Acta Metallurgica Sinica (English Letters) ›› 2020, Vol. 33 ›› Issue (11): 1477-1486.DOI: 10.1007/s40195-020-01069-1
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Pei Li1,2, Danhui Hou2, En-Hou Han2, Rongshi Chen2(), Zhiwei Shan1(
)
Received:
2020-01-12
Revised:
2020-03-02
Online:
2020-11-10
Published:
2020-11-17
Contact:
Rongshi Chen,Zhiwei Shan
Pei Li, Danhui Hou, En-Hou Han, Rongshi Chen, Zhiwei Shan. Solidification of Mg-Zn-Zr Alloys: Grain Growth Restriction, Dendrite Coherency and Grain Size[J]. Acta Metallurgica Sinica (English Letters), 2020, 33(11): 1477-1486.
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Alloys | Zn | Zr | Mg |
---|---|---|---|
K1 | 0 | 0.38 | Bal. |
ZK11 | 0.97 | 0.40 | Bal. |
ZK31 | 2.82 | 0.50 | Bal. |
ZK41 | 3.72 | 0.56 | Bal. |
ZK51 | 4.60 | 0.47 | Bal. |
Table 1 Chemical compositions of Mg-xZn-0.5Zr (x = 0, 1, 3, 4, 5 wt%) alloys
Alloys | Zn | Zr | Mg |
---|---|---|---|
K1 | 0 | 0.38 | Bal. |
ZK11 | 0.97 | 0.40 | Bal. |
ZK31 | 2.82 | 0.50 | Bal. |
ZK41 | 3.72 | 0.56 | Bal. |
ZK51 | 4.60 | 0.47 | Bal. |
Fig. 1 a Device, b result of thermal analysis for determining the dendrite coherency temperature (TDCP) (Tc and Te refer to the temperatures in the center and near the edge of ingots, respectively)
Fig. 4 BSE observations of a K1, b ZK11, c, d ZK31, e, f ZK41 g, h ZK51 alloys (the black and white arrows in the enlarged views indicate the Zr-rich areas and Zr particles, respectively)
Fig. 8 a Plots of the constitutional undercooling against solid-phase fraction of Mg-xZn-0.5Zr (x = 0, 1, 3, 4, 5 wt%) alloys at the initial stage of solidification ,b the calculated Q values variation against Zn content
Alloys | K1 | ZK11 | ZK31 | ZK41 | ZK51 |
---|---|---|---|---|---|
TDCP (°C) | 650 | 645 | 636 | 626 | 630 |
Table 2 Dendrite coherency temperatures of Mg-xZn-0.5Zr (x = 0, 1, 3, 4, 5 wt%) alloys
Alloys | K1 | ZK11 | ZK31 | ZK41 | ZK51 |
---|---|---|---|---|---|
TDCP (°C) | 650 | 645 | 636 | 626 | 630 |
Fig. 10 a Plots of temperature against solid fraction of Mg-xZn-0.5Zr (x = 0, 1, 3, 4, 5 wt%) alloys calculated by the Scheil simulation, b dendrite coherency solid fractions (fDCPs ) of the alloys obtained from (a)
[1] | K.N. Solanki, D. Orlov, A. Singh, N.R. Neelameggham, (eds.), Magnesium Technology 2017 (Springer, Cham, 2017) |
[2] | P.L. Zhang, Y.H. Zhao, R.P. Lu, Z.B. Ding, H. Hou, Acta Metall. Sin. -Engl. Lett. 32, 550(2018) |
[3] | H. Zengin, Y. Turen, M.E. Turan, F. Aydın, Acta Metall. Sin. -Engl. Lett. 32, 1309(2019) |
[4] | S.Q. Yin, Z.Q. Zhang, X. Liu, Q.C. Le, Q. Lan, L. Bao, J.Z. Cui, Mater. Sci. Eng. A-Struct. Mater. Prop. Microstruct. Process 695, 135(2017) |
[5] | R.G. Guan, I. Johnson, T. Cui, T. Zhao, Z.Y. Zhao, X. Li, H.N. Liu, J. Biomed. Mater. Res. Part A 100, 999 (2012) |
[6] | Y. Ali, D. Qiu, B. Jiang, F. Pan, M.X. Zhang, J. Alloys Compd. 619, 639(2015) |
[7] | M. Qian, L. Zheng, D. Graham, M.T. Frost, J. Light Met 1, 157 (2001) |
[8] | M. Qian, D.H. StJohn, M.T. Frost, Scr. Mater. 46, 649(2002) |
[9] |
M. Qian, D.H. StJohn, M.T. Frost, Scr. Mater. 50, 1115(2004)
DOI URL |
[10] |
M. Easton, D. StJohn, Metall. Mater. Trans. A 36, 1911 (2005)
DOI URL |
[11] |
D.H. StJohn, M. Qian, M.A. Easton, P. Cao, Acta Mater. 59, 4907(2011)
DOI URL |
[12] |
M. Qian, P. Cao, M.A. Easton, S.D. McDonald, D.H. StJohn, Acta Mater. 58, 3262(2010)
DOI URL |
[13] |
D.H. Stjohn, M.A. Easton, P. Cao, M. Qian, Int. J. Cast. Met. Res. 20, 131(2007)
DOI URL |
[14] |
I. Maxwell, A. Hellawell, Acta Metall. 23, 229(1975)
DOI URL |
[15] |
T. Quested, A. Dinsdale, A. Greer, Acta Mater. 53, 1323(2005)
DOI URL |
[16] |
H. Xu, L.D. Xu, S.J. Zhang, Q. Han, Scr. Mater. 54, 2191 (2006)
DOI URL |
[17] |
Y.C. Lee, A.K. Dahle, D.H. StJohn, Metall. Mater. Trans. A 31, 2895 (2000)
DOI URL |
[18] | J. Gu, Y. Huang, M. Zhang, K.U. Kainer, N. Hort, Effects of Mn and Zn solutes on grain refinement of commercial pure magnesium,in Magnesium Technology 2017, ed. by K.N. Solanki, D. Orlov, A.Singh, N.R. Neelameggham (Springer, Cham, 2017), pp. 191-198 |
[19] | S. Liang, Dissertation, Institute of Metal Research, Chinese Academy of Sciences (2010) |
[20] |
X. Yao, A.K. Dahle, C.J. Davidson, D.H. StJohn, J. Mater. Sci. 42, 9756(2007)
DOI URL |
[21] |
M. Malekan, S.G. Shabestari, Metall. Mater. Trans. A 40, 3196 (2009)
DOI URL |
[22] |
G.C. Chai, L. Backerud, T. Rolland, L. Arnberg, Metall. Mater.Trans. A 26, 965 (1995)
DOI URL |
[23] | Z. Hildebrand, M. Qian, D. StJohn, M. Frost, Influence of zinc on the soluble zirconium content in magnesium and the subsequent grain refinement by zirconium, in Magnesium Technology 2004, ed. By A.A. Luo (Springer, Cham, 2004), pp. 241-245 |
[24] | C.H. Cáceres, A. Blake, Phys. Status Solidi A 194, 147 (2002) |
[25] | S.M. Liang, R.S. Chen, J.J. Blandin, M. Suery, E.H. Han, Mater. Sci. Eng. A 480, 365 (2008) |
[26] |
Z.H. Huang, S.M. Liang, R.S. Chen, E.H. Han, J. Alloys Compd. 468, 170(2009)
DOI URL |
[27] |
W. Cao, S.L. Chen, F. Zhang, K. Wu, Y. Yang, Y.A. Chang, R. Schmid-Fetzer, W.A. Oates, Calphad 33, 328 (2009)
DOI URL |
[28] |
R. Schmid-Fetzer, J. Gröner, Metals 2, 377 (2012)
DOI URL |
[29] |
R. Schmid-Fetzer, A. Kozlov, Acta Mater. 59, 6133(2011)
DOI URL |
[30] |
M. Qian, Z.C.G. Hildebrand, D.H. StJohn, Metall. Mater. Trans. A 40, 2470 (2009)
DOI URL |
[31] |
M.A. Easton, D.H. StJohn, Acta Mater.. 49, 1867(2001)
DOI URL |
[32] |
Y.P. Xie, Z.Y. Wang, Z.F. Hou, Scr. Mater. 68, 495(2013)
DOI URL |
[33] |
R.W. Armstrong, Mater. Trans. 55, 2(2014)
DOI URL |
[34] |
J.D. Robson, C. Paa-Rai, Acta Mater. 95, 10(2015)
DOI URL |
[35] | K. Kurz, D.J. Fisher, Fundamentals of Solidification, 4th edn.(Trans Tech Publications, 984) |
[36] | J.D. Hunt, Mater. Sci. Eng. 65, 75(1984) |
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