SAM AND XPS STUDIES ON SURFACE SEGREGATION OF SUBSTRATE ELEMENTS IN Au-Ni-KOVAR ALLOY SYSTEM

Abstract

Abstract: The surface segregation of substrate elements through the Au layer in the Au-Ni-Kovar sys- tem specimens heated at 250—350℃ for 0.5—1.5 h has been studied by SAM and XPS. Visual evidence of the mechanism for Ni and Co surface segregation of the complicated sys- tem has been given,i.e.Ni and Co penetrated the gold layer mainly by grain boundary diffu- sion and then covered the Au layer by surface diffusion.The strdy results of the chemical states of surface segregation elements not only indicate that oxygen adsorption and oxidation reaction are the driving force for the surface segregation of Ni and Co,but also show that the above segregation can result in water absorption on surfaces.

Key words: Au-Ni-Kovar alloy system, surface segregation, substrate element, SAM, XPS

QI Yunxin TANG Wentai XIA Jianguo Nei Mongol Institute of Metallic Materials,Baotou,ChinaLI Wang ZHAN Zhenzong Institute of Physical and Chemical Engineering Research,Tianjin,China. SAM AND XPS STUDIES ON SURFACE SEGREGATION OF SUBSTRATE ELEMENTS IN Au-Ni-KOVAR ALLOY SYSTEM[J]. Acta Metallurgica Sinica (English Letters), 1991, 4(9): 219-224.

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SAM AND XPS STUDIES ON SURFACE SEGREGATION OF SUBSTRATE ELEMENTS IN Au-Ni-KOVAR ALLOY SYSTEM

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