S-Doped Carbon-Coated FeS2/C@C Nanorods for Potassium Storage

doi:10.1007/s40195-020-01050-y

金属学报英文版 ›› 2021, Vol. 34 ›› Issue (3): 321-328.DOI: 10.1007/s40195-020-01050-y

收稿日期:2020-01-10 修回日期:2020-02-10 出版日期:2021-03-10 发布日期:2021-03-10

S-Doped Carbon-Coated FeS₂/C@C Nanorods for Potassium Storage

Xin Li¹, Huaping Wang¹, Wenchao Zhang², Yuezhan Feng³, Jianmin Ma¹()

¹School of Physics and Electronics, Hunan University, Changsha, 410082, China
²Institute for Superconducting and Electronic Materials (ISEM), School of Mechanical, Materials, Mechatronics and Biomedical Engineering, Faculty of Engineering and Information Sciences, University of Wollongong, Wollongong, NSW, 2500, Australia

Received:2020-01-10 Revised:2020-02-10 Online:2021-03-10 Published:2021-03-10
Contact: Jianmin Ma
About author:Jianmin Ma, nanoelechem@hnu.edu.cn

摘要/Abstract

Abstract:

Potassium-ion batteries (PIBs) are promising scalable energy storage system; however, one of the challenges for its potential application is the huge volume variations during cycling due to the insertion/extraction of large size potassium ions. Here, we fabricated the S-doped carbon-coated rod-like FeS₂/C@C, which not only effectively alleviate the volume variations upon cycling but also can improve electrical conductivity and maintain the structural integrity. As an anode material for PIBs, the rod-like FeS₂/C@C electrodes delivered excellent rate performance (175 mA h g^-1 at 0.5 A g^-1) and stable cycle performance (262 mA h g^-1 after 100 cycles at 0.1 A g^-1). The superior excellent performance is associated with the unique structure of FeS₂/C@C. The as-synthesized FeS₂/C@C is demonstrated to be a potential anode for PIBs.

Key words: Iron disulfide, Carbon matrix, Potassium-ion batteries, Nanorods, Volume variations

. [J]. 金属学报英文版, 2021, 34(3): 321-328.

Xin Li, Huaping Wang, Wenchao Zhang, Yuezhan Feng, Jianmin Ma. S-Doped Carbon-Coated FeS₂/C@C Nanorods for Potassium Storage[J]. Acta Metallurgica Sinica (English Letters), 2021, 34(3): 321-328.

图/表 5

Fig. 1 Schematic illustration of the synthesis of rod-like FeS2/C@C

Fig. 2 a SEM images of the Fe-MOF; b, c SEM images of the Fe3O4/C@C; d, e SEM images; f XRD images of the FeS2/C@C

Fig. 3 a SEM image, b TEM image, c HRTEM image, d corresponding elemental mapping of Fe, S, and C of FeS2/C@C

Fig. 4 a Raman spectra, b TGA curves of FeS2/C@C and FeS2/C; c XPS survey spectra d Fe 2p, e S 2p, f C 1 s spectra of FeS2/C@C

Fig. 5 a Cyclic voltammograms of FeS2/C@C at a scan rate of 0.1 mV s -1 for the initial 3 cycles; b discharge-charge profiles of FeS2/C@C at different current densities; c cycling performance at 0.1 A g-1 and d rate capability of FeS2/C@C and FeS2/C; e EIS of FeS2/C@C and FeS2/C electrodes before cycling; f BET nitrogen adsorption and desorption isotherms of FeS2/C@C (inset is the corresponding pore size distribution)

参考文献 60

[1]	L. Dai, W. Zhang, C. Hu, Z. Guo, Angew. Chem. 132, 3498(2020)
[2]	W. Zhang, J. Mao, S. Li, Z. Chen, Z. Guo, J. Am. Chem. Soc. 139, 3316(2017) DOI URL PMID
[3]	B. Xu, S. Qi, M. Jin, X. Cai, L. Lai, Z. Sun, X. Han, Z. Lin, H. Shao, P. Peng, Z. Xiang, J. ten Elshof, R. Tan, C. Liu, Z. Zhang, X. Duan, J. Ma, Chin. Chem. Lett. 30, 2053 (2019) DOI URL
[4]	B. Xu, S. Qi, P. He, J. Ma, Chem. Asian J. 14, 2925(2019) DOI URL PMID
[5]	Z. Yan, Q. Yang, Q. Wang, J. Ma, Chin. Chem. Lett. 31, 583(2020)
[6]	Y. Dong, Y. Feng, J. Deng, P. He, J. Ma, Chin. Chem. Lett. 31, 909(2020)
[7]	X. Zhou, Q. Liu, C. Jiang, B. Ji, X. Ji, Y. Tang, H. Cheng, Angew. Chem. Int. Ed. 59, 3802(2020)
[8]	Z. Wei, B. Ding, H. Dou, J. Gascon, X. Kong, Y. Xiong, B. Cai, R. Zhang, Y. Zhou, M. Long, J. Miao, Y. Dou, D. Yuan, J. Ma, Chin. Chem. Lett. 30, 2110 (2019)
[9]	S. Qi, B. Xu, V. Tiong, J. Hu, J. Ma, Chem. Eng. J. 379, 122261(2020) DOI URL
[10]	J. Liao, W. Ni, C. Wang, J. Ma, Chem. Eng. J.(2020). https://doi.org/10.1016/j.cej.2019.123489 DOI URL PMID
[11]	D. Wu, W. Zhang, Y. Feng, J. Ma, J. Mater. Chem. A 8, 2618 (2020)
[12]	S. Qi, X. Xie, X. Peng, D.H.L. Ng, M. Wu, Q. Liu, J. Yang, J. Ma, Phys. Status Solidi RRL 13, 1900209 (2019)
[13]	X. Chang, X. Zhou, X. Ou, C.-S. Lee, J. Zhou, Y. Tang, Adv. Energy Mater. 9, 1902672(2019)
[14]	D. Xie, M. Zhang, Y. Wu, L. Xiang, Y. Tang, Adv. Funct. Mater. 30, 1906770(2020) DOI URL
[15]	L. Xue, H. Gao, W. Zhou, S. Xin, K. Park, Y. Li, J. Goodenough, Adv. Mater. 28, 9608(2016) DOI URL PMID
[16]	W. Luo, J. Wan, B. Ozdemir, W. Bao, Y. Chen, J. Dai, H. Lin, Y. Xu, F. Gu, V. Barone, L. Hu, Nano Lett. 15, 7671(2015) URL PMID
[17]	M. Wu, B. Xu, Y. Zhang, S. Qi, W. Ni, J. Hu, J. Ma, Chem. Eng. J. 381, 122558(2020) DOI URL
[18]	H. Hou, C.E. Banks, M. Jing, Y. Zhang, X. Ji, Adv. Mater. 27, 7861(2015) DOI URL PMID
[19]	N. Li, F. Zhang, Y. Tang, J. Mater. Chem. A 6, 17889 (2018) DOI URL
[20]	M. Chen, D. Cortie, Z. Hu, H. Jin, S. Wang, Q. Gu, W. Hua, E. Wang, W. Lai, L. Chen, S. Chou, X. Wang, S. Dou, Adv. Energy Mater. 8, 1800944(2018) DOI URL
[21]	A. Eftekhari, Z. Jian, X. Ji, A.C.S. Appl, Mater. Interfaces 9, 4404 (2017)
[22]	W. Zhang, Y. Liu, Z. Guo, Sci. Adv. 5, 7412(2019)
[23]	M. Chen, E. Wang, Q. Liu, X. Guo, W. Chen, S. Chou, S. Dou, Energy Storage Mater. 19, 163(2019)
[24]	Z. Jian, W. Luo, X. Ji, J. Am. Chem. Soc. 137, 11566(2015) URL PMID
[25]	M. Wu, J. Yang, D. Ng, J. Ma, Phys. Status Solidi RRL 13, 1900329 (2019)
[26]	X. Xie, S. Qi, D. Wu, H. Wang, F. Li, X. Peng, J. Cai, J. Liang, J. Ma, Chin. Chem. Lett. 31, 223(2020)
[27]	B. Xu, S. Qi, F. Li, X. Peng, J. Cai, J. Liang, J. Ma, Chin. Chem. Lett. 31, 217(2020)
[28]	B. Liu, J. Wang, J. Li, K. Fan, D. Zhao, G. Liu, C. Yang, H. Tong, D. Qian, J. Phys. Chem. Solids 134, 214 (2019)
[29]	X. Yang, P. Wang, Y. Tang, C. Peng, Y. Lai, J. Li, Z. Zhang, Ionics 25, 2945 (2019)
[30]	L. Fang, J. Xu, S. Sun, B. Lin, Q. Guo, D. Luo, H. Xia, Small 15, 1804806 (2019)
[31]	Z. Hu, Z. Zhu, F. Cheng, K. Zhang, J. Wang, C. Chen, J. Chen, Energy Environ. Sci. 8, 1309(2015)
[32]	B. Hou, Y. Wang, J. Guo, Q. Ning, X. Xi, W. Pang, A. Cao, X. Wang, J. Zhang, X. Wu, Nanoscale 10, 9218 (2018) DOI URL PMID
[33]	J. Liu, Y. Wen, Y. Wang, P.A. van Aken, J. Maier, Y. Yu, Adv. Mater. 26, 6025(2014) DOI URL PMID
[34]	Y. Zhao, J. Zhu, S.J.H. Ong, Q. Yao, X. Shi, K. Hou, Z.J. Xu, L. Guan, Adv. Energy Mater. 8, 1802565(2018)
[35]	M. Walter, T. Zünd, M.V. Kovalenko, Nanoscale 7, 9158 (2015) DOI URL PMID
[36]	Z. Shadike, Y.N. Zhou, F. Ding, L. Sang, K.W. Nam, X.Q. Yang, Z.W. Fu, J. Power Sources 260, 72 (2014)
[37]	J. Xie, Y. Zhu, N. Zhuang, H. Lei, W. Zhu, Y. Fu, M.S. Javed, J. Li, W. Mai, Nanoscale 10, 17092-17098 (2018) DOI URL PMID
[38]	Z. Zhao, Z. Hu, R. Jiao, Z. Tang, P. Dong, Y. Li, S. Li, H. Li, Energy Storage Mater. 22, 228(2019)
[39]	B. Guan, X. Wang, Y. Xiao, Y. Liu, Q. Huo, Nanoscale 364, 208 (2017)
[40]	Y. Xu, W. Li, F. Zhang, X. Zhang, W. Zhang, C.S. Lee, Y. Tang, J. Mater. Chem. A 4, 3697 (2016)
[41]	K. Share, A.P. Cohn, R. Carter, B. Rogers, C.L. Pint, ACS Nano 10, 9738 (2016) DOI URL PMID
[42]	X. Xu, J. Liu, Z. Liu, J. Shen, R. Hu, J. Liu, L. Ouyang, L. Zhang, M. Zhu, ACS Nano 11, 9033 (2017) DOI URL PMID
[43]	Z. Cao, H. Song, B. Cao, J. Ma, X. Chen, J. Zhou, Z. Ma, J. Power Sources 364, 208 (2017)
[44]	Z. Chen, S. Li, Y. Zhao, M.F. Aly Aboud, I. Shakir, Y. Xu, J. Mater. Chem. A 7, 26342 (2019)
[45]	H. Pang, W. Sun, L.P. Lv, F. Jin, Y. Wang, J. Mater. Chem. A 4, 19179 (2016)
[46]	F. Jin, Y. Wang, J. Mater. Chem. A 3, 14741 (2015)
[47]	W. Chen, S. Qi, M. Yu, X. Feng, S. Cui, J. Zhang, L. Mi, Electrochim. Acta 230, 1 (2017)
[48]	Q. Yao, J. Zhang, X. Shi, B. Deng, K. Hou, Y. Zhao, L. Guan, Electrochim. Acta 307, 118 (2019)
[49]	K. Shehzad, Y. Xu, C. Gao, X. Duan, Chem. Soc. Rev. 45, 5541(2016) DOI URL PMID
[50]	Q. Wang, W. Zhang, C. Guo, Y. Liu, C. Wang, Z. Guo, Adv. Funct. Mater. 27, 1703390(2017)
[51]	X. Xu, J. Liu, J. Liu, L. Ouyang, R. Hu, H. Wang, L. Yang, M. Zhu, Adv. Funct. Mater. 28, 1707573(2018)
[52]	Y. Wang, J. Yang, S. Chou, H. Liu, W. Zhang, D. Zhao, S. Dou, Nat. Commun. 6, 8689(2015) DOI URL PMID
[53]	B. Wu, H. Song, J. Zhou, X. Chen, Chem. Commun. 47, 8653(2011) DOI URL
[54]	O. Mashtalir, M. Naguib, V.N. Mochalin, Y. Dall’Agnese, M. Heon, M.W. Barsoum, Y. Gogotsi, Nat. Commun. 4, 1716(2013) DOI URL PMID
[55]	L. Yu, J. Liu, X. Xu, L. Zhang, R. Hu, J. Liu, L. Ouyang, L. Yang, M. Zhu, ACS Nano 11, 5120 (2017) DOI URL PMID
[56]	J. Cho, J. Lee, Y. Kang, Sci. Rep. 6, 23699(2016) URL PMID
[57]	J. Cho, S. Lee, Y. Kang, Sci. Rep. 6, 23338(2016) URL PMID
[58]	Y. Zhao, L.P. Wang, S. Xi, Y. Du, Q. Yao, L. Guan, Z. Xu, J. Mater. Chem. A 5, 25609 (2017)
[59]	D. Wu, C. Wang, M. Wu, Y. Chao, P. He, J. Ma, J. Energy Chem. 43, 24(2020)
[60]	D. Li, Q. Sun, Y. Zhang, L. Chen, Z. Wang, Z. Liang, P. Si, L. Ci, Chemsuschem 12, 2689 (2019) DOI URL PMID

S-Doped Carbon-Coated FeS₂/C@C Nanorods for Potassium Storage

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 5

参考文献 60

相关文章 0

编辑推荐

Metrics

本文评价