Preparation and Characterization of Ag2S/PMMA Nanocomposites by Microemulsion

doi:10.1007/s40195-014-0029-3

Abstract

Abstract:

Ag₂S nanoparticles in polymethyl methacrylate (PMMA) are prepared in n-heptane/sodium bis(2-ethylhexyl)sulfosuccinate/water microemulsions. The Ag₂S nanoparticles dispersed in the polymer are characterized by FT-IR spectrum, UV–Vis absorption spectroscopy, transmission electron microscopy (TEM), and X-ray powder diffraction (XRD). The FT-IR spectrum shows that the composite has the characteristic bands of nano-Ag₂S and pure PMMA. The TEM photograph of the sample shows that the Ag₂S nanoparticles are elliptical. The phase structure of the composite is characterized by XRD, which reveals that Ag₂S particles are formed. The UV–Vis absorption recorded at various times indicates an initial rapid formation of the nanoparticles and the quantum confinement effect of Ag₂S nanoparticles.

Key words: Nanoparticle, Nanocomposite, Coating

Yuzhen Li, Lizhen Gao, Wenjun Chen, Weike Zhang, Lili Gao, Yanqing Yang, Likun Shang, Meilu Wang. Preparation and Characterization of Ag₂S/PMMA Nanocomposites by Microemulsion[J]. Acta Metallurgica Sinica (English Letters), 2014, 27(1): 175-179.

Figures/Tables 4

References 25

[1]	K.R. Vijaya, O. Palchik, Y. Koltypin, Y. Diamant, A. Gedanken, Ultrason. Sonochem. 7, 173(2002)
[2]	M.C. Brelle, J.Z. Zhang, L. Nguyen, R.K. Mehra, J. Phys. Chem. A 103, 10194(1999)10.1021/jp991999j
[3]	S. Ummartyotin, N. Bunnak, J. Juntaro, M. Sain, H. Manuspiya, Solid State Sci. 14, 299(2012)10.1016/j.solidstatesciences.2011.12.005
[4]	J.F. Luna-Martínez, D.B. Hernández-Uresti, M.E. Reyes-Melo, C.A. Guerrero-Salazar, V.A. González-González, S. Sepúlveda-Guzmán, Carbohydr. Polym. 84, 566(2011)10.1016/j.carbpol.2010.12.021
[5]	S. WookShin, S. Kang, J. Yun, A.V. Moholkar, J.H. Moon, J.Y. Lee, J.H. Kim, Sol. Energy Mater. Sol. Cell. 95, 856(2011)10.1016/j.solmat.2010.11.002
[6]	J.J. Kanga, C.B. Wang, H.D. Wang, B.S. Xu, J.J. Liu, G.L. Li, Appl. Surf. Sci. 258, 1940(2012)10.1016/j.apsusc.2011.06.149
[7]	L. Pedone, E. Caponetti, M. Leone, V. Militello, V. Pantò, S. Polizzi, M.L. Saladino, J. Colloid Interface Sci. 284, 495(2005)10.1016/j.jcis.2004.10.019
[8]	M.Z. Rong, M.Q. Zhang, H.C. Liang, H.M. Zeng, Chem. Phys. 286, 267(2003)10.1016/S0301-0104(02)00928-X
[9]	G.R. Deen, M. Hara, Polymer 46, 10883(2005)10.1016/j.polymer.2005.08.084
[10]	B. Liu, H.P. Li, C.H. Chew, W.X. Que, Y.L. Lam, C.H. Kam, L.M. Gan, G.Q. Xu, Mater. Lett. 51, 461(2001)10.1016/S0167-577X(01)00336-6
[11]	A.P. Alivisatos, Science 271, 933(1996)10.1126/science.271.5251.933
[12]	R.G. Cope, H.J. Goldsmid, J. Appl. Phys. 16, 1501(1965)
[13]	G. Hodes, J. Manasen, D. Cahen, Nature 261, 403(1976)10.1038/261403a0
[14]	Y. Li, Y. Ding, Y. Qian, Y. Zhang, L. Yang, Inorg. Chem. 37, 2844(1998)10.1021/ic9800637
[15]	M.L. Breen, A.D. Dinsmoe, R.H. Pink, S.B. Qadri, B.R. Ratna, Langmuir 17, 903(2001)10.1021/la0011578
[16]	V.T. John, B. Simmons, G.L. McPherson, A. Bose, Curr. Opin. J. Colloid Interface Sci. 7, 288(2002)10.1016/S1359-0294(02)00070-5
[17]	J. Eastoe, B. Warne, J. Colloid Interface Sci. 1, 800(1996)10.1016/S1359-0294(96)80084-7
[18]	T.C. Mu, J.M. Du, Z.H. Li, Z.M. Liu, B.X. Han, J.Q. Wang, D.H. Sun, B. Wang, Colloid Polym. Sci. 282, 1179(2004)10.1007/s00396-004-1058-7
[19]	Z.H. Li, J.L. Zhang, J.M. Du, T.C. Mu, Z.M. Liu, J. Chen, B.X. Han, J. Appl. Polym. Sci. 94, 1643(2004)10.1002/app.21042
[20]	J.P. Cason, M.E. Miller, J.B. Thompson, C.B. Roberts, J. Phys. Chem. B 105, 2297(2001)10.1021/jp002127g
[21]	H.J. Zhai, H.S. Wang, Mater. Res. Bull. 43, 2354(2008)10.1016/j.materresbull.2007.08.004
[22]	W.S. Yang, T.F. Xie, T.F. Jiang, D.J. Wang, Colloids Surf. A Physicochem. Eng. Asp. 433, 55(2013)10.1016/j.colsurfa.2013.05.007
[23]	R.G. Chaudhuri, S. Paria, J. Colloid Interface Sci. 369, 117(2012)10.1016/j.jcis.2011.11.064
[24]	Z.P. Wang, X.D. Li, Q. Luo, Chem. J. Chin. Univ. 27, 527(2006)
[25]	J.F. Zhou, X.J. Tao, Z.J. Zhang, W.M. Liu, Q.J. Xue, Chem. Res. 10, 1(1999)

Preparation and Characterization of Ag₂S/PMMA Nanocomposites by Microemulsion

RichHTML

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 4

References 25

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Shasha Zhang, Niels van Dijk, Sybrand van der Zwaag. A Review of Self-healing Metals: Fundamentals, Design Principles and Performance [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(9): 1167-1179.
[2]	Jing-Hua Liu, Jin-Jun Liu, Qiang Zheng, Bao-Ru Bian, Juan Du. In Situ Transmission Electron Microscopy Observations of the Growth Process of Fe₃O₄-Ag Nanoparticles [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(9): 1283-1288.
[3]	Yang Shao, Rong-Chang Zeng, Shuo-Qi Li, Lan-Yue Cui, Yu-Hong Zou, Shao-Kang Guan, Yu-Feng Zheng. Advance in Antibacterial Magnesium Alloys and Surface Coatings on Magnesium Alloys: A Review [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(5): 615-629.
[4]	Tielong Han, Jiajun Li, Naiqin Zhao, Chunnian He. Fabrication of Graphene Nanoplates Modified with Nickel Nanoparticles for Reinforcing Copper Matrix Composites [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(5): 643-648.
[5]	Jin Hyuk Choi, Gobinda Gyawali, Dhani Ram Dhakal, Bhupendra Joshi, Soo Wohn Lee. Electrodeposited Ni-W-TiC Composite Coatings: Effect of TiC Reinforcement on Microstructural and Tribological Properties [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(4): 573-582.
[6]	Jie Liu, Shui-Sheng Zhu, Xin Deng, Jian-Ye Liu, Zhong-Ping Wang, Zhi Qu. Cutting Performance and Wear Behavior of AlTiN- and TiAlSiN-Coated Carbide Tools During Dry Milling of Ti-6Al-4V [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(3): 459-470.
[7]	Wen-Ya Zhang, Can-Ming Wang, Jing-Xin Ji, Xiao-Li Feng, Hong-Zhi Cui, Qiang Song, Chun-Zhi Zhang. Synthetic Effect of Cr and Mo Elements on Microstructure and Properties of Laser Cladding NiCr_xMo_y Alloy Coatings [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(10): 1331-1345.
[8]	Hua Zhang, Chang-Yu Zhao, Qi-Long Guo, Rui-Sheng Yang, Li-Yuan Liu, San-Bao Lin. Microstructure and Corrosion Behavior of Friction Stir Welded Al Alloy Coated by In Situ Shot-Peening-Assisted Cold Spray [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(1): 172-182.
[9]	Yu-Fen Zhang, Sha-Wei Tang, Tie-Gui Lin, Guang-Yi Liu, Jin Hu. Corrosion Properties of Calcium Stearate-Based Hydrophobic Coatings on Anodized Magnesium Alloy [J]. Acta Metallurgica Sinica (English Letters), 2019, 32(9): 1111-1121.
[10]	Li Jun-Lei, Wang Shuai, Cao Fang, Lin Xiao, Wei Xiao-Wei, Zhao Zhen-Hua, Dou Xiao-Jie, Yu Wei-Ting, Yang Ke, Zhao De-Wei. Fabrication and Characterization of Nanopillar-Like HA Coating on Porous Ti6Al4V Scaffold by a Combination of Alkali-Acid-Heat and Hydrothermal Treatments [J]. Acta Metallurgica Sinica (English Letters), 2019, 32(9): 1075-1088.
[11]	Tian-Hui Hu, Hong-Wei Shi, Tao Wei, Shi-Hua Fan, Fu-Chun Liu, En-Hou Han. Corrosion Protection of AA2024-T3 by Cerium Malate and Cerium Malate-Doped Sol-Gel Coatings [J]. Acta Metallurgica Sinica (English Letters), 2019, 32(7): 913-924.
[12]	Wen-Bo Li, Lan-Lan Liu, Ying-Fei Yang, Sheng-Long Zhu, Fu-Hui Wang. Hot Corrosion Behavior of SiO₂-Al₂O₃-Glass Composite Coating on Ti-47Al-2Cr-2Nb Alloy: Diffusion Barrier for S and Cl [J]. Acta Metallurgica Sinica (English Letters), 2019, 32(5): 599-606.
[13]	Tian-Long Zhang, Toko Tokunaga, Munekazu Ohno, Mi-Lin Zhang, Kiyotaka Matsuura. Fabrication of Al-Coated Mg-Li Alloy Sheet and Investigation of Its Properties [J]. Acta Metallurgica Sinica (English Letters), 2019, 32(2): 169-177.
[14]	He Liu, Shuai Li, Cheng-Yang Jiang, Chun-Tang Yu, Ze-Bin Bao, Sheng-Long Zhu, Fu-Hui Wang. Oxidation Performance and Interdiffusion Behavior of a Pt-Modified Aluminide Coating with Pre-deposition of Ni [J]. Acta Metallurgica Sinica (English Letters), 2019, 32(12): 1490-1500.
[15]	Ming-Chun Zhao, Ying-Chao Zhao, Deng-Feng Yin, Shuo Wang, Yong-Ming Shangguan, Chao Liu, Li-Li Tan, Ci-Jun Shuai, Ke Yang, Andrej Atrens. Biodegradation Behavior of Coated As-Extruded Mg–Sr Alloy in Simulated Body Fluid [J]. Acta Metallurgica Sinica (English Letters), 2019, 32(10): 1195-1206.