Acta Metallurgica Sinica (English Letters) ›› 2021, Vol. 34 ›› Issue (1): 1-11.DOI: 10.1007/s40195-020-01058-4
Dong-Dong Gu1, Jian Peng1,2(), Jia-Wen Wang1, Zheng-Tao Liu1, Fu-Sheng Pan1,2
Received:
2019-12-06
Revised:
2020-01-23
Accepted:
2020-05-18
Online:
2021-01-10
Published:
2021-01-28
Contact:
Jian Peng
Dong-Dong Gu, Jian Peng, Jia-Wen Wang, Zheng-Tao Liu, Fu-Sheng Pan. Effect of Mn Modification on the Corrosion Susceptibility of Mg-Mn Alloys by Magnesium Scrap[J]. Acta Metallurgica Sinica (English Letters), 2021, 34(1): 1-11.
Add to citation manager EndNote|Ris|BibTeX
Alloys | Mn | Fe | Si | Mg |
---|---|---|---|---|
1# (Mg-0Mn-0.023Fe) | 0 | 0.0236 | 0.0179 | Bal |
2# (Mg-0.1Mn-0.023Fe) | 0.1090 | 0.0232 | 0.0188 | Bal |
3# (Mg-0.3Mn-0.020Fe) | 0.2780 | 0.0201 | 0.0203 | Bal |
4# (Mg-0.5Mn-0.018Fe) | 0.5030 | 0.0182 | 0.0171 | Bal |
5# (Mg-1.0Mn-0.018Fe) | 0.7610 | 0.0172 | 0.0206 | Bal |
6# (Mg-2.0Mn-0.010Fe) | 1.4890 | 0.0079 | 0.0200 | Bal |
Table 1 Chemical composition of the Mg-Mn-Fe alloy samples (wt%)
Alloys | Mn | Fe | Si | Mg |
---|---|---|---|---|
1# (Mg-0Mn-0.023Fe) | 0 | 0.0236 | 0.0179 | Bal |
2# (Mg-0.1Mn-0.023Fe) | 0.1090 | 0.0232 | 0.0188 | Bal |
3# (Mg-0.3Mn-0.020Fe) | 0.2780 | 0.0201 | 0.0203 | Bal |
4# (Mg-0.5Mn-0.018Fe) | 0.5030 | 0.0182 | 0.0171 | Bal |
5# (Mg-1.0Mn-0.018Fe) | 0.7610 | 0.0172 | 0.0206 | Bal |
6# (Mg-2.0Mn-0.010Fe) | 1.4890 | 0.0079 | 0.0200 | Bal |
Fig. 3 Scanning electron micrographs showing typical corrosion morphology of the Mg-Mn-Fe alloy samples after immersion in 3.5 wt% NaCl solution for 48 h with the corrosion products removing: a 1#, b 2#, c 3#, d 4#, e 5#, f 6#, g high magnification of the marked area A in a, h high magnification of the marked area B in c, i j high magnification of the marked area C and D in d, k high magnification of the marked area E in e
Fig. 4 Optical images showing the macro-corrosion morphology evolution on the surfaces of the Mg-Mn-Fe alloy samples during immersion in 3.5 wt% NaCl solution
Alloy | Mn (wt%) | The total iron (ppm) | Iron solubility (ppm) | The free iron (ppm) | Corrosion rate (mg/cm2 day) |
---|---|---|---|---|---|
1# | 0 | 236 | 180 | 56 | 144.88 ± 5.22 |
2# | 0.109 | 232 | 105 | 127 | 70.09 ± 3.60 |
3# | 0.278 | 201 | 75 | 126 | 13.79 ± 1.17 |
4# | 0.503 | 182 | 42 | 140 | 0.40 ± 0.12 |
5# | 0.761 | 172 | 30 | 142 | 0.54 ± 0.15 |
6# | 1.489 | 79 | 20 | 59 | 0.38 ± 0.09 |
Table 2 Iron content and corrosion performance of the alloy samples
Alloy | Mn (wt%) | The total iron (ppm) | Iron solubility (ppm) | The free iron (ppm) | Corrosion rate (mg/cm2 day) |
---|---|---|---|---|---|
1# | 0 | 236 | 180 | 56 | 144.88 ± 5.22 |
2# | 0.109 | 232 | 105 | 127 | 70.09 ± 3.60 |
3# | 0.278 | 201 | 75 | 126 | 13.79 ± 1.17 |
4# | 0.503 | 182 | 42 | 140 | 0.40 ± 0.12 |
5# | 0.761 | 172 | 30 | 142 | 0.54 ± 0.15 |
6# | 1.489 | 79 | 20 | 59 | 0.38 ± 0.09 |
Fig. 9 Fe-Mn solubility limits and the iron tolerance limit. The red numbers adjacent to the data points are the corrosion rates of the Mg-Mn-Fe alloy samples
[1] | T. Tu, X.H. Chen, J. Chen, C.Y. Zhao, F.S. Pan , Acta Metall. Sin. Engl. Lett. 32, 23( 2019) |
[2] | M. Nabiyouni, T. Brückner, H. Zhou, U. Gbureck, S.B. Bhaduri , Acta Biomater. 66, 23( 2018) |
[3] | N. Sezer, Z. Evis, S.M. Kayhan, A. Tahmasebifar, M. Koç , J. Magnes. Alloy. 6, 23( 2018) |
[4] | L.X. Wang, R.B. Song, C.H. Cai, J.Y. Li , Acta Metall. Sin. Engl. Lett. 32, 10( 2019) |
[5] | G.S. Frankel, A. Samaniego, N. Birbilis , Corros. Sci. 70, 104( 2013) |
[6] | Z.M. Shi, J.X. Jia, A. Atrens , Corros. Sci. 60, 296( 2012) |
[7] | S. Simanjuntak, M.K. Cavanaugh, D.S. Gandel, M.A. Easton, M.A. Gibson, N. Birbilis , Corrosion 71, 199 ( 2015) |
[8] | J.Y. Lee, G. Han, Y.C. Kim, J.Y. Byun, J.I. Jang, H.K. Seok, S.J. Yang , Met. Mater. Int. 15, 955( 2009) |
[9] | K. Riechek, K. Clark, J. Hillis , Pennsylvania, 1985) |
[10] | J. Hillis, S. Shook , Pennsylvania, 1989) |
[11] | W. Mercer, J. Hillis , Pennsylvania, 1992) |
[12] | M. Liu, P. Uggowitzer, P. Schmutz, A. Atrens , JOM 60, 39 ( 2008) |
[13] | L. Yang, X.R. Zhou, M. Curioni, S. Pawar, H. Liu, Z.Y. Fan, G. Scamans, G. Thompson , J. Electrochem. Soc. 162, C362( 2015) |
[14] | L. Yang, G.K. Liu, L.G. Ma, E.L. Zhang, X.R. Zhou, G. Thompson , Corros. Sci. 139, 421( 2018) |
[15] | R. Baboian ( Pennsylvania, 2005) |
[16] | B.A. Shaw, R.C. Wolfe ( OH, 2005) |
[17] | J.D. Hanawalt, C.E. Nelson, J.A. Peloubet , Trans. AIME 147, 273 ( 1942) |
[18] | M. Liu, P.J. Uggowitzer, A.V. Nagasekhar, P. Schmutz, M. Easton, G.L. Song, A. Atrens , Corros. Sci. 51, 602( 2009) |
[19] | L. Yang, X.R. Zhou, S.M. Liang, R. Schmid-Fetzer, Z.Y. Fan, G. Scamans, J. Robson, G. Thompson , J. Alloys Compd. 619, 396( 2015) |
[20] | J.G. Kim, S.J. Koo , Corrosion 56, 380 ( 2000) |
[21] | G. Han, J.Y. Lee, Y.C. Kim, J.H. Park, D.I. Kim, H.S. Han, S.J. Yang, H.K. Seok , Corros. Sci. 63, 316( 2012) |
[22] | G.L. Song, R. Mishra, Z.Q. Xu , Electrochem. Commun. 12, 1009( 2010) |
[23] | G.L. Song, A. Atrens , Adv. Eng. Mater. 1, 11( 1999) |
[24] | O. Lunder, T.K. Aune, K. Nisancioglu , Corrosion 43, 291 ( 1987) |
[25] | W.J. Binns, F. Zargarzadah, V. Dehnavi, J. Chen, J.J. Noel, D.W. Shoesmith , Corrosion 75, 58 ( 2019) |
[26] | Z. Rajabalizadeh, D. Seifzadeh , Prot. Met. Phys. Chem. Surf. 50, 516( 2014) |
[27] | J. Chen, J.Q. Wang, E.H. Han, J.H. Dong, W. Ke , Electrochim. Acta 52, 3299 ( 2007) |
[28] | A. Nayeb-Hashemi, J. Clark, L. Swartzendruber , Bull. Alloy Phase Diagr. 6, 235( 1985) |
[29] | L. Ansara , Mem. Sci. Rev. Metall. 88, 711( 1991) |
[30] | H. Ohta, H. Suito , ISIJ INT 46, 42 ( 2006) |
[31] | L.Z. Wang, S.F. Yang, J.S. Li, S. Zhang, J.T. Ju , Metall. Mater. Trans. B 48, 805 ( 2017) |
[32] | J.D. Robson, D.T. Henry, B. Davis , Acta Mater. 57, 2739( 2009) |
[33] | D.S. Gandel, M.A. Easton, M.A. Gibson, N. Birbilis , Mater. Chem. Phys. 143, 1082( 2014) |
[34] | G.L. Song, A. Atrens, M. Liu, Z.M. Shi, F.Y. Cao, M.S. Dargusch , Adv. Eng. Mater. 17, 400( 2015) |
[35] | B.Y. Qian, W. Miao, M. Qiu, F. Gao, D.H. Hu, J.F. Sun, R.Z. Wu, B. Krit, S. Betsofen , Acta Metall. Sin. Engl. Lett. 32, 194( 2019) |
[36] | L. Kumari, W.Z. Li, C.H. Vannoy, R.M. Leblanc, D.Z. Wang , Ceram. Int. 35, 3355( 2009) |
[37] | K.A. Yasakau, D. Hoeche, S.L. Lamaka, M.G. S. Corrosion 73, 583 ( 2017) |
[38] | S. Thomas, N.V. Medhekar, G.S. Frankel, N. Birbilis , Curr. Opin. Solid. State Mater. Sci. 19, 85( 2015) |
[1] | Chongfeng Sun, Shengqi Xi, Xiaofeng Dang, Jianping Li, Yongchun Guo, Zhong Yang, Yaping Bai. Formation of Fe-19 wt%Cr-9 wt%Ni Nanocrystalline Alloy with Excellent Corrosion Resistance: Phase Transition and Microstructure [J]. Acta Metallurgica Sinica (English Letters), 2021, 34(6): 825-833. |
[2] | Zheng-Zheng Yin, Wei Zhao, Jing Xu, Rong-Chang Zeng, Feng-Qin Wang, Zhen-Lin Wang. Corrosion Resistance of Superhydrophobic Mg(OH)2/Calcium Myristate Composite Coating on Magnesium Alloy AZ31 [J]. Acta Metallurgica Sinica (English Letters), 2021, 34(12): 1618-1634. |
[3] | Ben-Qi Xu, Hui Zhang, Dong Ma, Qun-Shuang Ma, Li-Zhai Pei. Ageing Hardening Mechanism and Corrosion Resistance in the Fe65Cr13Cu3(CoMnMoNiAlTi)19 Medium-Entropy Stainless Alloy [J]. Acta Metallurgica Sinica (English Letters), 2021, 34(11): 1601-1608. |
[4] | Mingming Zhang, Yipeng Feng, Yahui Wang, Yunsong Niu, Li Xin, Yongfeng Li, Jianxiu Su, Shenglong Zhu, Fuhui Wang. Corrosion Behaviors of Nitride Coatings on Titanium Alloy in NaCl-Induced Hot Corrosion [J]. Acta Metallurgica Sinica (English Letters), 2021, 34(10): 1434-1446. |
[5] | Zheng-Zheng Yin, Zhao-Qi Zhang, Xiu-Juan Tian, Zhen-Lin Wang, Rong-Chang Zeng. Corrosion Resistance and Durability of Superhydrophobic Coating on AZ31 Mg Alloy via One-Step Electrodeposition [J]. Acta Metallurgica Sinica (English Letters), 2021, 34(1): 25-38. |
[6] | Yuanyuan Liu, Zhongmin Lang, Jinlong Cui, Shengli An. Performance of Nb0.8Zr0.2 Layer-Modified AISI430 Stainless Steel as Bipolar Plates for Direct Formic Acid Fuel Cells [J]. Acta Metallurgica Sinica (English Letters), 2021, 34(1): 77-84. |
[7] | Xigang Yang, Yun Zhou, Ruihua Zhu, Shengqi Xi, Cheng He, Hongjing Wu, Yuan Gao. A Novel, Amorphous, Non-equiatomic FeCrAlCuNiSi High-Entropy Alloy with Exceptional Corrosion Resistance and Mechanical Properties [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(8): 1057-1063. |
[8] | P. F. Zhou, D. H. Xiao, T. C. Yuan. Microstructure, Mechanical and Corrosion Properties of AlCoCrFeNi High-Entropy Alloy Prepared by Spark Plasma Sintering [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(7): 937-946. |
[9] | Haifei Zhou, Zhouhai Qian, Mengcheng Zhou, Xuebing Liu, Yong Li, Xinfang Zhang. Synergistic Balance of Strength and Corrosion Resistance in Al-Mg-Er Alloys [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(5): 659-670. |
[10] | Li-Mei Liu, Yu-Xiang Lai, Chun-Hui Liu, Jiang-Hua Chen. Optimized Combinatorial Properties of an AlMgSi(Cu) Alloy Achieved by a Mechanical-Thermal Combinatorial Process [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(5): 751-758. |
[11] | Jing-Jing Dong, Lin Fan, Hai-Bing Zhang, Li-Kun Xu, Li-Li Xue. Electrochemical Performance of Passive Film Formed on Ti-Al-Nb-Zr Alloy in Simulated Deep Sea Environments [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(4): 595-604. |
[12] | Hao-Yi Niu, Fang-Fang Cao, Kun-Kun Deng, Kai-Bo Nie, Jin-Wen Kang, Hong-Wei Wang. Microstructure and Corrosion Behavior of the As-Extruded Mg-4Zn-2Gd-0.5Ca Alloy [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(3): 362-374. |
[13] | Yu-Fen Zhang, Sha-Wei Tang, Tie-Gui Lin, Guang-Yi Liu, Jin Hu. Corrosion Properties of Calcium Stearate-Based Hydrophobic Coatings on Anodized Magnesium Alloy [J]. Acta Metallurgica Sinica (English Letters), 2019, 32(9): 1111-1121. |
[14] | S. M. A. Shibli, K. S. Chinchu, M. Ameen Sha. Development of Nano-tetragonal Zirconia-Incorporated Ni-P Coatings for High Corrosion Resistance [J]. Acta Metallurgica Sinica (English Letters), 2019, 32(4): 481-494. |
[15] | Peng-Peng Wu, Kun-Kun Deng, Kai-Bo Nie, Zhong-Zhong Zhang. Corrosion Resistance of AZ91 Mg Alloy Modified by High-Current Pulsed Electron Beam [J]. Acta Metallurgica Sinica (English Letters), 2019, 32(2): 218-226. |
Viewed | ||||||
Full text |
|
|||||
Abstract |
|
|||||