Acta Metallurgica Sinica (English Letters) ›› 2014, Vol. 27 ›› Issue (1): 47-54.DOI: 10.1007/s40195-013-0016-0
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M. Premović1, D. Minić1, D. Manasijević2, Vladan Ćosović3(), D. Živković2, I. Dervišević1, N. Talijan3
Received:
2013-05-08
Revised:
2013-07-25
Online:
2014-02-25
Published:
2014-03-11
M. Premović, D. Minić, D. Manasijević, Vladan Ćosović, D. Živković, I. Dervišević, N. Talijan. Mechanical and Electrical Properties of the Ternary Ag–Sb–Zn System[J]. Acta Metallurgica Sinica (English Letters), 2014, 27(1): 47-54.
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COST 531 thermodynamic database name | Common name | Struktur-bericht symbol | Pearson symbol |
---|---|---|---|
LIQUID | Liquid | ||
RHOMBO_A7 | (Sb) | A7 | hR2 |
FCC_A1 | (Ag) | A1 | cF4 |
HCP_A3 | ζ | A3 | hP2 |
AGSB_ORTHO | ε (LT) | – | oP4 |
ε (HT) | D0 | oP8 | |
HCP_ZN | (Zn) | A3 mod | hP2 |
BCC_A2 | β | A2 | cl2 |
AGZN_ZETA | ζ′ | Bb | hP9 |
AGZN_BRASS | γ | D82 | cl52 |
SBZN_BETA | β′ | Be | oP16 |
SBZN_GAMMA | γ′ | – | – |
SBZN_DELTA | δ | – | – |
SBZN_EPSILON | ε′ | – | – |
SBZN_ZETA | ζ′′ | – | ol* |
SBZN_ETA | η | – | oP30 |
Table 1 Considered phases and their crystal structures [19]
COST 531 thermodynamic database name | Common name | Struktur-bericht symbol | Pearson symbol |
---|---|---|---|
LIQUID | Liquid | ||
RHOMBO_A7 | (Sb) | A7 | hR2 |
FCC_A1 | (Ag) | A1 | cF4 |
HCP_A3 | ζ | A3 | hP2 |
AGSB_ORTHO | ε (LT) | – | oP4 |
ε (HT) | D0 | oP8 | |
HCP_ZN | (Zn) | A3 mod | hP2 |
BCC_A2 | β | A2 | cl2 |
AGZN_ZETA | ζ′ | Bb | hP9 |
AGZN_BRASS | γ | D82 | cl52 |
SBZN_BETA | β′ | Be | oP16 |
SBZN_GAMMA | γ′ | – | – |
SBZN_DELTA | δ | – | – |
SBZN_EPSILON | ε′ | – | – |
SBZN_ZETA | ζ′′ | – | ol* |
SBZN_ETA | η | – | oP30 |
Sample | Phase | Composition | |||||
---|---|---|---|---|---|---|---|
Ag | Sb | Zn | |||||
exp. | calc. | exp. | calc. | exp. | calc. | ||
I (Ag60Sb20Zn20) | (Ag) | 80.72 | 81.64 | 2.97 | 1.801 | 16.31 | 16.56 |
β′ | 1.325 | – | 50.54 | 50 | 48.13 | 50 | |
ε | 74.4 | 77.07 | 25.37 | 22.93 | 0.23 | – | |
II (Ag60Sb28Zn12) | (Sb) | 1.92 | – | 96.95 | 100 | 1.13 | – |
β′ | 1.723 | – | 51.72 | 50 | 46.65 | 50 | |
ε | 75.24 | 76.19 | 24.33 | 23.81 | 0.43 | – | |
III (Ag18Sb28Zn54) | β′ | 1.36 | – | 63.24 | 65.06 | 35.4 | 34.94 |
γ | 51.82 | 50.66 | 2.48 | – | 45.7 | 45.34 | |
IV (Ag51Sb8.5Zn40.5) | (Ag) | 72.46 | 73.22 | 1.04 | 0.12 | 26.5 | 26.66 |
β′ | 0.14 | – | 64.24 | 65.06 | 35.62 | 34.94 |
Table 2 Calculated and experimentally determined compositions of different phases in the ternary Ag–Sb–Zn system at 300 °C (in at.%)
Sample | Phase | Composition | |||||
---|---|---|---|---|---|---|---|
Ag | Sb | Zn | |||||
exp. | calc. | exp. | calc. | exp. | calc. | ||
I (Ag60Sb20Zn20) | (Ag) | 80.72 | 81.64 | 2.97 | 1.801 | 16.31 | 16.56 |
β′ | 1.325 | – | 50.54 | 50 | 48.13 | 50 | |
ε | 74.4 | 77.07 | 25.37 | 22.93 | 0.23 | – | |
II (Ag60Sb28Zn12) | (Sb) | 1.92 | – | 96.95 | 100 | 1.13 | – |
β′ | 1.723 | – | 51.72 | 50 | 46.65 | 50 | |
ε | 75.24 | 76.19 | 24.33 | 23.81 | 0.43 | – | |
III (Ag18Sb28Zn54) | β′ | 1.36 | – | 63.24 | 65.06 | 35.4 | 34.94 |
γ | 51.82 | 50.66 | 2.48 | – | 45.7 | 45.34 | |
IV (Ag51Sb8.5Zn40.5) | (Ag) | 72.46 | 73.22 | 1.04 | 0.12 | 26.5 | 26.66 |
β′ | 0.14 | – | 64.24 | 65.06 | 35.62 | 34.94 |
Sample | Phase | Vickers microhardness of different tests (HV) | Mean value (HV) | ||||
---|---|---|---|---|---|---|---|
No.1 | No.2 | No.3 | No.4 | No.5 | |||
6 | White phase | 188.27 | 194.98 | 199.53 | 192.45 | – | 193.8 |
Mixed phase | 232.36 | 243.23 | 244.56 | 259.48 | 246.43 | 241.64 | |
9 | Light phase | 119.26 | 121.43 | 127.67 | – | – | 122.78 |
Gray phase | 147.26 | 148.42 | 141.29 | – | – | 145.65 | |
Dark phase | 165.33 | 166.24 | 156.39 | – | – | 162.65 |
Table 3 Measured Vickers microhardness of the studied phases in samples 6 and 9
Sample | Phase | Vickers microhardness of different tests (HV) | Mean value (HV) | ||||
---|---|---|---|---|---|---|---|
No.1 | No.2 | No.3 | No.4 | No.5 | |||
6 | White phase | 188.27 | 194.98 | 199.53 | 192.45 | – | 193.8 |
Mixed phase | 232.36 | 243.23 | 244.56 | 259.48 | 246.43 | 241.64 | |
9 | Light phase | 119.26 | 121.43 | 127.67 | – | – | 122.78 |
Gray phase | 147.26 | 148.42 | 141.29 | – | – | 145.65 | |
Dark phase | 165.33 | 166.24 | 156.39 | – | – | 162.65 |
x | Brinell hardness (MPa) | |||
---|---|---|---|---|
Agx(Sb0.5Zn0.5)1-x | Sbx(Ag0.5Zn0.5)1-x | Agx(Sb0.2Zn0.8)1-x | Ag0.4SbxZn0.6-x | |
0.0 | 82 | 126 | 167 | 159 |
0.1 | 107 | 132 | 132 | 169 |
0.2 | 131 | 164 | 95 | 142 |
0.3 | 138 | 139 | 124 | 124 |
0.4 | 182 | 115 | 128 | 121 |
0.5 | 162 | 105 | 126 | 102 |
0.6 | 121 | 78 | 86 | 72 |
0.7 | 103 | 69 | 78 | – |
0.8 | 80 | 42 | 46 | – |
0.9 | 67 | 132 | 42 | – |
1.0 | 24.5 | 294 | 24.5 | – |
Table 4 Brinell hardness of the alloys of the ternary Ag–Sb–Zn system
x | Brinell hardness (MPa) | |||
---|---|---|---|---|
Agx(Sb0.5Zn0.5)1-x | Sbx(Ag0.5Zn0.5)1-x | Agx(Sb0.2Zn0.8)1-x | Ag0.4SbxZn0.6-x | |
0.0 | 82 | 126 | 167 | 159 |
0.1 | 107 | 132 | 132 | 169 |
0.2 | 131 | 164 | 95 | 142 |
0.3 | 138 | 139 | 124 | 124 |
0.4 | 182 | 115 | 128 | 121 |
0.5 | 162 | 105 | 126 | 102 |
0.6 | 121 | 78 | 86 | 72 |
0.7 | 103 | 69 | 78 | – |
0.8 | 80 | 42 | 46 | – |
0.9 | 67 | 132 | 42 | – |
1.0 | 24.5 | 294 | 24.5 | – |
Fig. 5 Brinell hardness versus mole fraction of components for four vertical sections: a Agx(Sb0.5Zn0.5)1-x; b Sbx(Ag0.5Zn0.5)1-x; c Agx(Sb0.2Zn0.8)1-x; d Ag0.4SbxZn0.6-x
x | Electrical conductivity (106 S/m) | |||
---|---|---|---|---|
Agx(Sb0.5Zn0.5)1-x | Sbx(Ag0.5Zn0.5)1-x | Agx(Sb0.2Zn0.8)1-x | Ag0.4SbxZn0.6-x | |
0.0 | 4.5426 | 11.7267 | 13.5748 | 8.0231 |
0.1 | 3.7825 | 6.9758 | 10.6854 | 2.2437 |
0.2 | 1.4328 | 1.0329 | 4.4765 | 0.9587 |
0.3 | 1.3367 | 0.7869 | 3.3324 | 0.4450 |
0.4 | 0.3441 | 0.3199 | 2.4601 | 1.1023 |
0.5 | 1.4597 | 0.4263 | 3.1208 | 1.4810 |
0.6 | 2.6947 | 0.3388 | 3.8029 | 1.523 |
0.7 | 4.132 | 0.3562 | 5.6524 | – |
0.8 | 10.9946 | 0.4868 | 6.5848 | – |
0.9 | 19.8739 | 1.4375 | 17.5642 | – |
1.0 | 62 | 2.5 | 62 | – |
Table 5 Electrical conductivity of the alloys of the ternary Ag–Sb–Zn system
x | Electrical conductivity (106 S/m) | |||
---|---|---|---|---|
Agx(Sb0.5Zn0.5)1-x | Sbx(Ag0.5Zn0.5)1-x | Agx(Sb0.2Zn0.8)1-x | Ag0.4SbxZn0.6-x | |
0.0 | 4.5426 | 11.7267 | 13.5748 | 8.0231 |
0.1 | 3.7825 | 6.9758 | 10.6854 | 2.2437 |
0.2 | 1.4328 | 1.0329 | 4.4765 | 0.9587 |
0.3 | 1.3367 | 0.7869 | 3.3324 | 0.4450 |
0.4 | 0.3441 | 0.3199 | 2.4601 | 1.1023 |
0.5 | 1.4597 | 0.4263 | 3.1208 | 1.4810 |
0.6 | 2.6947 | 0.3388 | 3.8029 | 1.523 |
0.7 | 4.132 | 0.3562 | 5.6524 | – |
0.8 | 10.9946 | 0.4868 | 6.5848 | – |
0.9 | 19.8739 | 1.4375 | 17.5642 | – |
1.0 | 62 | 2.5 | 62 | – |
Fig. 6 Electrical conductivity versus mole fraction of components for four vertical sections: a Agx(Sb0.5Zn0.5)1-x; b Sbx(Ag0.5Zn0.5)1-x; (c) Agx(Sb0.2Zn0.8)1-x; d Ag0.4SbxZn0.6-x
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