Acta Metallurgica Sinica (English Letters) ›› 2025, Vol. 38 ›› Issue (6): 961-968.DOI: 10.1007/s40195-024-01812-y

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Experimental and Molecular Dynamics Simulation Study of Chemical Short-Range Order in CrCoNi Medium-Entropy Alloy Fabricated Using Laser Powder Bed Fusion

Bolun Han1,2, Kai Feng1,2(), Zhuguo Li1,2(), Pan Liu3,4, Yakai Zhao5, Junnan Jiang3,4, Yiwei Yu1,2, Zhiyuan Wang1,2, Kaifeng Ji1,2   

  1. 1Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
    2Collaborative Innovation Center for Advanced Ship and Deep-Sea Exploration, Shanghai 200240, China
    3Shanghai Key Laboratory of Advanced High-Temperature Materials and Precision Forming, State Key Laboratory of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
    4Shanghai Jiao Tong University - JA Solar New Energy Materials Joint Research Center, Shanghai 200240, China
    5Institute of Materials Research and Engineering (IMRE), Agency for Science, Technology and Research (A*STAR), Singapore 138634, Republic of Singapore
  • Received:2024-09-03 Revised:2024-10-19 Accepted:2024-10-26 Online:2025-06-10 Published:2025-01-28
  • Contact: Kai Feng, fengkai@sjtu.edu.cn; Zhuguo Li, lizg@sjtu.edu.cn

Abstract:

CrCoNi medium entropy alloy (MEA) fabricated by laser powder bed fusion (LPBF) benefits from its distinctive hierarchical microstructure and has great potential as a structural material. However, while the intriguing chemical short-range order (CSRO) widely exists in high/medium entropy alloys, its formation in the LPBF-built samples still lacks enough understanding. In this study, we verified its existence by fine transmission electron microscopy characterizations and utilized hybrid Monte Carlo/molecular dynamics simulations to investigate the features and effects of CSRO in LPBF-built CrCoNi MEA (AM model). Results showed that the CSRO fraction and the stacking fault energy of the AM model lie between those of the well-annealed and random solid solution counterparts. Among these models, the AM model exhibited the best strain hardening ability due to its highest capability to generate and store sessile dislocations. The results agreed well with existing data and provide guidance to the future development of LPBF-built CrCoNi MEA.

Key words: Laser powder bed fusion, Medium entropy alloy, Chemical short-range order, Monte Carlo/molecular dynamics simulation