PRODUCTION OF HIGHLY GRAPHITIZED MULTIWALlED CARBON  ANOTUBES

Abstract

Abstract: Multiwalled carbon nanotubes ( MWNTs) were prepared by DCarc dischargein hydrogen gas, and werethermally purified byinfrared radiation in air. The morphology of pristineand purified MWNTs was observed by scanning electron microscope ( SEM) , and the crys tallinestructureand perfection wereinvestigated by high resolution transmission electron mi croscope( HRTEM) and Raman spectrometer. Itcameto the conclusion thatthese MWNTs possessed a high degreeof graphitization and very narrow centralchannel(about1 0 nm indiameter) , giving risetotheappearanceof breathing modesfor MWNTs.

Key words: multiwalled carbon nanotubes, hydrogen arc, SEM, HRTEM, Raman spectrometer

X.L.Zhao1) ,T.L.Guo2) ,M.Ohkohchi3) ,T.Okazaki3) ,S.Iijima and Y.Ando3) 1) Japan Science and Technology Corporation ,Department of Physics, Meijo University ,Shiogamaguchi1 501 ,Tempaku ku , Nagoya 468 8502 ,Japan 2) Scientific Research Department,Shenyang University, Wanghuanan Street21 ,Dadong District,Shenyang 110044 ,China 3) Department of Physics, Meijo University, Shiogamaguchi 1 501,Tempaku ku, Nagoya 468 8502,Japan$. PRODUCTION OF HIGHLY GRAPHITIZED MULTIWALlED CARBON ANOTUBES[J]. Acta Metallurgica Sinica (English Letters), 1999, 12(4): 345-352.

References

1 S.Iijima,Nature 354(1991)56.
2 Y.Ando and S.Iijima,Jpn.J. Appl. Phys.32 (1993) L107.
3 T. W.Ebbesen , Physics Today 49(1996) 26 .
4 Y.Saito,T.Yoshikawa,S.Bandow , M.Tomita and T.Hayashi,Phys. Rev . B48 (1993)9 .
5 N.Hamada,S.Sawada,and A.Oshiyama, Phys. Rev. Lett.68(1992) 1579 .
6 K.Harigaya, Phys. Rev . B45(1992) 12071 .
7 R.Saito, M.Fujita, G. Dresselhausand M.S. Dresselhaus, Appl. Phys. Lett.60 (1992)2204 .
8 R.Saito, M.Fujita,G.Dresselhausand M.S.Dresselhaus, Phys. Rev . B46(1992) 1804.
9 K.Harigaya and M.Fujita, Phys. Rev. B47 (1993) 16563 .
10 R.Saito,G.Dresselhausand M.S.Dresselhaus, Physical Propertiesof Carbon Nanotubes(Imperial College Press,London ,1998) .
11 S.Iijima and T.Ichihashi, Nature 363 (1993) 603 .
12 D.S.Bethune,C.H.Kiang, M.S.de Vries,G.Gorman,R.Savoy,J.Vazquezand R.Beyers, Nature 363(1993) 605.
13 T. W.Ebbesen and P. M.Ajayan, Nature 358(1992) 220.
14 T.Guo,P.Nikolaev,A.Thess,D.T.Colbertand R.E.Smalley,Chem . Phys. Lett.243(1995) 49.
15 C.Journet, W.K. Maser,P.Bernier,A.Loiseau, M.Lamy dela Chapelle,S.Lefrant,P.Deniard,R.Lee and J.E.Fischer, Nature 388 (1997) 756 .
16 T. W.Ebbesen,P. M.Ajayan,H. Hiuraand K.Tanigaki, Nature 367(1994) 519 .
17 K.Tohji,T.Goto,H.Takahashi,Y.Shinoda,N.Shimizu,B.Jeyadevan,I. Matsuoka,Y.Saito,A. Kasuya,T.Ohsuna,K. Hiraga and Y.Nishina, Nature 383(1996) 679 .
18 M. M.J.Treacy,T. W.Ebbesen and J. M.Gibson, Nature 381 (1996) 678 .
19 T. W.Ebbesen,H.J.Lezec,H.Hiura,J. W.Bennett,H.F.Ghaemiand T.Thio, Nature 382(1996) 54 .
20 S.J.Tans, M. H. Devoret, H.Dai,A. Thess, R. E.Smalley, L.J. Geerligs and C.Dekker, Nature 386(1997) 474 .
21 H.Dai,J. H. Hafner, A. G. Rinzler, D. T. Colbert and R. E.Smalley, Nature 384(1996) 147 .
22 Y.Saito,S.Uemura and K. Hamaguchi,Jpn . J. Appl. Phys.37 (1998) L346.
23 W.Z.Li,S.S.Xie,L.X.Qian,B.H.Chang,B.S.Zou, W.Y.Zhou,R.A.Zhaoand G. Wang, Science 274(1996) 1701.
24 Z. W.Pan ,S.S.Xie,B.H.Chang,C. Y. Wang,L.Lu, W.Liu, W.Y.Zhou, W.Z.Liand L.X. Qian, Nature 394 (1998) 631 .
25 X.Zhao, M. Ohkohchi, M. Wang, S.Iijima, T.Ichihashi and Y. Ando, Carbon , 35(1997) 775 .
26 Y.Ando,X.Zhao and M.Ohkohchi,Jpn . J. Appl. Phys.37 (1998) L61.
27 Y.Ando,X.Zhao and M.Ohkohchi, Carbon 35(1997) 153.
28 X.Zhao and Y.Ando,Jpn . J. Appl. Phys.37(1998) 4846.
29 Y.Ando,X.Zhao and H.Shimoyama,J.Electron Microsc.in submitting.
30 H. Kataura, Y. Achiba, X. Zhao and Y. Ando, Proc.16th Fullerene Sympo.Okazaki(1999) 116 .
31 A. M.Rao,E.Richer,S.Bandow ,B.Chase,P.C.Eklund,K.A. Williams,S.Fang ,K.R.Subbaswamy, M. Menon, A. Thess, R.E.Smalley, G. Dresselhaus and M.S.Dresselhaus, Science275 (1997) 187.

[1]	Jagdish Kaur, Ramneek Kaur, S. K. Tripathi. Silver Dopant-Induced Effect on Structural and Optoelectronic Properties of CdSe Thin Films [J]. Acta Metallurgica Sinica (English Letters), 2019, 32(5): 541-549.
[2]	Lin Jiang, Liang Zhang, Zhi-Quan Liu. Optimal Design of Co/In/Cu Sputtering Target Assembly Using Finite Element Method and Taguchi Method [J]. Acta Metallurgica Sinica (English Letters), 2019, 32(11): 1407-1414.
[3]	En-Yang Liu, Si-Rong Yu, Ming Yuan, Fan-Guo Li, Yan Zhao, Wei Xiong. Effects of Semi-solid Isothermal Heat Treatment on Microstructures and Damping Capacities of Fly Ash Cenosphere/AZ91D Composites [J]. Acta Metallurgica Sinica (English Letters), 2018, 31(9): 953-962.
[4]	Yong-Jin Wang, Ren-Bo Song, Ren-Feng Song. Phase Transformation and Carbide Precipitation of Functional Gradient Semi-solid 9Cr18 Steel [J]. Acta Metallurgica Sinica (English Letters), 2018, 31(8): 823-830.
[5]	Jin-Long Fu, Hong-Jun Jiang, Kai-Kun Wang. Influence of Processing Parameters on Microstructural Evolution and Tensile Properties for 7075 Al Alloy Prepared by an ECAP-Based SIMA Process [J]. Acta Metallurgica Sinica (English Letters), 2018, 31(4): 337-350.
[6]	Kapil Sirohi, Suresh Kumar, Virender Singh, Anil Vohra. Synthesis and Characterization of CdO-SnO₂ Nanocomposites Prepared by Hydrothermal Method [J]. Acta Metallurgica Sinica (English Letters), 2018, 31(3): 254-262.
[7]	Dan-Dan Liang, Xian-Shun Wei, Chun-Tao Chang, Jia-Wei Li, Yong Wang, Xin-Min Wang, Jun Shen. Effects of W Addition on the Electrochemical Behaviour and Passive Film Properties of Fe-Based Amorphous Alloys in Acetic Acid Solution [J]. Acta Metallurgica Sinica (English Letters), 2018, 31(10): 1098-1108.
[8]	Ajit Mishra. Corrosion Study of Base Material and Welds of a Ni-Cr-Mo-W Alloy [J]. Acta Metallurgica Sinica (English Letters), 2017, 30(4): 326-332.
[9]	Liang Fan, Fujian Tang, Signo T. Reis, Genda Chen, Michael L. Koenigstein. Corrosion Resistance of Transmission Pipeline Steel Coated with Five Types of Enamels [J]. Acta Metallurgica Sinica (English Letters), 2017, 30(4): 390-398.
[10]	Xiao-Lin Li, Cheng-Shuai Lei, Xiang-Tao Deng, Yan-Mei Li, Yong Tian, Zhao-Dong Wang, Guo-Dong Wang. Carbide Precipitation in Ferrite in Nb-V-Bearing Low-Carbon Steel During Isothermal Quenching Process [J]. Acta Metallurgica Sinica (English Letters), 2017, 30(11): 1067-1079.
[11]	A. Alshareef,K. Laird,R. B. M. Cross. Chemical Synthesis of Copper Nanospheres and Nanocubes and Their Antibacterial Activity Against Escherichia coli and Enterococcus sp. [J]. Acta Metallurgica Sinica (English Letters), 2017, 30(1): 29-35.
[12]	Paolo Ferro,Alberto Fabrizi,Franco Bonollo. Non-isothermal Dissolution Modelling of Sigma Phase in Duplex Stainless Steels [J]. Acta Metallurgica Sinica (English Letters), 2016, 29(9): 859-868.
[13]	Nour El-Houda Fares, Nadir Bouarissa. Positron Affinity, Deformation Potential and Diffusion Constant in Al_xIn_1-_xSb Ternary Semiconductor Alloys [J]. Acta Metallurgica Sinica (English Letters), 2016, 29(7): 661-667.
[14]	Xin-Liang Gao,Yi Han Gui-Qin Fu,Miao-Yong Zhu,Xing-Zhong Zhang. Evolution of the Rust Layers Formed on Carbon and Weathering Steels in Environment Containing Chloride Ions [J]. Acta Metallurgica Sinica (English Letters), 2016, 29(11): 1025-1036.
[15]	Min Sun, Yuan-Yuan Yang, Ming Luo, Lai-Zhu Jiang, Yi-Ming Jiang, Jin Li. Investigation of Susceptibility to Intergranular Corrosion of Tin-Added Austenitic Stainless Steel [J]. Acta Metallurgica Sinica (English Letters), 2015, 28(9): 1183-1189.

PRODUCTION OF HIGHLY GRAPHITIZED MULTIWALlED CARBON ANOTUBES

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments