Acta Metallurgica Sinica (English Letters) ›› 2019, Vol. 32 ›› Issue (7): 913-924.DOI: 10.1007/s40195-018-0846-x
Special Issue: 2019年铝合金专辑; 2019年腐蚀专辑-2
• Orginal Article • Previous Articles
Tian-Hui Hu 1,2, Hong-Wei Shi 2(), Tao Wei2, Shi-Hua Fan1, Fu-Chun Liu2, En-Hou Han2
Received:
2018-08-26
Revised:
2018-10-15
Accepted:
2018-11-19
Online:
2018-11-19
Published:
2019-06-20
Tian-Hui Hu, Hong-Wei Shi, Tao Wei, Shi-Hua Fan, Fu-Chun Liu, En-Hou Han. Corrosion Protection of AA2024-T3 by Cerium Malate and Cerium Malate-Doped Sol-Gel Coatings[J]. Acta Metallurgica Sinica (English Letters), 2019, 32(7): 913-924.
Add to citation manager EndNote|Ris|BibTeX
Fig. 1 SEM images of polished AA2024-T3 samples after 1 day of immersion in a 0.05 mol/L NaCl solution, b 0.05 mol/L NaCl solution with saturated CeMal
Fig. 2 Polarization curves for AA2024-T3 samples immersed in 0.05 mol/L NaCl solution, 0.05 mol/L NaCl solution with 0.018 mol/L NaMal, 0.012 mol/L CeCl3 or saturated CeMal
Fig. 5 Polarization curves for AA2024-T3 samples immersed in a blank 0.05 mol/L NaCl solution and 0.05 mol/L NaCl solution with saturated CeMal for different times, b Nyquist plot for AA2024-T3 sample immersed in blank 0.05 mol/L NaCl solution and 0.05 mol/L NaCl solution with saturated CeMal for different times
Fig. 6 SVET maps over the sample after a 0 h, b 10 h, c 24 h of immersion, d optical photograph of bare AA2024-T3 after 24 h of immersion in 0.05 mol/L NaCl solution
Fig. 7 SVET maps over the sample after a 0 h, b 12 h, c 24 h of immersion, d optical photograph of bare AA2024-T3 after 24 h of immersion in 0.05 mol/L NaCl solution with saturated CeMal
Fig. 8 SEM images of the surface of the samples coated with a reference, c E-CeMal, e S-CeMal sol-gel coatings, and cross section of the samples coated with b reference, d E-CeMal, f S-CeMal sol-gel coatings
Fig. 9 SEM images of the surface of the samples coated with a reference, b E-CeMal, c S-CeMal sol-gel coatings after 3 days of immersion in 0.005 mol/L NaCl solution
Fig. 10 Bode plots of the samples coated with a, b reference, c, d E-CeMal, e, f S-CeMal sol-gel coatings during immersion in 0.005 mol/L NaCl solution
Sample | Time (h) | Rc (ohm cm2) | Qc (S cm-2 sn) | n c | Ro (ohm cm2) | Qo (S cm-2 sn) | n o | Rct (ohm cm2) | Qdl (S cm-2 sn) | n dl |
---|---|---|---|---|---|---|---|---|---|---|
Reference | 0 | 3.81?×?104 | 1.25?×?10-7 | 0.78 | 3.50?×?107 | 3.26?×?10-6 | 0.80 | |||
8 | 1.51?×?104 | 1.91?×?10-7 | 0.75 | 1.54?×?106 | 4.07?×?10-6 | 0.84 | ||||
24 | 6.19?×?103 | 5.51?×?10-7 | 0.67 | 2.51?×?105 | 5.60?×?10-6 | 0.83 | ||||
96 | 9.28?×?102 | 1.61?×?10-6 | 0.56 | 7.45?×?103 | 1.14?×?10-5 | 0.77 | 1.65?×?104 | 3.27?×?10-5 | 0.85 | |
168 | 7.53?×?102 | 1.34?×?10-6 | 0.53 | 2.78?×?103 | 8.78?×?10-6 | 0.84 | 1.73?×?104 | 1.36?×?10-5 | 0.88 | |
E-CeMal | 0 | 8.01?×?103 | 2.58?×?10-7 | 0.71 | 2.22?×?106 | 2.33?×?10-6 | 0.88 | |||
8 | 5.29?×?103 | 2.36?×?10-7 | 0.73 | 7.78?×?105 | 5.31?×?10-6 | 0.76 | ||||
24 | 4.14?×?103 | 2.17?×?10-7 | 0.74 | 1.16?×?106 | 5.93?×?10-6 | 0.77 | ||||
96 | 2.19?×?103 | 3.11?×?10-7 | 0.72 | 9.59?×?105 | 5.63?×?10-6 | 0.79 | ||||
168 | 1.27?×?103 | 5.70?×?10-7 | 0.66 | 5.42?×?105 | 5.30?×?10-6 | 0.80 | ||||
S-CeMal | 0 | 3.17?×?104 | 4.09?×?10-8 | 0.82 | 3.14?×?107 | 3.41?×?10-6 | 0.86 | |||
8 | 1.83?×?104 | 5.26?×?10-8 | 0.81 | 8.95?×?106 | 3.86?×?10-6 | 0.87 | ||||
24 | 7.27?×?103 | 9.64?×?10-8 | 0.76 | 9.24?×?105 | 4.87?×?10-6 | 0.82 | ||||
96 | 3.13?×?103 | 2.15?×?10-7 | 0.71 | 4.15?×?105 | 5.17?×?10-6 | 0.85 | ||||
168 | 1.98?×?103 | 3.77?×?10-7 | 0.65 | 2.86?×?105 | 5.47?×?10-6 | 0.83 |
Table 1 Circuit parameters fitted from the EIS data of the sol-gel coatings during immersion in 0.005 mol/L NaCl solution
Sample | Time (h) | Rc (ohm cm2) | Qc (S cm-2 sn) | n c | Ro (ohm cm2) | Qo (S cm-2 sn) | n o | Rct (ohm cm2) | Qdl (S cm-2 sn) | n dl |
---|---|---|---|---|---|---|---|---|---|---|
Reference | 0 | 3.81?×?104 | 1.25?×?10-7 | 0.78 | 3.50?×?107 | 3.26?×?10-6 | 0.80 | |||
8 | 1.51?×?104 | 1.91?×?10-7 | 0.75 | 1.54?×?106 | 4.07?×?10-6 | 0.84 | ||||
24 | 6.19?×?103 | 5.51?×?10-7 | 0.67 | 2.51?×?105 | 5.60?×?10-6 | 0.83 | ||||
96 | 9.28?×?102 | 1.61?×?10-6 | 0.56 | 7.45?×?103 | 1.14?×?10-5 | 0.77 | 1.65?×?104 | 3.27?×?10-5 | 0.85 | |
168 | 7.53?×?102 | 1.34?×?10-6 | 0.53 | 2.78?×?103 | 8.78?×?10-6 | 0.84 | 1.73?×?104 | 1.36?×?10-5 | 0.88 | |
E-CeMal | 0 | 8.01?×?103 | 2.58?×?10-7 | 0.71 | 2.22?×?106 | 2.33?×?10-6 | 0.88 | |||
8 | 5.29?×?103 | 2.36?×?10-7 | 0.73 | 7.78?×?105 | 5.31?×?10-6 | 0.76 | ||||
24 | 4.14?×?103 | 2.17?×?10-7 | 0.74 | 1.16?×?106 | 5.93?×?10-6 | 0.77 | ||||
96 | 2.19?×?103 | 3.11?×?10-7 | 0.72 | 9.59?×?105 | 5.63?×?10-6 | 0.79 | ||||
168 | 1.27?×?103 | 5.70?×?10-7 | 0.66 | 5.42?×?105 | 5.30?×?10-6 | 0.80 | ||||
S-CeMal | 0 | 3.17?×?104 | 4.09?×?10-8 | 0.82 | 3.14?×?107 | 3.41?×?10-6 | 0.86 | |||
8 | 1.83?×?104 | 5.26?×?10-8 | 0.81 | 8.95?×?106 | 3.86?×?10-6 | 0.87 | ||||
24 | 7.27?×?103 | 9.64?×?10-8 | 0.76 | 9.24?×?105 | 4.87?×?10-6 | 0.82 | ||||
96 | 3.13?×?103 | 2.15?×?10-7 | 0.71 | 4.15?×?105 | 5.17?×?10-6 | 0.85 | ||||
168 | 1.98?×?103 | 3.77?×?10-7 | 0.65 | 2.86?×?105 | 5.47?×?10-6 | 0.83 |
|
[1] | Xiao-Lei Fan, Yun-Xiang Chen, Jun-Xi Zhang, De-Yuan Lin, Xuan-Xuan Liu, Xiao-Jian Xia. Galvanic Corrosion Behavior of Copper-Drawn Steel for Grounding Grids in the Acidic Red Soil Simulated Solution [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(11): 1571-1582. |
[2] | Huan-Huan Wang, Du Min ?. Corrosion Behavior of a Low-Carbon Steel in Simulated Marine Splash Zone [J]. Acta Metallurgica Sinica (English Letters), 2017, 30(6): 585-593. |
[3] | Robert Blair, Batric Pesic, Jacob Kline, Ian Ehrsam, Krishnan Raja. Threshold Chloride Concentrations and Passivity Breakdown of Rebar Steel in Real Concrete Solution at Different pH Conditions with the Addition of Glycerol [J]. Acta Metallurgica Sinica (English Letters), 2017, 30(4): 376-389. |
[4] | Liang Fan, Fujian Tang, Signo T. Reis, Genda Chen, Michael L. Koenigstein. Corrosion Resistance of Transmission Pipeline Steel Coated with Five Types of Enamels [J]. Acta Metallurgica Sinica (English Letters), 2017, 30(4): 390-398. |
[5] | Sahar A. Fadlallah, Mohammed A. Amin, Ghaida S. Alosaimi. Construction of Nanophase Novel Coatings-Based Titanium for the Enhancement of Protein Adsorption [J]. Acta Metallurgica Sinica (English Letters), 2016, 29(3): 243-252. |
[6] | Arash Fattah-Alhosseini, Mojtaba Vakili-Azghandi, Mohsen K. Keshavarz. Influence of Concentrations of KOH and Na2SiO3 Electrolytes on the Electrochemical Behavior of Ceramic Coatings on 6061 Al Alloy Processed by Plasma Electrolytic Oxidation [J]. Acta Metallurgica Sinica (English Letters), 2016, 29(3): 274-281. |
[7] | Qing-He Zhao,Wei Liu,Shuan-Zhu Li,Bin-Li Zhang,Yi-Chun Zhu,Min-Xu Lu. Effects of W and Mo Additions on Wet-dry Acid Corrosion Behavior of Low-Alloy Steels Under Different O2 Concentrations [J]. Acta Metallurgica Sinica (English Letters), 2016, 29(10): 951-962. |
[8] | Arash Fattah-alhosseini, Seyed Omid Gashti. Passive Behavior of Ultra-Fine-Grained 1050 Aluminum Alloy Produced by Accumulative Roll Bonding in a Borate Buffer Solution [J]. Acta Metallurgica Sinica (English Letters), 2015, 28(10): 1222-1229. |
[9] | Tang-Qing Wu, Mao-Cheng Yan, De-Chun Zeng, Jin Xu, Chang-Kun Yu, Cheng Sun, Wei Ke. Microbiologically Induced Corrosion of X80 Pipeline Steel in a Near-Neutral pH Soil Solution [J]. Acta Metallurgica Sinica (English Letters), 2015, 28(1): 93-102. |
Viewed | ||||||
Full text |
|
|||||
Abstract |
|
|||||