Acta Metallurgica Sinica (English Letters) ›› 2016, Vol. 29 ›› Issue (10): 951-962.DOI: 10.1007/s40195-016-0475-1

Special Issue: 2016年钢铁材料专辑

• Orginal Article • Previous Articles     Next Articles

Effects of W and Mo Additions on Wet-dry Acid Corrosion Behavior of Low-Alloy Steels Under Different O2 Concentrations

Qing-He Zhao,Wei Liu(),Shuan-Zhu Li,Bin-Li Zhang,Yi-Chun Zhu,Min-Xu Lu   

  1. Corrosion and Protection Center, Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China
  • Received:2016-04-12 Online:2016-10-10 Published:2016-11-08

Abstract:

Effects of W and Mo additions on wet-dry acid corrosion behavior of low-alloy steels under different O2 concentrations were investigated. The results showed that W and Mo-containing steels presented excellent wet-dry corrosion resistance under O2 concentrations of both 1 and 5%. The roles of W and Mo played in increasing corrosion resistance of the steels were different. W could improve the thermodynamic stability of the steel substrate, while Mo could promote the formation of protective rust. Interaction between W, Mo and O2 concentration greatly influenced wet-dry acid corrosion of low-alloy steels. W addition was more effective for depressing charge transfer process at the rust/substrate interface and presented higher enhanced effect on increasing corrosion resistance than Mo under O2 concentration of 1%. Mo was more effective on increasing rust compactness and showed higher enhanced effect on increasing corrosion resistance than W under O2 concentration of 5%.

Key words: Wet-dry acid corrosion, SteelCorrosion resistance, Electrochemical impedance spectroscopy (EIS), Rust