Acta Metallurgica Sinica (English Letters) ›› 2025, Vol. 38 ›› Issue (3): 396-406.DOI: 10.1007/s40195-024-01805-x

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A Novel BCC/B2 Structural Nb38Ti35Al15V6Cr4(TaHfMoW)2 Refractory High-Entropy Alloy with Excellent Specific Yield Strength-Plasticity Synergy

Hongbin Liu1,2, Zhenqiang Xing2, Yitong Yang2, Jingyu Pang2,3(), Wen Li1(), Zhengwang Zhu4, Long Zhang2, Aimin Wang2, Haifeng Zhang4, Hongwei Zhang2()   

  1. 1School of Materials Science and Engineering, Shenyang Ligong University, Shenyang, 110159, China
    2Shi-Changxu Innovation Center for Advanced Materials, Institute of Metal Research, Chinese Academy of Sciences, Shenyang, 110016, China
    3Foshan Sino-Tech Industrial Technology Research Institute, Foshan, 528000, China
    4School of Metallurgy, Northeastern University, Shenyang, 110819, China

Abstract:

Refractory high-entropy alloys (RHEAs) stand as promising candidates for the development of a new generation of high-temperature materials due to their exceptional mechanical properties. However, the inherent low ductility and high density of RHEAs have hindered their widespread adoption in industrial applications. In this study, an Nb38Ti35Al15V6Cr4(TaHfMoW)2 RHEA with a BCC/B2 dual-phase structure is successfully developed. The RHEA exhibits excellent specific yield strength of 162.4 MPa·g−1·cm3 and 84.3 MPa·g−1·cm3 at room temperature (RT) and 800 °C, respectively. It was found that the pinning effect of the B2 phase induces a gradual transition in dislocation slip mode from planar slip to cross slip, homogenizing the plastic flow and resulting in excellent compression plasticity (ε > 50%). Additionally, the B2 phase endows the alloy with excellent yield strength at high temperatures by precipitation strengthening. Moreover, the dominated a/2 < 111 > type dislocation contributes to the alloy's superior plasticity at high temperatures.

Key words: Refractory high entropy alloy, B2 phase, Microstructure, Mechanical property, Deformation mechanism