Acta Metallurgica Sinica (English Letters) ›› 2002, Vol. 15 ›› Issue (2): 154-159 .

• Research Articles • Previous Articles     Next Articles

CORROSION AND MECHANICAL BEHAVIOR OF COPPER- NIOBIUM NANO-FILAMENTARY MICRO-COMPOSITES FOR HIGH PERFORMANCE ELECTRICAL CONDUCTOR WIRE

Y. Choi, T.W. Lim, S.I. Hong   

  1. Department of Metallurgical Engineering,Chungnam National University,Taedok Science Town,Daejeon 305-764,Korea
  • Received:2001-07-31 Revised:1900-01-01 Online:2002-04-25 Published:2009-10-10
  • Contact: Y. Choi

Abstract: Corrosion behavior of heavily drawn bundled Copper-niobium filamentary micro-composite was studied as a function of niobium content to develop the relationshipbetween microstructure and corrosion behavior in aqueous 30% HCl-FeCl3 solution.TEM observation revealed that niobium filaments were distributed regularly in coppermatrix along the sides of a triangular unit cell in the transverse section and more sub-grain boundaries were absorbed at copper/niobium phase boundaries with increasingniobium content. The corrosion potential and rate in aqueous 30% HCl-10% FeCl3 was-680.3mVSHE and 1.179×10-5A/cra2. The corrosion potential and rate decreasedas increasingniobium content and FeCl3. The yield stress can be described as thesum of the substructure strengthening component due to elongated grains, subgrainsand/or cells, the phase boundary strengthening term associated with the Hall-Petchtype interaction between dislocations and phase boundaries and precipitate strength-ening component.

Key words: Cu-Nb micro-composites, corrosion, microstructure