Mechanical Relaxation of a Ti36.2Zr30.3Cu8.3Fe4Be21.2 Bulk Metallic Glass: Experiments and Theoretical Analysis

doi:10.1007/s40195-018-0860-z

Abstract

Abstract:

The dynamic mechanical relaxation behavior of Ti_36.2Zr_30.3Cu_8.3Fe₄Be_21.2 bulk metallic glass with good glass-forming ability was investigated by mechanical spectroscopy. The mechanical relaxation behavior was analyzed in the framework of quasi-point defects model. The experimental results demonstrate that the atomic mobility of the metallic glass is closely associated with the correlation factor χ. The physical aging below the glass transition temperature T_g shows a non-Debye relaxation behavior, which could be well described by stretched Kohlrausch exponential equation. The Kohlrausch exponent \(\beta_{\text{aging}}\) reflects the dynamic heterogeneities of the metallic glass. Both concentration of “defects” and atomic mobility decrease caused by the in situ successive heating during the mechanical spectroscopy experiments.

Key words: Metallic, glasses, Mechanical, relaxation, Physical, aging, Quasi-point, defects

Qiao J.C., Chen Y.H., Lyu G.J., Song K.K., Pelletier J.M., Yao Y.. Mechanical Relaxation of a Ti_36.2Zr_30.3Cu_8.3Fe₄Be_21.2 Bulk Metallic Glass: Experiments and Theoretical Analysis[J]. Acta Metallurgica Sinica (English Letters), 2019, 32(6): 726-732.

Figures/Tables 8

Fig. 1 a XRD pattern of the as-cast Ti36.2Zr30.3Cu8.3Fe4Be21.2 bulk metallic glass, which confirms the amorphous structure of the model alloy, b DSC curve of the Ti36.2Zr30.3Cu8.3Fe4Be21.2 metallic glass with a heating rate of 20 K/min

Fig. 2 Temperature dependence of the normalized storage modulus E′/Eu and loss modulus E″/Eu of the Ti36.2Zr30.3Cu8.3Fe4Be21.2 bulk metallic glass. The driving frequency is set to be 0.3 Hz, and the heating rate is 3 K/min. The unrelaxed modulus Eu is estimated as the storage modulus at ambient temperature

Fig. 3 Variation of ln (tan\(\delta\)) as a function of 1000/T of Ti36.2Zr30.3Cu8.3Fe4Be21.2 bulk metallic glass

Fig. 4 Normalized storage modulus E′/Eu and loss modulus E″/Eu as functions of temperature with frequency ranges from 0.1 to 3 Hz for the Ti36.2Zr30.3Cu8.3Fe4Be21.2 bulk metallic glass

Fig. 5 Time dependence of the normalized storage modulus E′/Eu and loss modulus E″/Eu at the aging temperature of 523 K for 24 h

Fig. 6 Variation of internal friction tan\(\delta\) as a function of annealing time at isothermal temperature 523 K for Ti36.2Zr30.3Cu8.3Fe4Be21.2 metallic glass

Fig. 7 Time dependence of internal friction tan\(\delta\) under different annealing temperatures, and the red lines are the fitting curves

Fig. 8 Temperature dependence of the normalized storage modulus E′/Eu and loss modulus E″/Eu in Ti36.2Zr30.3Cu8.3Fe4Be21.2 metallic glass during successive heating to 800 K (640-685-725-800 K). The frequency is 0.3 Hz, and the heating rate is 3 K/min

References

[1]	A.L. Greer, Y.Q. Cheng, E. Ma, Mater. Sci. Eng. R Rep. 74, 71(2013)
[2]	W.H. Wang, Prog. Mater. Sci. 57, 487(2012)
[3]	F.F. Wu, J.S. Wei, K.C. Chan, S.H. Chen, R.D. Zhao, G.A. Zhang, X.F. Wu, Sci. Rep. 7, 42598(2017)
[4]	M. Chen, NPG Asia Mater. 3, 82(2011)
[5]	H.B. Yu, W.H. Wang, K. Samwer, Mater. Today 16, 183 (2013)
[6]	J.C. Qiao, J.M. Pelletier, J. Mater. Sci. Technol. 30, 523(2014)
[7]	J.C. Qiao, Q. Wang, D. Crespo, Y. Yang, J.M. Pelletier, Chin. Phys. B 26, 016402 (2017)
[8]	R. Richert, Phys. Rev. Lett. 104(4), 085702(2010)
[9]	P. Luo, Y.Z. Li, H.Y. Bai, P. Wen, W.H. Wang, Phys. Rev. Lett. 116, 175901(2016)
[10]	B. Ruta, Y. Chushkin, G. Monaco, L. Cipelletti, E. Pineda, P. Bruna, V.M. Giordano, M. Gonzalez-Silveira, Phys. Rev. Lett. 109, 165701(2012)
[11]	Q. Wang, J.J. Liu, Y.F. Ye, T.T. Liu, S. Wang, C.T. Liu, J. Lu, Y. Yang, Mater. Today 20, 293 (2017)
[12]	S.V. Nemilov, Y.S. Balashov, Glass Phys.Chem. 42, 119(2016)
[13]	J.C. Qiao, J. Cong, Q. Wang, J.M. Pelletier, Y. Yao, J. Alloys Compd. 749, 262(2018)
[14]	F.X. Qin, Y. Zhou, C. Ji, Z.H. Dan, G.Q. Xie, S. Yang, Acta Metall. Sin. (Engl. Lett.) 29, 1011(2016)
[15]	J. Mei, J. Li, H. Kou, J.-L. Soubeyroux, H. Fu, L. Zhou, J. Alloys Compd. 467, 235(2009)
[16]	J. Qiao, S. Feng, J. Pelletier, D. Crespo, E. Pineda, Y. Yao, J. Alloys Compd. 726, 195(2017)
[17]	H.B. Yu, K. Samwer, Phys. Rev. B 90, 114201 (2014)
[18]	L. Zhang, Z.W. Zhu, A.M. Wang, H. Li, H.M. Fu, H.W. Zhang, H.F. Zhang, Z.Q. Hu, J. Alloys Compd. 562, 205(2013)
[19]	Y.H. Sun, A. Concustell, M.A. Carpenter, J.C. Qiao, A.W. Rayment, A.L. Greer, Acta Mater. 112, 132(2016)
[20]	Y. Wu, W.L. Song, Z.Y. Zhang, X.D. Hui, D. Ma, X.L. Wang, X.C. Shang, Z.P. Lu, Chin. Phys. B 56, 3960 (2011)
[21]	J.C. Qiao, J.M. Pelletier, Intermetallics 28, 40 (2012)
[22]	J.C. Qiao, Y. Yao, J.M. Pelletier, L.M. Keer, Int. J. Plast. 82, 62(2016)
[23]	Q. Wang, J.M. Pelletier, J.J. Blandin, J. Alloys Compd. 504, 357(2010)
[24]	J. Perez, Polymer 29, 483 (1988)
[25]	J. Perez, Solid State Ion. 39, 69(1990)
[26]	R. Rinaldi, R. Gaertner, L. Chazeau, C. Gauthier, Int. J.Non-Linear Mech. 46, 496(2011)
[27]	M.B.M. Mangion, J.Y. Cavaille, J. Perez, Philos.Mag. A Phys. Condens. Matter Struct. Defect Mech. Prop. 66, 773(1992)
[28]	K.P. Menard, Dynamic Mechanical Analysis: A Practical Introduction (CRC Press, Boca Raton, 2008)
[29]	D.P. Wang, Z.G. Zhu, R.J. Xue, D.W. Ding, H.Y. Bai, W.H. Wang, J. Appl. Phys. 114, 362(2013)
[30]	J.C. Qiao, J.M. Pelletier, R. Casalini, J. Phys. Chem. B 117, 13658 (2013)
[31]	X.D. Wang, J.Z. Jiang, S. Yi, J. Solids Non-Cryst. 353, 4157(2007)
[32]	J.C. Qiao, J.M. Pelletier, C. Esnouf, Y. Liu, H. Kato, J. Alloys Compd. 607, 139(2014)
[33]	J.M. Pelletier, J. Non-Cryst.Solids 354, 3666 (2008)
[34]	L. Berthier, Physics 4, 42 (2011)
[35]	R. Richert, J. Phys.-Condens. Matter 14, 26721-1 (2002)
[36]	J.C. Qiao, J.M. Pelletier, H.C. Kou, X. Zhou, Intermetallics 28, 128 (2012)
[37]	J. Qiao, B. Sun, J. Gu, M. Song, J. Pelletier, J. Qiao, Y. Yao, Y. Yang, J. Alloys Compd. 724, 921(2017)

Mechanical Relaxation of a Ti_36.2Zr_30.3Cu_8.3Fe₄Be_21.2 Bulk Metallic Glass: Experiments and Theoretical Analysis

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