Acta Metallurgica Sinica (English Letters) ›› 2015, Vol. 28 ›› Issue (6): 663-670.DOI: 10.1007/s40195-015-0283-z

• Orginal Article •     Next Articles

Understanding Solid-Solid (fcc→ω+bcc) Transition at Atomic Scale

De-Hai Ping1()   

  1. (1)National Institute for Materials Science, Sengen 1-2-1, Tsukuba 305-0047, Japan
  • Received:2015-03-05 Revised:2015-05-01 Online:2015-05-15 Published:2015-07-23

Abstract:

An atomic transition model of a face-centered cubic (fcc) crystal to a primitive hexagonal ω and body-centered cubic (bcc) structures has been crystallographically built. The fcc structure can transform into the ω structure through a local shuffling or displacement of atoms about 0.4014 Å in iron for a fcc iron = 3.59 Å. The bcc structure can form either after the ω formation or concurrently by the similar mechanism, or the ω structure can be treated as an intermediate stage during the transition of fcc → bcc. Such a transition (fcc → ω + bcc transition) can be confirmed by Widmanstätten pattern formed in an iron meteorite, pearlitic structure and martensite composed of bcc-ferrite and ultra-fine ω particles in iron-carbon steels. The present fcc-bcc orientation relationship matches with Pitsch’s one.

Key words: Solid-solid, transition, ω, Transition, Martensitic, steel, Modeling, Crystallography, Twin, Phase, transformation