Acta Metallurgica Sinica (English Letters) ›› 2019, Vol. 32 ›› Issue (1): 10-22.DOI: 10.1007/s40195-018-0793-6
Special Issue: 2019年镁合金专辑; 2019年腐蚀专辑-2
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Luan-Xiang Wang1, Ren-Bo Song1(), Chang-Hong Cai1, Jing-Yuan Li1
Received:
2018-05-08
Revised:
2018-06-05
Online:
2019-01-10
Published:
2019-01-18
Contact:
Song Ren-Bo
About author:
Author brief introduction:Dao-Kui Xu Professor of IMR, CAS, and “Young Merit Scholar” of Corrosion Center in the Institute of Metal Research (IMR), Chinese Academy of Sciences (CAS). He achieved Ph.D. degree from IMR, CAS, in 2008, during which he obtained “Chinese Academy of Sciences-BHP Billiton” Scholarship award, “Shi Changxu” Scholarship award and “Zhu-LiYueHua” Excellent Doctorate Student Scholarship of Chinese Academy of Sciences. He worked as a Research Fellow in ARC Center of Excellence, Design of Light Metals, Department of Materials Engineering, Monash University, Australia (2008.10-2011.10). He published more than 60 peer-reviewed scientific papers, attended 20 invited lectures and holds seven patents. His papers were cited more than 1200 times. His research interests mainly include: (1) fatigue behavior and fracture toughness of light metals, such as Mg, Al and Ti alloys; (2) effects of alloying, heat treatment and thermomechanical processes on the microstructural evolution and mechanical improvement of light metals; (3) corrosion, stress corrosion cracking and corrosion fatigue behavior of lightweight alloys; and (4) design of new lightweight alloys with a good balance of properties in terms of mechanical property and corrosion resistance.
Luan-Xiang Wang, Ren-Bo Song, Chang-Hong Cai, Jing-Yuan Li. Enhanced Strength and Corrosion Resistance of Mg-2Zn-0.6Zr Alloy with Extrusion[J]. Acta Metallurgica Sinica (English Letters), 2019, 32(1): 10-22.
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Alloy | Zn | Zr | Fe | Ni | Cu | Al | Mg |
---|---|---|---|---|---|---|---|
Nominal composition | 2 | 0.6 | - | - | - | - | Bal. |
Analyzed composition | 1.87 | 0.54 | < 0.01 | < 0.01 | < 0.01 | 0.06 | Bal. |
Table 1 Nominal and analyzed compositions of Mg-Zn-Zr alloys (wt%)
Alloy | Zn | Zr | Fe | Ni | Cu | Al | Mg |
---|---|---|---|---|---|---|---|
Nominal composition | 2 | 0.6 | - | - | - | - | Bal. |
Analyzed composition | 1.87 | 0.54 | < 0.01 | < 0.01 | < 0.01 | 0.06 | Bal. |
Element (at.%) | Mg | Zn | Zr |
---|---|---|---|
Area A | 65.87 | 34.07 | 0.06 |
Area B | 58.46 | 18.16 | 23.38 |
Area C | 99.36 | 0.53 | 0.11 |
Area D | 56.94 | 12.4 | 30.66 |
Area E | 99.23 | 0.68 | 0.09 |
Table 2 EDS analysis of tested alloys
Element (at.%) | Mg | Zn | Zr |
---|---|---|---|
Area A | 65.87 | 34.07 | 0.06 |
Area B | 58.46 | 18.16 | 23.38 |
Area C | 99.36 | 0.53 | 0.11 |
Area D | 56.94 | 12.4 | 30.66 |
Area E | 99.23 | 0.68 | 0.09 |
Alloy | Ecorr (VSCE) | Icorr (μA/cm2) | Eb (VSCE) | βc (mV/decade) | βa (mV/decade) | Rp (kΩ cm2) |
---|---|---|---|---|---|---|
As-cast | -?1.550 | 12.2 | -?1.501 | 178.1 | 142.2 | 2.82 |
As-extruded | -?1.498 | 5.3 | -?1.399 | 146.8 | 161.2 | 6.3 |
Table 3 Electrochemical parameters of Mg-2Zn-0.6Zr alloys in Hank’s solution attained from the polarization test
Alloy | Ecorr (VSCE) | Icorr (μA/cm2) | Eb (VSCE) | βc (mV/decade) | βa (mV/decade) | Rp (kΩ cm2) |
---|---|---|---|---|---|---|
As-cast | -?1.550 | 12.2 | -?1.501 | 178.1 | 142.2 | 2.82 |
As-extruded | -?1.498 | 5.3 | -?1.399 | 146.8 | 161.2 | 6.3 |
Fig. 8 EIS plots of Mg-2Zn-0.6Zr alloys in Hank’s solution: a Nyquist plot, b Bode plot of |Z| versus frequency, c Bode plot of degree versus frequency, d equivalent circuit
Alloy | Rs (Ω cm2) | Yo (μΩ-1 cm-2 s-1) | n | Rct (Ω cm2) | Cf (μF cm-2) | Rf (Ω cm2) |
---|---|---|---|---|---|---|
As-cast | 27.8 | 23.3 | 0.678 | 5139.2 | 4.6 | 144.2 |
As-extruded | 17.6 | 18.0 | 0.724 | 6904.7 | 1.9 | 164.4 |
Table 4 Fitting results of the EIS spectra
Alloy | Rs (Ω cm2) | Yo (μΩ-1 cm-2 s-1) | n | Rct (Ω cm2) | Cf (μF cm-2) | Rf (Ω cm2) |
---|---|---|---|---|---|---|
As-cast | 27.8 | 23.3 | 0.678 | 5139.2 | 4.6 | 144.2 |
As-extruded | 17.6 | 18.0 | 0.724 | 6904.7 | 1.9 | 164.4 |
Fig. 12 Corrosion morphologies of as-cast a, c, e and as-extruded b, d, f Mg-2Zn-0.6Zr alloys after immersion in Hank’s solution for a, b 0.5 h, c, d 12 h, e, f 5d
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