Nano-SnO2 Decorated Carbon Cloth as Flexible, Self-supporting and Additive-Free Anode for Sodium/Lithium-Ion Batteries

doi:10.1007/s40195-020-01001-7

金属学报英文版 ›› 2021, Vol. 34 ›› Issue (3): 390-400.DOI: 10.1007/s40195-020-01001-7

收稿日期:2019-09-28 修回日期:2019-10-24 出版日期:2021-03-10 发布日期:2021-03-10

Nano-SnO₂ Decorated Carbon Cloth as Flexible, Self-supporting and Additive-Free Anode for Sodium/Lithium-Ion Batteries

Xu Yang¹^,², Ying-Ying Wang¹, Bao-Hua Hou¹^,², Hao-Jie Liang¹^,², Xin-Xin Zhao¹^,³, Haosen Fan⁴(), Guang Wang¹(), Xing-Long Wu¹^,²^,³()

¹Faculty of Chemistry, Northeast Normal University, Changchun, 130024, China
²National and Local United Engineering Laboratory for Power Batteries, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, China
³Key Laboratory for UV Light-Emitting Materials and Technology of Ministry of Education, Northeast Normal University, Changchun, 130024, China
⁴School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou, 510006, China

Received:2019-09-28 Revised:2019-10-24 Online:2021-03-10 Published:2021-03-10
Contact: Haosen Fan,Guang Wang,Xing-Long Wu
About author:Xing-Long Wu, xinglong@nenu.edu.cn
Guang Wang, wangg923@nenu.edu.cn;
Haosen Fan, hsfan@gzhu.edu.cn;

摘要/Abstract

Abstract:

In this study, nano-sized SnO₂ decorated on carbon cloth (SnO₂/CC) is prepared through a simple and facile solid method. The nano-sized SnO₂ is uniformly distributed on the surface of carbon fibers in carbon cloth, providing sufficient free space to relieve volume expansion and reduce electrode pulverization during cycling. The as-prepared SnO₂/CC as a flexible, self-supporting and additive-free anode electrode for sodium-ion/lithium-ion batteries (SIBs/LIBs) can demonstrate outstanding electrochemical performance. SnO₂/CC after annealing at 350 °C (SC-350) as an anode for SIBs can deliver a reversible capacity of 0.587 mA h cm^-2 at the current density of 0.3 mA cm^-2 after 100 cycles. In addition, when cycling at 1.5 mA cm^-2, SC-350 can maintain 1.69 mA h cm^-2 after 500 cycles when used as LIB anode. These results illustrate that the as-prepared SnO₂/CC can be a promising flexible anode material for flexible SIBs/LIBs and provide a simple and practical method for designing new flexible electrode materials.

Key words: Flexible carbon cloth, SnO₂ coating, Sodium/lithium-ion batteries

. [J]. 金属学报英文版, 2021, 34(3): 390-400.

Xu Yang, Ying-Ying Wang, Bao-Hua Hou, Hao-Jie Liang, Xin-Xin Zhao, Haosen Fan, Guang Wang, Xing-Long Wu. Nano-SnO₂ Decorated Carbon Cloth as Flexible, Self-supporting and Additive-Free Anode for Sodium/Lithium-Ion Batteries[J]. Acta Metallurgica Sinica (English Letters), 2021, 34(3): 390-400.

图/表 9

Fig. 1 Preparation procedures of SnO2/CC anode

Fig. 2 Structure characterizations: a XRD patterns, b TG curves of CC, SC-300, SC-350, SC-400 and SC-450 (sc is the abbreviation of SnO2 content)

Fig. 3 a SEM images of SC-350; b TEM and HRTEM (inset) images of SC-350; c-f SEM images and the corresponding element mappings of SC-350; g the optical photograph of SC-350

Fig. 4 a Rate capabilities of SC-300, SC-350, SC-400 and SC-450 at various current densities from 0.15 to 3.0 mA cm-2; b cycling performance of CC, SC-300, SC-350, SC-400 and SC-450 at a current density of 0.3 mA cm-2; c Cycling performance of SC-350 at 0.75 mA cm-2

Fig. 5 a CV curves of the initial three cycles at a scanning rate of 0.1 mV/s, b the first three galvanostatic profiles of SC-350 at a current density of 0.15 mA cm-2

Fig. 6 a CV curves of the SC-350 at different scanning rates from 0.1 to 1 mV/s; b log (i) versus log (v) plots for the SC-350

Fig. 7 Electrochemical properties of SC-350: a rate performance; b galvanostatic profiles at various current densities of 0.15, 0.3, 0.45, 0.6, 0.75, 1.5 and 3 mA cm-2; c CV curves of the initial three cycles at a scanning rate of 0.1 mV/s; d the first three galvanostatic profiles at the current density of 0.15 mA cm-2; e cycling performance at 1.5 mA cm-2

Fig. 8 SC-350 electrodes after 500 cycles in sodium-ion half-cells: a XRD pattern; b SEM image; c optical photographs

Fig. 9 a Charge/discharge curves of NVPOF and SC-350 in the Na-ion half-cells at 0.2 C and 20 mA g-1 (~ 0.15 mA cm-2); b Rate performance of SC-350//NVPOF full cells. c Cycling performance of SC-350//NVPOF full cells

参考文献 48

[1]	H. Cha, Y. Lee, J. Kim, M. Park, J. Cho, Adv. Energy Mater. 8, 1801917(2018)
[2]	Z. Zhang, M. Liao, H. Lou, Y. Hu, X. Sun, H. Peng, Adv. Mater. 30, 1704261(2018)
[3]	G. Zhou, F. Li, H.-M. Cheng, Energy Environ. Sci. 7, 1307(2014)
[4]	Y. He, B. Matthews, J. Wang, L. Song, X. Wang, G. Wu, J. Mater. Chem. A 6, 735 (2018)
[5]	M. Feng, S. Wang, Y. Yu, Q. Feng, J. Yang, B. Zhang, Appl. Surf. Sci. 392, 27(2017)
[6]	B. Ahmed, D.H. Anjum, Y. Gogotsi, H.N. Alshareef, Nano Energy 34, 249 (2017)
[7]	D.H. Liu, W.H. Li, Y.P. Zheng, Z. Cui, X. Yan, D.S. Liu, J. Wang, Y. Zhang, H.Y. Lu, F.Y. Bai, J.Z. Guo, X.L. Wu, Adv. Mater. 30, 1706317(2018)
[8]	X.W. Huang, W.P. Xiao, L.Z. Zhao, J. Mol. Sci. 33, 313(2017)
[9]	W.T. Zhang, D.H. Tang, Q.S. Huo, J. Mol. Sci. 33, 460(2017)
[10]	S.Y. Liu, C.Y. Fan, Y.H. Shi, H.C. Wang, X.L. Wu, J.P. Zhang, A.C.S. Appl, Mater. Interfaces 10, 509 (2018)
[11]	Q.L. Ning, B.H. Hou, Y.Y. Wang, D.S. Liu, Z.Z. Luo, W.H. Li, Y. Yang, J.Z. Guo, X.L. Wu, A.C.S. Appl, Mater. Interfaces 10, 36902 (2018)
[12]	H.G. Wang, W. Li, D.P. Liu, X.L. Feng, J. Wang, X.Y. Yang, X.B. Zhang, Y. Zhu, Y. Zhang, Adv. Mater. 29, 1703012(2017)
[13]	L. Xiao, H. Lu, Y. Fang, M.L. Sushko, Y. Cao, X. Ai, H. Yang, J. Liu, Adv. Energy Mater. 8, 1703238(2018)
[14]	Y.X. Ren, T.S. Zhao, M. Liu, L. Wei, R.H. Zhang, Electrochim. Acta 242, 137 (2017)
[15]	P. Xu, G. Wang, J. Yan, Z. Zhang, M. Xu, S. Cai, X. Ruan, Z. Deng, Mater. Lett. 190, 56(2017)
[16]	L.Y. Yang, H.Z. Li, L.Z. Cheng, S.T. Li, J. Liu, J. Min, K.J. Zhu, H. Wang, M. Lei, J. Alloys Compd. 726, 837(2017)
[17]	L. Jabbour, R. Bongiovanni, D. Chaussy, C. Gerbaldi, D. Beneventi, Cellulose 20, 1523 (2013)
[18]	M. Jonoobi, R. Oladi, Y. Davoudpour, K. Oksman, A. Dufresne, Y. Hamzeh, R. Davoodi, Cellulose 22, 935 (2015)
[19]	S.H. Osong, S. Norgren, P. Engstrand, Cellulose 23, 93 (2015)
[20]	Q. Zhang, K. Zhou, J. Lei, W. Hu, Appl. Surf. Sci. 467-468, 992(2019)
[21]	S. Xie, S. Liu, F. Cheng, X. Lu, ChemElectroChem 5, 571 (2018)
[22]	X. Chen, Y. Ma, Adv. Mater. Technol. 3, 1800041(2018)
[23]	H.Y. Lü, X.H. Zhang, F. Wan, D.S. Liu, C.Y. Fan, H.M. Xu, G. Wang, X.L. Wu, A.C.S. Appl, Mater. Interfaces 9, 12518 (2017)
[24]	X. Gu, S. Wang, L. Wang, C. Wu, K. Xu, L. Zhao, Q. Liu, M. Ding, J. Xu, J. Nanosci. Nanotechnol. 19, 226(2019) DOI URL PMID
[25]	L. Wang, X. Xie, K.N. Dinh, Q. Yan, J. Ma, Coord. Chem. Rev. 397, 138(2019)
[26]	G.D. Park, J.-K. Lee, Y.C. Kang, Adv. Funct. Mater. 27, 1603399(2017)
[27]	J. Qin, N. Zhao, C. Shi, E. Liu, F. He, L. Ma, Q. Li, J. Li, C. He, J. Mater. Chem. A 5, 10946 (2017)
[28]	P. Zheng, Z. Dai, Y. Zhang, K.N. Dinh, Y. Zheng, H. Fan, J. Yang, R. Dangol, B. Li, Y. Zong, Q. Yan, X. Liu, Nanoscale 9, 14820 (2017) URL PMID
[29]	S. Qi, B. Xu, V.T. Tiong, J. Hu, J. Ma, Chem. Eng. J. 379, 122261(2020)
[30]	M. Wu, B. Xu, Y. Zhang, S. Qi, W. Ni, J. Hu, J. Ma, Chem. Eng. J. 381, 122558(2020)
[31]	D. Wu, C. Wang, M. Wu, Y. Chao, P. He, J. Ma, J. Energy Chem. 43, 24(2020)
[32]	D. Liu, Z.J. Liu, X. Li, W. Xie, Q. Wang, Q. Liu, Y. Fu, D. He, Small 13, 1702000 (2017)
[33]	H.B. Wu, J.S. Chen, H.H. Hng, X.W. Lou, Nanoscale 4, 2526 (2012) DOI URL PMID
[34]	B. Zhang, G. Rousse, D. Foix, R. Dugas, D.A. Corte, J.M. Tarascon, Adv. Mater. 28, 9824(2016) URL PMID
[35]	Y. Xu, B. Peng, F.M. Mulder, Adv. Energy Mater. 8, 1701847(2018) DOI URL
[36]	X. Yang, R.Y. Zhang, J. Zhao, Z.X. Wei, D.X. Wang, X.F. Bie, Y. Gao, J. Wang, F. Du, G. Chen, Adv. Energy Mater. 8, 1701827(2018)
[37]	B. Qu, C. Ma, G. Ji, C. Xu, J. Xu, Y.S. Meng, T. Wang, J.Y. Lee, Adv. Mater. 26, 3854(2014) DOI URL PMID
[38]	J.H. Kim, M.J. Jung, M.J. Kim, Y.S. Lee, J. Ind. Eng. Chem. 61, 368(2018)
[39]	S. Qiu, L. Xiao, M.L. Sushko, K.S. Han, Y. Shao, M. Yan, X. Liang, L. Mai, J. Feng, Y. Cao, X. Ai, H. Yang, J. Liu, Adv. Energy Mater. 7, 1700403(2017)
[40]	D. Saurel, B. Orayech, B. Xiao, D. Carriazo, X. Li, T. Rojo, Adv. Energy Mater. 8, 1703268(2018)
[41]	J.Z. Guo, Y. Yang, D.S. Liu, X.L. Wu, B.H. Hou, W.L. Pang, K.C. Huang, J.P. Zhang, Z.M. Su, Adv. Energy Mater. 8, 1702504(2018)
[42]	J. Liang, C. Yuan, H. Li, K. Fan, Z. Wei, H. Sun, J. Ma, Nano-Micro Lett. 10, 21(2018)
[43]	M.S. Park, G.X. Wang, Y.M. Kang, D. Wexler, S.X. Dou, H.K. Liu, Angew. Chem. Int. Ed. 46, 750(2007)
[44]	Y. Yang, X. Zhao, H.-E. Wang, M. Li, C. Hao, M. Ji, S. Ren, G. Cao, J. Mater. Chem. A 6, 3479 (2018)
[45]	X.W. Lou, C.M. Li, L.A. Archer, Adv. Mater. 21, 2536(2009)
[46]	X. Zhou, L.J. Wan, Y.G. Guo, Adv. Mater. 25, 2152 (2013) DOI URL PMID
[47]	D. Chao, C. Zhu, P. Yang, X. Xia, J. Liu, J. Wang, X. Fan, S.V. Savilov, J. Lin, H.J. Fan, Z.X. Shen, Nat. Commun. 7, 12122(2016) DOI URL PMID
[48]	J.Z. Guo, P.F. Wang, X.L. Wu, X.H. Zhang, Q. Yan, H. Chen, J.P. Zhang, Y.G. Guo, Adv. Mater. 29, 1701968(2017)

Nano-SnO₂ Decorated Carbon Cloth as Flexible, Self-supporting and Additive-Free Anode for Sodium/Lithium-Ion Batteries

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 9

参考文献 48

相关文章 0

编辑推荐

Metrics

本文评价