Hongjie Luo. Characterization and Tribological Properties of Graphene/Copper Composites Fabricated by Electroless Plating and Powder Metallurgy [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(7): 903-912. |
Viewed | ||||||
Full text |
|
|||||
Abstract |
|
|||||