Acta Metallurgica Sinica (English Letters) ›› 2025, Vol. 38 ›› Issue (2): 177-204.DOI: 10.1007/s40195-024-01799-6
Yingying Fu1, Zhihao Yao1(), Yang Chen1, Hongying Wang1, Yajing Li1, Jianxin Dong1
Received:
2024-07-15
Revised:
2024-09-10
Accepted:
2024-10-11
Online:
2025-02-10
Published:
2024-12-07
Contact:
Zhihao Yao, Yingying Fu, Zhihao Yao, Yang Chen, Hongying Wang, Yajing Li, Jianxin Dong. Progress in the Deposition Mechanisms and Key Performance Evaluation of Thermal Barrier Coatings for Turbine Blades: A Review[J]. Acta Metallurgica Sinica (English Letters), 2025, 38(2): 177-204.
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Materials | Advantages | Disadvantages |
---|---|---|
7-8YSZ [ | High thermal expansion coefficient, Good impact resistance Low thermal conductivity, High fracture toughness | Sintering above 1200 °C, Phase transition occurs at 1170 °C, Oxygen permeable material, Corrosion |
A2B2O7 structure pyrochlore [ | High thermal stability, Low thermal conductivity, Low sintering tendency | Low fracture toughness |
Multicomponent rare earth oxides doped zirconia [ | Low thermal conductivity, High thermal stability, High thermal expansion coefficient | Low fracture toughness, Low thermal cycling lifetime |
Magnetoplumbite compounds [ | Excellent phase stability above 1600 °C, High thermal expansion coefficient | Low fracture toughness |
Garnet structure compounds (RE3Al5O12) (e.g., Y3Al5O12) [ | Low thermal conductivity, High-temperature stability | Low thermal expansion coefficient, An amorphous phase is produced during the spraying process |
ABO3 perovskites (e.g., SrZrO3) [ | High melting point, Good cycling performance above 1250 °C | Phase transformation, Low fracture toughness |
Table 1 Ceramic materials and their properties
Materials | Advantages | Disadvantages |
---|---|---|
7-8YSZ [ | High thermal expansion coefficient, Good impact resistance Low thermal conductivity, High fracture toughness | Sintering above 1200 °C, Phase transition occurs at 1170 °C, Oxygen permeable material, Corrosion |
A2B2O7 structure pyrochlore [ | High thermal stability, Low thermal conductivity, Low sintering tendency | Low fracture toughness |
Multicomponent rare earth oxides doped zirconia [ | Low thermal conductivity, High thermal stability, High thermal expansion coefficient | Low fracture toughness, Low thermal cycling lifetime |
Magnetoplumbite compounds [ | Excellent phase stability above 1600 °C, High thermal expansion coefficient | Low fracture toughness |
Garnet structure compounds (RE3Al5O12) (e.g., Y3Al5O12) [ | Low thermal conductivity, High-temperature stability | Low thermal expansion coefficient, An amorphous phase is produced during the spraying process |
ABO3 perovskites (e.g., SrZrO3) [ | High melting point, Good cycling performance above 1250 °C | Phase transformation, Low fracture toughness |
Materials | Synthetic method |
---|---|
7-8YSZ | Solid-state sintering [ |
A2B2O7 structure pyrochlore | Solid-state reaction [ |
Multicomponent rare earth oxides doped zirconia | Sol-gel [ |
Magnetoplumbite compounds | Solid-state reaction [ |
Garnet structure compounds | Sol-gel [ |
ABO3 perovskites | Solid-state reaction [ |
Table 2 Ceramic materials synthetic methods
Materials | Synthetic method |
---|---|
7-8YSZ | Solid-state sintering [ |
A2B2O7 structure pyrochlore | Solid-state reaction [ |
Multicomponent rare earth oxides doped zirconia | Sol-gel [ |
Magnetoplumbite compounds | Solid-state reaction [ |
Garnet structure compounds | Sol-gel [ |
ABO3 perovskites | Solid-state reaction [ |
Technology | APS | EB-PVD | PS-PVD |
---|---|---|---|
Microstructure [ | Lamellar-structure | Columnar structured | Lamellar-structure, columnar structured, quasi-columnar structured |
Depositional mode [ | Line-of-sight deposition | Line-of-sight deposition | Non-line-of-sight deposition |
Substrate temperature (K) [ | ~ 650 | ~ 1300 | ~ 1300 |
Plasma temperature/evaporating temperature (°C) [ | 8000-10000 | 2000-3500 | 10000-16000 |
Pressure (mbar) [ | ~ 1000 | ≤ 5.0 × 10-3 | 0.5-2.0 |
Deposition rate (μm/h) [ | ~ 600 | 240-600 | up to 1500 |
Advantages [ | Low thermal conductivity, low elastic modulus, high deposition efficiency, wide application range, low cost | Good thermal shock resistance, high bonding strength, high density of coating, good corrosion and oxidation resistance, good surface finish | Non-line sight deposition, high deposition rate, microstructural flexibility |
Disadvantages [ | Low bonding strength, loose structure, low thermal cycle life | Low thermal conductivity, good thermal shock resistance, high sedimentation rate, high thermal cycle life, high-cost | High cost, complex operation |
Table 3 Different characteristics of TBCs preparation by APS, EB-PVD, and PS-PVD
Technology | APS | EB-PVD | PS-PVD |
---|---|---|---|
Microstructure [ | Lamellar-structure | Columnar structured | Lamellar-structure, columnar structured, quasi-columnar structured |
Depositional mode [ | Line-of-sight deposition | Line-of-sight deposition | Non-line-of-sight deposition |
Substrate temperature (K) [ | ~ 650 | ~ 1300 | ~ 1300 |
Plasma temperature/evaporating temperature (°C) [ | 8000-10000 | 2000-3500 | 10000-16000 |
Pressure (mbar) [ | ~ 1000 | ≤ 5.0 × 10-3 | 0.5-2.0 |
Deposition rate (μm/h) [ | ~ 600 | 240-600 | up to 1500 |
Advantages [ | Low thermal conductivity, low elastic modulus, high deposition efficiency, wide application range, low cost | Good thermal shock resistance, high bonding strength, high density of coating, good corrosion and oxidation resistance, good surface finish | Non-line sight deposition, high deposition rate, microstructural flexibility |
Disadvantages [ | Low bonding strength, loose structure, low thermal cycle life | Low thermal conductivity, good thermal shock resistance, high sedimentation rate, high thermal cycle life, high-cost | High cost, complex operation |
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[1] | D.B.Zhang, S.K.Gong, H.B.Xu. THE INFLUENCE OF Mo DIFFUSION ON THE THERMAL BEHAVIOR OF TBCs ON Ni3Al BASED ALLOY IC-6 [J]. Acta Metallurgica Sinica (English Letters), 2002, 15(1): 45-48 . |
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