Acta Metallurgica Sinica (English Letters) ›› 2023, Vol. 36 ›› Issue (3): 486-494.DOI: 10.1007/s40195-022-01484-6

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Formation of Face-Centered Cubic Phase in Ti35 Alloy Under In Situ Heating Transmission Electron Microscopy

Jianan Hu1, Mengmeng Yang1, Wenlong Xiao2, Hao Wang1, Dehai Ping3, Chengze Liu4, Shewei Xin5, Songquan Wu1, Kai Zhang1,7, Yi Yang1(), Lai-Chang Zhang6, Aijun Huang7   

  1. 1School of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai 200093, China
    2Key Laboratory of Aerospace Advanced Materials and Performance of Ministry of Education, School of Materials Science and Engineering, Beihang University, Beijing 100191, China
    3School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, China
    4Xi’an Rare Metal Materials Institute Co. Ltd, Xi’an 710016, China
    5Northwest Institute for Non-Ferrous Metal Research, Xi’an 710016, China
    6School of Engineering, Edith Cowan University, 270 Joondalup Drive, Joondalup, Perth, WA 6027, Australia
    7Department of Materials Science and Engineering, Monash University, Clayton, VIC 3800, Australia
  • Received:2022-06-19 Revised:2022-08-10 Accepted:2022-08-26 Online:2023-03-10 Published:2022-11-09
  • Contact: Yi Yang,yiyang.imr@163.com

Abstract:

A thermally induced hexagonal close-packed (HCP) to face-centered cubic (FCC) phase transition was investigated in an α-type Ti35 alloy with twinned structure by in situ heating transmission electron microscopy (TEM) and ab initio calculations. TEM observations indicated that the HCP to FCC phase transition occurred both within matrix/twin and at the twin boundaries in the thinner region of the TEM film, and the FCC-Ti precipitated as plates within the matrix/twin, while as equiaxed cells at twin boundaries. The crystallographic orientation relationship between HCP-Ti and FCC-Ti can be described as: $\left\{ {111} \right\}_{{{\text{FCC}}}} //\left\{ {0002} \right\}_{{{\text{HCP}}}} \;{\text{and}}\; < 110 >\,_{{{\text{FCC}}}} //\, <1\overline{2} 10>\,_{{{\text{HCP}}}}$. The HCP to FCC phase transition was accomplished by forming an intermediate state with a BB stacking sequence through the slip of partial dislocations. The formation of such FCC-Ti may be related to the thermal stress and temperature. Ab initio calculations showed that the formation of FCC-Ti may also be related to the contamination of interstitial atoms such as oxygen.

Key words: In situ heating TEM, FCC titanium, Phase transition, Ab initio calculation