Electrochemical and Pseudocapacitive Analysis of Rod-Like MoO2@MoSe2@NC Heterostructures for High-Performance Lithium Ion Batteries

doi:10.1007/s40195-021-01207-3

Abstract

Abstract:

A micro-scale rod-like heterostructure derived from molybdenum-based metal organic framework (Mo-MOF) has been successfully prepared via subsequent annealing treatment, which assembled from N-doped carbon encapsulated MoSe₂ nanosheets grown on the surface of MoO₂ microrod (named as MoO₂@MoSe₂@NC). For this novel heterostructure, the MoO₂ nanoparticles assembled into rod core not only serve as supporting substrate for facilitating the fast kinetics of Li⁺ cations inside the electrode but also protect the MoSe₂ structure from restacking in the charge/discharge process. Moreover, the outer-layered MoSe₂ nanosheets enable the fast lithium ion movement owing to its large interlayer spacing. Moreover, this unique rod-like core-shell structure composite could further effectively alleviate the structural strains caused by large volume expansion during charge/discharge process, thus leading to stable electrochemical performance when evaluated as anode material for lithium ion batteries. Electrochemical testing exhibits that the MoO₂@MoSe₂@NC heterostructure presents highly reversible capacity of 468 mAh g^-1 at 0.5 A g^-1 and superior rate capability (318 mAh g^-1 even at 5.0 A g^-1), which is attributed to the synergistic effect of N-doped carbon encapsulated MoSe₂ nanosheets and MoO₂ nanoparticles.

Key words: Mo-MOF, MoO₂@MoSe₂@NC, MoSe₂ nanosheet, Heterostructure, Lithium ion batteries (LIBs)

Zhaoxia Qin, Xinlong Liu, Zhiyin Huang, Rui Sun, Zhiyong Li, Haosen Fan, Shengjun Lu. Electrochemical and Pseudocapacitive Analysis of Rod-Like MoO₂@MoSe₂@NC Heterostructures for High-Performance Lithium Ion Batteries[J]. Acta Metallurgica Sinica (English Letters), 2021, 34(3): 425-434.

Figures/Tables 7

Fig. 1 Schematic illustration of the preparation of MoO2@MoSe2@NC heterostructures

Fig. 2 SEM images of Mo-MOF a, and pure MoO2@NC composite b, c; d XRD patterns of MoO2@MoSe2@NC composite annealed at different temperatures

Fig. 3 SEM images of MoO2@MoSe2@NC composite annealed at different selenization temperatures: a-c 500 °C, d-f 600 °C, g-i 700 °C, respectively

Fig. 4 High resolution XPS spectra: a Mo 3d; b Se 3d; c O 1 s; d C 1 s peaks of MoO2@MoSe2@NC heterostructures

Fig. 5 a CV curves of MoO2@MoSe2@NC in the three cycles at a scan rate of 0.1 mV s-1; b-d Charge and discharge profiles of MoO2@MoSe2@NC in the first 50 cycles at the current density of 0.2 A g-1 at 500, 600, 700 ℃, respectively

Fig. 6 a Rate performance of MoO2@MoSe2@NC at different annealing temperatures; b-d Charge and discharge profiles of MoO2@MoSe2@NC under various current densities at 500, 600, 700 ℃, respectively; e Cycling performance of MoO2@MoSe2@NC electrodes at a current density of 0.5 A g-1

Fig. 7 Kinetics investigation of MoO2@MoSe2@NC: a CV curves at different scan rates; b Corresponding ln (peak current) versus ln (scan rate) plots at different redox states; c Bar chart of the percent of pseudocapacitive contribution at different scan rates; d CV curve of the pseudocapacitive fraction shown by the purple region at a scan rate of 0.6 mV s-1

References 49

[1]	X. Yang, Y. Wang, B. Hou, H. Liang, X. Zhao, H. Fan, G. Wang, X. Wu, Acta Metall Sin.-Engl. Lett.(2020). https://doi.org/10.1007/s40195-020-01001-7
[2]	S. Mohapatra, S.V. Nair, A.K. Rai, Acta Metall Sin. -Engl. Lett. 31, 164(2018)
[3]	X. Chen, G. Gao, Z. Wu, J. Xiang, X. Li, G. Guan, K. Zhang, RSC Adv. 9, 37556(2019)
[4]	Y. Liu, N. Zhang, C. Yu, L. Jiao, J. Chen, Nano Lett. 16, 3321(2016) DOI URL PMID
[5]	B. Hu, L. Mai, W. Chen, F. Yang, ACS Nano 3, 478 (2009) DOI URL PMID
[6]	Y. Lin, Z. Qiu, D. Li, S. Ullah, Y. Hai, H. Xin, W. Liao, B. Yang, H. Fan, J. Xu, C. Zhu, Energy Storage Mater. 11, 67(2018)
[7]	H. Fan, H. Yu, Y. Zhang, J. Guo, Z. Wang, H. Wang, N. Zhao, Y. Zheng, C. Du, Z. Dai, Q. Yan, J. Xu, Energy Storage Mater. 10, 48(2018)
[8]	J. Huang, Z. Wei, J. Liao, W. Ni, C. Wang, J. Ma, J. Energy Chem. 33, 100(2019)
[9]	H. Wang, X. Wang, L. Wang, J. Wang, D. Jiang, G. Li, Y. Zhang, H. Zhong, Y. Jiang, J. Phys. Chem. C 119, 10197 (2015)
[10]	P. Geng, S. Zheng, H. Tang, R. Zhu, L. Zhang, S. Cao, H. Xue, H. Pang, Adv. Energy Mater. 8, 1703259(2018)
[11]	X. Li, M. Sun, S. Cheng, X. Ren, J. Zang, T. Xu, X. Wei, S. Li, Q. Chen, C. Shan, 2D Mater. 6, 035027(2019)
[12]	A. Eftekhari, Appl. Mater. Today 8, 1 (2017)
[13]	T. Xiang, S. Tao, W. Xu, Q. Fang, C. Wu, D. Liu, Y. Zhou, A. Khalil, Z. Muhammad, W. Chu, Z. Wang, H. Xiang, Q. Liu, L. Song, ACS Nano 11, 6483 (2017) URL PMID
[14]	J. Maier, Nat. Mater. 4, 805(2005) URL PMID
[15]	F. Xu, L. Wu, Q. Meng, M. Kaltak, J. Huang, J.L. Durham, M. Fernandez-Serra, L. Sun, A.C. Marschilok, E.S. Takeuchi, K.J. Takeuchi, M.S. Hybertsen, Y. Zhu, Nat. Commun. 8, 15400(2017) DOI URL PMID
[16]	X. Zhao, J. Sui, F. Li, H. Fang, H. Wang, J. Li, W. Cai, G. Cao, Nanoscale 8, 17902 (2016) URL PMID
[17]	C. Huang, S. Wu, A.M. Sanchez, J.J. Peters, R. Beanland, J.S. Ross, P. Rivera, W. Yao, D.H. Cobden, X. Xu, Nat. Mater. 13, 1096(2014) URL PMID
[18]	Z. Mao, H. Wang, D. Chao, R. Wang, B. He, Y. Gong, H. Fan, Small 33, 2001950 (2020)
[19]	D. Xu, H. Wang, R. Qiu, Q. Wang, Z. Mao, Y. Jiang, R. Wang, B. He, Y. Gong, D. Li, X. Hu, Energy Storage Mater. 28, 91(2020)
[20]	R. Fei, H. Wang, Q. Wang, R. Qiu, S. Tang, R. Wang, B. He, Y. Gong, H. Fan, Adv. Energy Mater. 47, 2002741(2020)
[21]	H. Lu, K. Tian, L. Bu., X. Huang, X. Li, Y. Zhao, F. Wang, J. Bai, L. Gao, J. Zhao, J. Energy Chem. 55, 449(2021).
[22]	B. Hou, Y. Wang, D. Liu, Z. Gu, X. Feng, H. Fan, T. Zhang, C. Lü, X. Wu, Adv. Funct. Mater. 28, 1805444(2018)
[23]	H. Fan, H. Yu, Y. Zhang, Y. Zheng, Y. Luo, Z. Dai, B. Li, Y. Zong, Q. Yan, Angew. Chem. Int. Ed. Engl. 56, 12566(2017) DOI URL PMID
[24]	P. Martían-Zarza, J.M. Arrieta, M.C. Muñoz-Roca, P. Gili, J. Chem. Soc. Dalton Trans. 10, 1551(1993)
[25]	Z. Wang, T. Chen, W. Chen, K. Chang, L. Ma, G. Huang, D. Chen, J.Y. Lee, J. Mater. Chem. A 1, 2202 (2013)
[26]	Y. Zhang, Q. Gong, L. Li, H. Yang, Y. Li, Q. Wang, Nano Res. 8, 1108(2014)
[27]	L. Yang, W. Zhou, D. Hou, K. Zhou, G. Li, Z. Tang, L. Li, S. Chen, Nanoscale 7, 5203 (2015) DOI URL PMID
[28]	S. Wu, Y. Du, S. Sun, Chem. Eng. J. 307, 189(2017)
[29]	Y. Sun, X. Hu, W. Luo, Y. Huang, J. Mater. Chem. 22, 425(2012)
[30]	Y. Zhou, H. Xie, C. Wang, Q. He, Q. Liu, Z. Muhammad, Y.A. Haleem, Y. Sang, S. Chen, L. Song, J. Phys. Chem. C 121, 15589 (2017)
[31]	J. Zhang, W. Kang, M. Jiang, Y. You, Y. Cao, T.W. Ng, D.Y. Yu, C.S. Lee, J. Xu, Nanoscale 9, 1484 (2017) URL PMID
[32]	D. Zheng, H. Feng, X. Zhang, X. He, M. Yu, X. Lu, Y. Tong, Chem. Commun. 53, 3929(2017)
[33]	X. Zhao, H.E. Wang, J. Cao, W. Cai, J. Sui, Chem. Commun. 53, 10723(2017)
[34]	Y. Sun, X. Hu, W. Luo, Y. Huang, ACS Nano 5, 7100 (2011) DOI URL PMID
[35]	X. Zhao, H. Wang, X. Chen, J. Cao, Y. Zhao, Z. Garbe Neale, W. Cai, J. Sui, G. Cao, Energy Storage Mater. 11, 161(2018)
[36]	Q. Hao, G. Cui, Y. Zhao, Z. Bakenov, Nanomaterials (Basel) 9, 1256(2019)
[37]	F. Niu, J. Yang, N. Wang, D. Zhang, W. Fan, J. Yang, Y. Qian, Adv. Funct. Mater. 27, 1700522(2017)
[38]	J. Xie, J. Zhang, S. Li, F. Grote, X. Zhang, H. Zhang, R. Wang, Y. Lei, B. Pan, Y. Xie, J. Am. Chem. Soc. 135, 17881(2013) URL PMID
[39]	Y. Liu, Y. Xiao, F. Liu, P. Han, G. Qin, J. Mater. Chem. A 7, 26818 (2019)
[40]	X. Zhao, H. Wang, R.C. Massé, J. Cao, J. Sui, J. Li, W. Cai, G. Cao, J. Mater. Chem. A 5, 7394 (2017)
[41]	H. Fan, H. Yu, Y. Zhang, J. Guo, Z. Wang, H. Wang, X. Hao, N. Zhao, H. Geng, Z. Dai, Q. Yan, J. Xu, Nano Energy 33, 168 (2017)
[42]	Y. Wang, Z. Huang, Y. Wang, J. Mater. Chem. A 3, 21314 (2015)
[43]	H. Zhang, K. Wang, X. Wu, Y. Jiang, Y. Zhai, C. Wang, X. Wei, J. Chen, Adv. Funct. Mater. 24, 3399(2014)
[44]	L.C. Yang, W. Sun, Z.W. Zhong, J.W. Liu, Q.S. Gao, R.Z. Hu, M. Zhu, J. Power Sour. 306, 78(2016)
[45]	W. Devina, J. Hwang, J. Kim, Chem. Eng. J. 345, 1(2018)
[46]	Y. Dou, J. Xu, B. Ruan, Q. Liu, Y. Pan, Z. Sun, S.X. Dou, Adv. Energy Mater. 6, 1501835(2016)
[47]	T. Brezesinski, J. Wang, S.H. Tolbert, B. Dunn, Nat. Mater. 9, 146(2010) URL PMID
[48]	V. Augustyn, P. Simon, B. Dunn, Energy Environ. Sci. 7, 1597(2014)
[49]	T. Brezesinski, J. Wang, J. Polleux, B. Dunn, S.H. Tolbert, J. Am. Chem. Soc. 131, 1802(2009) URL PMID

Electrochemical and Pseudocapacitive Analysis of Rod-Like MoO₂@MoSe₂@NC Heterostructures for High-Performance Lithium Ion Batteries

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 7

References 49

Related Articles 2

Recommended Articles

Metrics

Comments

[1]	Nour El-Houda Fares, Nadir Bouarissa. Positron Affinity, Deformation Potential and Diffusion Constant in Al_xIn_1-_xSb Ternary Semiconductor Alloys [J]. Acta Metallurgica Sinica (English Letters), 2016, 29(7): 661-667.
[2]	Dong-Ning He, Peter Hodgson, Wei-Min Gao. Epitaxial Growth of Multi-structure SnO₂ by Chemical Vapor Deposition [J]. Acta Metallurgica Sinica (English Letters), 2015, 28(7): 946-950.