Synthesis and Properties of Monodisperse Superparamagnetic Mg0.8Mn0.2Fe2O4 Nanoparticles Using Polyol Reflux Method

doi:10.1007/s40195-014-0139-y

Abstract

Abstract:

Superparamagnetic monodisperse Mg_0.8Mn_0.2Fe₂O₄ nanoparticles have been successfully synthesized in liquid polyol at elevated temperature of 200°C. Diethylene glycol (DEG) used here plays dual role in synthesis as it acts as reducing agent and alternatively coats the surface of nanoparticles while synthesis and thereby maintaining uniform size and dispersibility. Powder X-ray diffraction (XRD) and magnetic measurements showed that the sample is cubic spinel and superparamagnetic at room temperature. Raman spectra confirmed the formation of the Mg_0.8Mn_0.2Fe₂O₄ nanoparticles. The nanoparticles exhibit very good stability in water due to in situ coating with DEG molecules.

Key words: Magnetic materials, Chemical synthesis, Magnetic properties, Transmission electron microscopy (TEM), X-ray diffraction, Mg0.8Mn0.2Fe2O4 nanoparticles

Sabale Sandip, Khot Vishwajeet, Jadhav Vidhya, Zhu Xiaoli, Xu Yanhong. Synthesis and Properties of Monodisperse Superparamagnetic Mg_0.8Mn_0.2Fe₂O₄ Nanoparticles Using Polyol Reflux Method[J]. Acta Metallurgica Sinica (English Letters), 2014, 27(6): 1122-1126.

Figures/Tables 4

Fig. 1 XRD pattern of Mg0.8Mn0.2Fe2O4 nanoparticles synthesized by polyol synthesis

Fig. 2 a TEM image (inset SAED pattern), b DLS spectra of Mg0.8Mn0.2Fe2O4 nanoparticles synthesized by polyol

Fig. 3 a Thermogravimetric graph, b Raman spectra of Mg0.8Mn0.2Fe2O4 nanoparticles

Fig. 4 a M-H curve at 300 and 10 K, b M-T curve of Mg0.8Mn0.2Fe2O4 nanoparticles

References 17

[1]	T.G. Altincekic, I. Boz, A. Baykal, S. Kazan, R. Topkaya, M.S. Toprak, J. Alloys Compd. 493, 493(2010)
[2]	V.M. Khot, A.B. Salunkhe, M.R. Phadatare, N.D. Thorat, S.H. Pawar, J. Phys. D Appl. Phys. 46, 0553031(2013)
[3]	M.A. Ahmed, J. Magn.Magn.Mater. 322, 763(2010)
[4]	M. Singh, S.P. Sud, Mater. Sci.Eng. B 83, 180 (2001)
[5]	S.F. Mansour, J. Magn.Magn.Mater. 323, 1735(2011)
[6]	F. Fievet, J.P. Lagier, B. Blin, M. Beaudoin, Solid State Ionics 32, 198 (1989)
[7]	C. Feldman, G.O. Jungk,Angew. Chem. Int. Ed. 40, 359(2001)
[8]	W. Cai, J. Wan,J. Colloid Interface Sci. 305, 366(2007)
[9]	E.J. Cho, H. Holback, K.C. Liu, S.A. Abouelmagd, J. Park, Y. Yeo,Mol. Pharm. 10, 2093(2013)
[10]	J. Jiang,Mater. Lett. 61, 3239(2007)
[11]	H. Deng, X. Li, Q. Peng, X. Wang, J. Chen, Y. Li,Angew. Chem. Int. Ed. 117, 2842(2005)
[12]	H. Hu, M. Mo, B. Yang, X. Zhang, Q. Li, W. Yu, Y. Qian, J.Cryst.Growth 258, 106 (2003)
[13]	W.G. Fateley, F.R. Dollish, N.T. McDevitt, F.F. Bentley,Infrared and Raman Selection Rules for Molecular and Lattice Vibrations: The Correlation Method (Weily, New York, 1972), p. 169
[14]	T. Yu, Z.X. Shen, Y. Shi, J. Ding, J. Phys.Condens.Matter 14, 613 (2002)
[15]	Y. Qu, H. Yang, N. Yang, Y. Fan, H. Zhu, G. Zou,Mater. Lett. 60, 3548(2006)
[16]	X. Cao, L. Gu, Nanotechnology 16, 180 (2005)
[17]	C. Liu, B. Zou, A.J. Rondinone, Z.J. Zhang, J. Am.Chem.Soc. 122, 6263(2000)

Synthesis and Properties of Monodisperse Superparamagnetic Mg_0.8Mn_0.2Fe₂O₄ Nanoparticles Using Polyol Reflux Method

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 4

References 17

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Ibrahim Ondicho, Bernard Alunda, Dicken Owino, Luke Otieno, Melody Chepkoech. Revealing a Transformation-Induced Plasticity (TRIP) Phenomenon in a Medium-Entropy Alloy [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(8): 1159-1165.
[2]	Xuyang Wang, Jieren Yang, Rui Hu, Zitong Gao, Jinguang Li, Hengzhi Fu. Creep-Induced Phase Instability and Microstructure Evolution of a Nearly Lamellar Ti-45Al-8.5Nb-(W, B, Y) Alloy [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(12): 1591-1600.
[3]	Liang Yang, Jun Li, Defang Tu, Joel C. J. Strickland, Qiaodan Hu, Hongbiao Dong, Jianguo Li. Reduced Annealing Time and Enhanced Magnetocaloric Effect of La(Fe, Al)₁₃ Alloy by La-nonstoichiometry and Si-doping [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(11): 1535-1542.
[4]	Wei Wang, Zong-Ning Chen, En-Yu Guo, Hui-Jun Kang, Yi Liu, Cun-Lei Zou, Ren-Geng Li, Guo-Mao Yin, Tong-Min Wang. Influence of Cryorolling on the Precipitation of Cu-Ni-Si Alloys: An In Situ X-ray Diffraction Study [J]. Acta Metallurgica Sinica (English Letters), 2018, 31(10): 1089-1097.
[5]	Rui-Yang Liang, Ping Yang, Wei-Min Mao. Effect of Initial Goss Texture Sharpness on Texture Evolution and Magnetic Properties of Ultra-thin Grain-oriented Electrical Steel [J]. Acta Metallurgica Sinica (English Letters), 2017, 30(9): 895-906.
[6]	M. Santhiya, K.S. Pugazhvadivu, K. Tamilarasan, C. Rangasami. Influence of Sputtering Power on the Structure and Electrical Properties of Bi₂Fe₄O₉ Thin Films [J]. Acta Metallurgica Sinica (English Letters), 2017, 30(7): 650-658.
[7]	Ning-Ning Li,Min-Zhi Wang,Yong-Sheng Li,Guang Chen,Pei Li. Corrosion Behavior of Fe-Al Coatings Fabricated by Pack Aluminizing Method [J]. Acta Metallurgica Sinica (English Letters), 2016, 29(9): 813-819.
[8]	M. J. Miah, A. K. M. Akther Hossain. Magnetic, Dielectric and Complex Impedance Properties of xBa_0.95Sr_0.05TiO₃-(1 - x)BiFe_0.9Gd_0.1O₃Multiferroic Ceramics [J]. Acta Metallurgica Sinica (English Letters), 2016, 29(6): 505-517.
[9]	Hong-Fei Qi, Da-Bo Liu, Song-Yan Dai, Tian-Min Wang. Magnetic Properties of Co 2D Antidot Arrays with Hexagonal Holes Using Colloidal Crystal Template Method [J]. Acta Metallurgica Sinica (English Letters), 2016, 29(5): 409-421.
[10]	Qiu-Hong Wang, Chao-Long Tang, Cheng-Ming Jiang, Dan-Feng Du, Feng Wang, Jin-Hui Song. Role of Substrate Roughness in ZnO Nanowire Arrays Growth by Hydrothermal Approach [J]. Acta Metallurgica Sinica (English Letters), 2016, 29(3): 237-242.
[11]	A. Harizi, M. Ben Rabeh, M. Kanzari. Substrate Temperature-Dependent Physical Properties of Thermally Evaporated Sn₄Sb₆S₁₃ Thin Films [J]. Acta Metallurgica Sinica (English Letters), 2016, 29(1): 79-88.
[12]	Rangasami Chinnusamy. Non-equilibrium Phases Formed in Cu-In-Se-Te System Synthesized by Melt-Quench Method [J]. Acta Metallurgica Sinica (English Letters), 2015, 28(5): 567-578.
[13]	Hossein Mostaan, Morteza Shamanian, Seyed Mahmoud Monirvaghefi, Peiman Behjati, Jerzy A. Szpunar, Morteza Amiri, Mashallah Fathi Moghadam. Structure, Texture and Magnetic Properties of Laser-Welded Ultrathin Fe-Co-V Foils [J]. Acta Metallurgica Sinica (English Letters), 2015, 28(3): 338-347.
[14]	Nikolay Velinov, Dimitar Dimitrov, Kremena Koleva, Krassimir Ivanov, Ivan Mitov. Mechanochemical Synthesis and Characterization of Nanocrystalline Copper-Cobalt Ferrites [J]. Acta Metallurgica Sinica (English Letters), 2015, 28(3): 367-372.
[15]	Neena Bachan, A. Asha, W. Jothi Jeyarani, D. Arun Kumar, J. Merline Shyla. A Comparative Investigation on the Structural, Optical and Electrical Properties of SiO₂-Fe₃O₄ Core-Shell Nanostructures with Their Single Components [J]. Acta Metallurgica Sinica (English Letters), 2015, 28(11): 1317-1325.