Acta Metallurgica Sinica (English Letters) ›› 2020, Vol. 33 ›› Issue (9): 1302-1310.DOI: 10.1007/s40195-020-01032-0
Yu-Wei Liu1,2, Jian Zhang3, Xiao Lu1,2, Miao-Ran Liu1,4, Zhen-Yao Wang1()
Received:
2019-10-23
Revised:
2019-11-26
Online:
2020-09-10
Published:
2020-09-17
Contact:
Zhen-Yao Wang
Yu-Wei Liu, Jian Zhang, Xiao Lu, Miao-Ran Liu, Zhen-Yao Wang. Effect of Metal Cations on Corrosion Behavior and Surface Structure of Carbon Steel in Chloride Ion Atmosphere[J]. Acta Metallurgica Sinica (English Letters), 2020, 33(9): 1302-1310.
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Cl- | SO42- | K+ | Na+ | Ca2+ | Mg2+ |
---|---|---|---|---|---|
20 | 2.18 | 5 | 10 | 0.3 | 1 |
Table 1 Main element composition of the seawater (g/L, pH 6.6)
Cl- | SO42- | K+ | Na+ | Ca2+ | Mg2+ |
---|---|---|---|---|---|
20 | 2.18 | 5 | 10 | 0.3 | 1 |
Fig. 4 SEM images of the carbon steel surface after removal of the corrosion products in different metal cations containing atmosphere after 240 h for a, b NaCl; c, d KCl; e, f MgCl2
Fig. 5 Three-dimensional roughness of the carbon steel surface after removal of the corrosion products exposed to Na+ a, K+ b, Mg2+ c containing atmosphere
Fig. 9 Equivalent circuits used to fit the experimental EIS data for a rusted carbon steel in Na+ and K+ containing atmosphere and bare carbon steel; b rusted carbon steel exposed in Mg2+ containing atmosphere
Na+-0 h | K+-0 h | Mg2+-0 h | Na+-240 h | K+-240 h | Mg2+-240 h | |
---|---|---|---|---|---|---|
Rs (Ω cm2) | 4.37 | 4.35 | 3.43 | 6.83 | 9.87 | 16.47 |
Qr (F cm-2) | - | - | - | - | - | 1.81E-3 |
nr | - | - | - | - | - | 0.45 |
Rr (Ω cm2) | - | - | - | - | - | 19.08 |
Qdl (F cm-2) | 1.09E-3 | 9.04E-4 | 1.53E-3 | 3.14E-2 | 3.26E-2 | 4.85E-2 |
ndl | 0.80 | 0.81 | 0.67 | 0.52 | 0.52 | 0.48 |
Rt (Ω cm2) | 1645 | 1368 | 633.5 | 2210 | 989.3 | 392.8 |
∑χ2 (× 10-4) | 2.39 | 3.58 | 4.55 | 1.38 | 1.96 | 0.18 |
Table 2 EIS fitting parameters for bare and rusted carbon steel in different metal cations
Na+-0 h | K+-0 h | Mg2+-0 h | Na+-240 h | K+-240 h | Mg2+-240 h | |
---|---|---|---|---|---|---|
Rs (Ω cm2) | 4.37 | 4.35 | 3.43 | 6.83 | 9.87 | 16.47 |
Qr (F cm-2) | - | - | - | - | - | 1.81E-3 |
nr | - | - | - | - | - | 0.45 |
Rr (Ω cm2) | - | - | - | - | - | 19.08 |
Qdl (F cm-2) | 1.09E-3 | 9.04E-4 | 1.53E-3 | 3.14E-2 | 3.26E-2 | 4.85E-2 |
ndl | 0.80 | 0.81 | 0.67 | 0.52 | 0.52 | 0.48 |
Rt (Ω cm2) | 1645 | 1368 | 633.5 | 2210 | 989.3 | 392.8 |
∑χ2 (× 10-4) | 2.39 | 3.58 | 4.55 | 1.38 | 1.96 | 0.18 |
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