Acta Metallurgica Sinica (English Letters) ›› 2025, Vol. 38 ›› Issue (11): 1909-1925.DOI: 10.1007/s40195-025-01922-1
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Shuaiwu Peng1, Zejun Chen1, Runhua Yao1, Sen Pei2, Ruiqiang Hang1, Yonghua Sun2(
), Xiaohong Yao1(
), Ying Lu3(
)
Received:2025-03-12
Revised:2025-05-29
Accepted:2025-06-05
Online:2025-11-10
Published:2025-09-26
Contact:
Yonghua Sun, sunyonghua@tyut.edu.cn;
Xiaohong Yao, xhyao@tyut.edu.cn;
Ying Lu, luying@sxbqeh.com.cnShuaiwu Peng, Zejun Chen, Runhua Yao, Sen Pei, Ruiqiang Hang, Yonghua Sun, Xiaohong Yao, Ying Lu. Corrosion Behavior, Antioxidation Property, Antibacterial Ability, and Osteogenic Activity of Zn / Chitosan-Catechol Coating Prepared on NiTi Alloy[J]. Acta Metallurgica Sinica (English Letters), 2025, 38(11): 1909-1925.
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Fig. 1 a Preparation process of Zn/PDA/ CS-C coating; b Fourier infrared spectra of CS, PDA and CS-C; c ultraviolet-visible spectrograms of CS and CS-C; d Fourier infrared spectra of different samples; e Fourier infrared spectra of each sample in the range of 1500-1700 cm−1; f, g and h represent the surface topography of samples Zn-3 h, Zn/PDA, Zn/PDA/CS-C-24 h and EDS analysis
Fig. 3 a Potentiodynamic polarization curves; b Nyquist plots of different samples; Bode plots c and phase angles d of different samples, with solid lines showing the fitting results (equivalent circuit diagram e); f schematic diagram of corrosion mechanism
| Sample | Ecorr (V vs SCE) | Icorr (A·cm−2) | βc (V · decade−1) |
|---|---|---|---|
| Zn-3 h | −0.577 | 6.310 × 10-8 | 0.14 |
| Zn/PDA | −0.635 | 8.121 × 10-9 | 0.08 |
| Zn/PDA/CS | −0.725 | 6.124 × 10-9 | 0.09 |
| Zn/PDA/CS-C-1 h | −0.576 | 5.636 × 10-9 | 0.13 |
| Zn/PDA/CS-C-6 h | −0.462 | 5.518 × 10-9 | 0.10 |
| Zn/PDA/CS-C-12 h | −0.599 | 4.872 × 10-9 | 0.12 |
| Zn/PDA/CS-C-24 h | −0.665 | 3.980 × 10-9 | 0.10 |
Table 1 Electrochemical parameters separated from the potentiodynamic polarization curves
| Sample | Ecorr (V vs SCE) | Icorr (A·cm−2) | βc (V · decade−1) |
|---|---|---|---|
| Zn-3 h | −0.577 | 6.310 × 10-8 | 0.14 |
| Zn/PDA | −0.635 | 8.121 × 10-9 | 0.08 |
| Zn/PDA/CS | −0.725 | 6.124 × 10-9 | 0.09 |
| Zn/PDA/CS-C-1 h | −0.576 | 5.636 × 10-9 | 0.13 |
| Zn/PDA/CS-C-6 h | −0.462 | 5.518 × 10-9 | 0.10 |
| Zn/PDA/CS-C-12 h | −0.599 | 4.872 × 10-9 | 0.12 |
| Zn/PDA/CS-C-24 h | −0.665 | 3.980 × 10-9 | 0.10 |
| Sample | Rs (Ω·cm2) | Rp (Ω·cm2) | CPEp (Ω−1·cm−2·s-n) | n |
|---|---|---|---|---|
| Zn-3 h | 21.63 | 9.693 × 107 | 2.696 × 10-5 | 0.97 |
| Zn/PDA | 29.42 | 7.547 × 108 | 9.626 × 10-5 | 0.93 |
| Zn/PDA/CS | 33.44 | 9.626 × 108 | 2.946 × 10-5 | 0.91 |
| Zn/PDA/CS-C-1 h | 26.81 | 1.845 × 109 | 3.058 × 10-5 | 0.96 |
| Zn/PDA/CS-C-6 h | 28.42 | 2.657 × 109 | 3.910 × 10-5 | 0.92 |
| Zn/PDA/CS-C-12 h | 29.11 | 4.872 × 109 | 3.491 × 10-5 | 0.92 |
| Zn/PDA/CS-C-24 h | 45.36 | 5.799 × 109 | 6.767 × 10-5 | 0.94 |
Table 2 EIS fitting data
| Sample | Rs (Ω·cm2) | Rp (Ω·cm2) | CPEp (Ω−1·cm−2·s-n) | n |
|---|---|---|---|---|
| Zn-3 h | 21.63 | 9.693 × 107 | 2.696 × 10-5 | 0.97 |
| Zn/PDA | 29.42 | 7.547 × 108 | 9.626 × 10-5 | 0.93 |
| Zn/PDA/CS | 33.44 | 9.626 × 108 | 2.946 × 10-5 | 0.91 |
| Zn/PDA/CS-C-1 h | 26.81 | 1.845 × 109 | 3.058 × 10-5 | 0.96 |
| Zn/PDA/CS-C-6 h | 28.42 | 2.657 × 109 | 3.910 × 10-5 | 0.92 |
| Zn/PDA/CS-C-12 h | 29.11 | 4.872 × 109 | 3.491 × 10-5 | 0.92 |
| Zn/PDA/CS-C-24 h | 45.36 | 5.799 × 109 | 6.767 × 10-5 | 0.94 |
Fig. 5 a SEM morphologies of S.aureus cultured at 37 °C for 12 h in different samples; b optical photographs of S.aureus cultured at 37 °C on AGAR plates; c antibacterial rates of different samples, *p < 0.05, **p < 0.01
Fig. 7 a Fluorescent images of cytoskeleton (green) and nucleus (blue); b fluorescent images of osteoblasts after 1, 3 and 5 days of culture; c MTT results of osteoblasts after 1, 3, and 5 days of culture. *p < 0.05, **p < 0.01
Fig. 8 a Absorbance values; b antioxidant rate; c and d quantitative results of cell proliferation of normal and H2O2-stimulated osteoblasts; e intracellular ROS fluorescence images of osteoblasts (staining ROS with DCFH-DA); f quantitative analysis of DCFH-DA mean fluorescence intensity of internal ROS of cells on each sample, *p < 0.05, **p < 0.01, ***p < 0.001
Fig. 9 Qualitative images a ALP activity; b collagen secretion and c ECM mineralization; quantitative results d collagen secretion and e ECM mineralization, *p < 0.05, **p < 0.01, ***p < 0.001
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