Acta Metallurgica Sinica (English Letters) ›› 2017, Vol. 30 ›› Issue (4): 296-305.DOI: 10.1007/s40195-017-0553-z
Special Issue: 2017腐蚀虚拟专辑
• Orginal Article • Previous Articles Next Articles
Helmuth Sarmiento Klapper1(), Natalia S. Zadorozne2, Raul B. Rebak3
Received:
2017-03-02
Revised:
2017-03-02
Online:
2017-03-02
Published:
2017-05-17
Helmuth Sarmiento Klapper, Natalia S. Zadorozne, Raul B. Rebak. Localized Corrosion Characteristics of Nickel Alloys: A Review[J]. Acta Metallurgica Sinica (English Letters), 2017, 30(4): 296-305.
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Alloy | UNS | Nominal approximate composition | Applications |
---|---|---|---|
Ni-200 | N02200 | 99Ni-0.2Mn-0.2Fe | Strong caustic environments |
Ni-301a | N03301 | 93Ni-4.5Al-0.6Ti | Fasteners, springs |
400 | N04400 | 67Ni-31.5Cu-1.2Fe | Hydrofluoric acid, CPI |
K-500a | N05500 | 63Ni-30Cu-3Al-0.5Ti | Fasteners, springs, Oil and gas |
B-2 | N10665 | 72Ni-28Mo | Hot hydrochloric acid |
B-3 | N10675 | 68.5Ni-28.5Mo-1.5Cr-1.5Fe | Reducing acids |
B-4 | N10629 | 65Ni-28Mo-4Fe-1Cr-0.3Al | Hydrochloric and sulfuric acid |
C-276 | N10276 | 59Ni-16Cr-16Mo-4 W-5Fe | Versatile CPI and pollution control |
625a | N06625 | 62Ni-21Cr-9Mo-3.7Nb | Aerospace, pollution control |
C-22 | N06022 | 59Ni-22Cr-13Mo-3 W-3Fe | FGD, CPI, nuclear waste |
2000 | N06200 | 59Ni-23Cr-16Mo-1.6Cu | CPI, oxidizing and reducing. Sulfuric acid |
59 | N06059 | 59Ni-23Cr-16Mo-1Fe | Oxidizing and reducing acids, CPI |
686 | N06686 | 46Ni-21Cr-16Mo-4 W-5Fe | Oxidizing and reducing acids, CPI |
C-22HSa | N07022 | 59Ni-21Cr-17Mo | Oil and gas |
Hy-BC | N10362 | 62Ni-15Cr-22Mo | Hydrochloric and sulfuric acid |
600 | N06600 | 76Ni-15.5Cr-8Fe | Nuclear power |
690 | N06690 | 58Ni-29Cr-9Fe | Nuclear power |
718a | N07718 | 53Ni-19Cr-18Fe-5Nb-3Mo-1Ti-0.5Al | Oil and gas |
716a | N07716 | 57Ni-21Cr-18Fe-8Mo-3.4Nb-1.4Ti-0.3Al | Oil and gas |
725a | N07725 | 57Ni-21Cr-18Fe-8Mo-3.4Nb-1.4Ti-0.3Al | Oil and gas |
X-750a | N07750 | 73Ni-15Cr-7Fe-2.5Ti-1Nb-0.7Al | Nuclear power |
825 | N08825 | 43Ni-21Cr-30Fe-3Mo-2.2Cu-1Ti | Oil and gas. Sulfuric and phosphoric acid |
925a | N09925 | 44Ni-21Cr-22Fe-3Mo-2Ti-0.3Al-2Cu | Oil and gas |
945a | N09945 | 50Ni-21Cr-18Fe-3Mo-3Nb-1.5Ti-0.3Al-2Cu | Oil and gas |
G-30 | N06030 | 44Ni-30Cr-15Fe-5Mo-2Cu-2.5 W-4Co | Nitric and phosphoric acid |
T21 | N06210 | Ni-19Cr-19Mo-1.8Ta | Resistant to localized attack |
Table 1 Nickel based corrosion-resistant alloys
Alloy | UNS | Nominal approximate composition | Applications |
---|---|---|---|
Ni-200 | N02200 | 99Ni-0.2Mn-0.2Fe | Strong caustic environments |
Ni-301a | N03301 | 93Ni-4.5Al-0.6Ti | Fasteners, springs |
400 | N04400 | 67Ni-31.5Cu-1.2Fe | Hydrofluoric acid, CPI |
K-500a | N05500 | 63Ni-30Cu-3Al-0.5Ti | Fasteners, springs, Oil and gas |
B-2 | N10665 | 72Ni-28Mo | Hot hydrochloric acid |
B-3 | N10675 | 68.5Ni-28.5Mo-1.5Cr-1.5Fe | Reducing acids |
B-4 | N10629 | 65Ni-28Mo-4Fe-1Cr-0.3Al | Hydrochloric and sulfuric acid |
C-276 | N10276 | 59Ni-16Cr-16Mo-4 W-5Fe | Versatile CPI and pollution control |
625a | N06625 | 62Ni-21Cr-9Mo-3.7Nb | Aerospace, pollution control |
C-22 | N06022 | 59Ni-22Cr-13Mo-3 W-3Fe | FGD, CPI, nuclear waste |
2000 | N06200 | 59Ni-23Cr-16Mo-1.6Cu | CPI, oxidizing and reducing. Sulfuric acid |
59 | N06059 | 59Ni-23Cr-16Mo-1Fe | Oxidizing and reducing acids, CPI |
686 | N06686 | 46Ni-21Cr-16Mo-4 W-5Fe | Oxidizing and reducing acids, CPI |
C-22HSa | N07022 | 59Ni-21Cr-17Mo | Oil and gas |
Hy-BC | N10362 | 62Ni-15Cr-22Mo | Hydrochloric and sulfuric acid |
600 | N06600 | 76Ni-15.5Cr-8Fe | Nuclear power |
690 | N06690 | 58Ni-29Cr-9Fe | Nuclear power |
718a | N07718 | 53Ni-19Cr-18Fe-5Nb-3Mo-1Ti-0.5Al | Oil and gas |
716a | N07716 | 57Ni-21Cr-18Fe-8Mo-3.4Nb-1.4Ti-0.3Al | Oil and gas |
725a | N07725 | 57Ni-21Cr-18Fe-8Mo-3.4Nb-1.4Ti-0.3Al | Oil and gas |
X-750a | N07750 | 73Ni-15Cr-7Fe-2.5Ti-1Nb-0.7Al | Nuclear power |
825 | N08825 | 43Ni-21Cr-30Fe-3Mo-2.2Cu-1Ti | Oil and gas. Sulfuric and phosphoric acid |
925a | N09925 | 44Ni-21Cr-22Fe-3Mo-2Ti-0.3Al-2Cu | Oil and gas |
945a | N09945 | 50Ni-21Cr-18Fe-3Mo-3Nb-1.5Ti-0.3Al-2Cu | Oil and gas |
G-30 | N06030 | 44Ni-30Cr-15Fe-5Mo-2Cu-2.5 W-4Co | Nitric and phosphoric acid |
T21 | N06210 | Ni-19Cr-19Mo-1.8Ta | Resistant to localized attack |
Alloy | UNS | Approximate composition | Common high-temperature use |
---|---|---|---|
75 | N06075 | 78Ni-20Cr-0.4Ti | Gas turbines, heat treatment |
230 | N06230 | 57Ni-22Cr-14 W-2Mo-0.3Al-0.02La | Gas turbines, super heater tubes |
600 | N06600 | 75Ni-16Cr-9Fe | Furnace components |
601 | N06601 | 60Ni-23Cr-15Fe-1.4Al-0.3Ti | Furnace and heat treatment components, Combustion chambers |
X | N06602 | 47Ni-22Cr-18Fe-9Mo-1.5Co-0.6 W | Combustion chambers, heat treatment components |
617 | N06617 | 55Ni-22Cr-12Co-9Mo-1Al | Gas turbine combustion cans, furnace components |
625 | N06625 | 62 Ni-21Cr-9Mo-3.7Nb | Aerospace, pollution control equipment |
214 | N07214 | 75Ni-16Cr-4.5Al-3Fe-0.01Y | Specialized heat treatment, turbine parts |
718 | N07718 | 53Ni-19Cr-18Fe-5Nb-3Mo-1Ti-0.5Al | Gas turbines, rocket engines, nuclear applications |
X-750 | N07750 | 72Ni-16Cr-7Fe-2.5Ti-1Nb-0.6Al | Gas turbine components, pressure vessels, applications in nuclear reactors |
800HT | N08811 | 31Ni-45Fe-21Cr-0.4Al-0.6Ti | Industrial furnaces, carburizing equipment |
242 | N10242 | 65Ni-25Mo-8Cr | Turbine seal rings, fasteners |
160 | N12160 | 37Ni-29Co-28Cr-2.75Si-2Fe | Thermocouple shields, calciner components |
120 | N08120 | 33Fe-37Ni-25Cr-0.7Nb-0.2N | Carburizing and sulfidizing environments |
282 | N07208 | 57Ni-20Cr-10Co-8.5Mo-2.1Ti-1.5Al | Age hardenable with creep resistance |
Table 2 Nickel-based high-temperature alloys
Alloy | UNS | Approximate composition | Common high-temperature use |
---|---|---|---|
75 | N06075 | 78Ni-20Cr-0.4Ti | Gas turbines, heat treatment |
230 | N06230 | 57Ni-22Cr-14 W-2Mo-0.3Al-0.02La | Gas turbines, super heater tubes |
600 | N06600 | 75Ni-16Cr-9Fe | Furnace components |
601 | N06601 | 60Ni-23Cr-15Fe-1.4Al-0.3Ti | Furnace and heat treatment components, Combustion chambers |
X | N06602 | 47Ni-22Cr-18Fe-9Mo-1.5Co-0.6 W | Combustion chambers, heat treatment components |
617 | N06617 | 55Ni-22Cr-12Co-9Mo-1Al | Gas turbine combustion cans, furnace components |
625 | N06625 | 62 Ni-21Cr-9Mo-3.7Nb | Aerospace, pollution control equipment |
214 | N07214 | 75Ni-16Cr-4.5Al-3Fe-0.01Y | Specialized heat treatment, turbine parts |
718 | N07718 | 53Ni-19Cr-18Fe-5Nb-3Mo-1Ti-0.5Al | Gas turbines, rocket engines, nuclear applications |
X-750 | N07750 | 72Ni-16Cr-7Fe-2.5Ti-1Nb-0.6Al | Gas turbine components, pressure vessels, applications in nuclear reactors |
800HT | N08811 | 31Ni-45Fe-21Cr-0.4Al-0.6Ti | Industrial furnaces, carburizing equipment |
242 | N10242 | 65Ni-25Mo-8Cr | Turbine seal rings, fasteners |
160 | N12160 | 37Ni-29Co-28Cr-2.75Si-2Fe | Thermocouple shields, calciner components |
120 | N08120 | 33Fe-37Ni-25Cr-0.7Nb-0.2N | Carburizing and sulfidizing environments |
282 | N07208 | 57Ni-20Cr-10Co-8.5Mo-2.1Ti-1.5Al | Age hardenable with creep resistance |
UNS | Element (wt%)a | PREb | CPT (°C) | CCT (°C) | ||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
Cr | Mo | W | Env1c | Env2d | Env3e | Env4f | Env1g | Env2d | Env3e | Env4f | ||
N07718 | 17.0 | 2.8 | 26 | 45 | 45 | <10 | ≤ 25 | |||||
N08825 | 19.5 | 2.5 | 28 | 30 | 25 | 5 | -5 | |||||
N09925 | 19.5 | 2.5 | 28 | 35 | ||||||||
N09946 | 19.5 | 3.0 | 29 | 45 | ||||||||
N07716 | 19.0 | 7.0 | 42 | >85 | 35 | |||||||
N07725 | 19.0 | 7.0 | 42 | >85 | 75 | 25 | ||||||
N06625 | 20.0 | 8.0 | 46 | >85 | 75 | 90 | 41 | 35 | 85 | 50 | ||
N06022 | 20.0 | 12.5 | 2.5 | 65 | >85 | 120 | 150 | 75 | 105 | 102 | ||
N10276 | 14.5 | 15.0 | 3.0 | 69 | >85 | 105 | 150 | 83 | 50 | 105 | 80 | |
N07022 | 20.0 | 15.5 | 71 | >85 | >120 | 100 | ||||||
N06059 | 22.0 | 15.0 | 72 | >85 | >120 | 100 | 110 | |||||
N06686 | 19.0 | 15.0 | 3.0 | 73 | >85 | >120 | 110 |
Table 3 CPT and CCT for selected Ni alloys in different testing environments (Env)
UNS | Element (wt%)a | PREb | CPT (°C) | CCT (°C) | ||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
Cr | Mo | W | Env1c | Env2d | Env3e | Env4f | Env1g | Env2d | Env3e | Env4f | ||
N07718 | 17.0 | 2.8 | 26 | 45 | 45 | <10 | ≤ 25 | |||||
N08825 | 19.5 | 2.5 | 28 | 30 | 25 | 5 | -5 | |||||
N09925 | 19.5 | 2.5 | 28 | 35 | ||||||||
N09946 | 19.5 | 3.0 | 29 | 45 | ||||||||
N07716 | 19.0 | 7.0 | 42 | >85 | 35 | |||||||
N07725 | 19.0 | 7.0 | 42 | >85 | 75 | 25 | ||||||
N06625 | 20.0 | 8.0 | 46 | >85 | 75 | 90 | 41 | 35 | 85 | 50 | ||
N06022 | 20.0 | 12.5 | 2.5 | 65 | >85 | 120 | 150 | 75 | 105 | 102 | ||
N10276 | 14.5 | 15.0 | 3.0 | 69 | >85 | 105 | 150 | 83 | 50 | 105 | 80 | |
N07022 | 20.0 | 15.5 | 71 | >85 | >120 | 100 | ||||||
N06059 | 22.0 | 15.0 | 72 | >85 | >120 | 100 | 110 | |||||
N06686 | 19.0 | 15.0 | 3.0 | 73 | >85 | >120 | 110 |
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