Acta Metallurgica Sinica (English Letters) ›› 2012, Vol. 25 ›› Issue (1): 76-80.DOI: 10.11890/1006-7191-121-76

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Magnetic transitions and magnetocaloric effect in MnAs0.9P0.1

Naikun SUN1, Feng LIU1, Yinbo GAO1, Jinjun LIU2   

  1. 1. School of Science, Shenyang Ligong University, Shenyang 110159, China
    2. Faculty of Materials Science & Chemical Engineering, Ningbo University,Ningbo 315211, China
  • Received:2011-09-20 Revised:2011-11-20 Online:2012-02-25 Published:2012-02-16
  • Contact: Naikun SUN

Abstract: The compound MnAs0.9P0.1 exhibits a multistep magnetic order-order transition from a helimagnetic γ-phase with Hα-type magnetic order to a ferromagnetic β-phase at 80 K and then to a helimagnetic α-phase at 203 K. The γ-β transition exhibits the characteristics of a first-order transition with a thermal hysteresis as large as 6 K, while the β-α transition is of second order with a thermal hysteresis smaller than 2 K and without magnetic hysteresis. With these two successive helimagnetism-related transitions, magnetic-entropy changes of -2.1 J/(kg•K) at 203~K for a field change from 0 to 5 T and 0.1 J/(kg•K) at 83 K for a field change from 0 to 1 T are obtained. Investigation of the magnetocaloric effect associated with a transition from Hα-type magnetic order to FM order may open a new route to explore candidates for magnetic refrigeration.

Key words: Magnetocaloric effect, Hysteresis, first-order transition