Acta Metallurgica Sinica (English Letters) ›› 1989, Vol. 2 ›› Issue (6): 412-417.

• Research paper • Previous Articles     Next Articles

IN-SITU ELECTRON MICROSCOPY STUDY ON PRECIPITATION OF ZIRCONIUM HYDRIDES INDUCED BY STRESS AND STRAIN IN ZIRCALOY-2

ZHOU Bangxin ZHENG Sikui WANG Shunxin Southwest Centre for Nuclear Reactor Engineering Research and Design,Chengdu,China [Originally published in ACTA METALL SIN(CHINESE EDN)25(3)1989 pp A190—A195, Southwest Centre for Nuclear Reactor Engineering Research and Design,Chengdu,China   

  • Received:1989-12-25 Revised:1989-12-25 Online:1989-12-25 Published:2009-10-10

Abstract: The precipitation process of zirconium hydrides induced by stress and strain was investigated by means of electron microscopy in-situ.The precipitating hydrides induced by stress were found to be γ phase with orientation relationship of (110)_γ‖(110)_(αZr),(001)_γ‖ (0001)_(αZr) between γ-hydrides and surrounding matrix.The growth rate of γ-hydrides which was much faster along [110] direction brought them in taper shape.After fracture of y-hydrides,a new one will precipitate at the tip of cracks.This is the essential process of hydrogen-induced delayed cracking in Zircaloy.The precipitating hydrides induced by strain were found to be δ phase with both orientation relationships of(111)_δ‖(0001)_(αZr),(110)_δ‖ (110)_(αZr) or (010)_δ‖(0001)_(αZr),(001)_δ‖(110)_(αZr)between δ-hydride and surrounding matrix.The δ-hydrides become much finer as the strain rate increased.

Key words: Zircaloy-2, precipitation of hydrides, hydrides, hydrogen-induced delayed cracking